Applied Chemistry for Engineering, Vol.25, No.3, 242-248, June, 2014
차세대 투명전극 소재의 종류와 특성
Materials and Characteristics of Emerging Transparent Electrodes
E-mail:
초록
정보.통신 분야의 발전에 따라 기존의 전자 기기들은 평면성을 벗어나 투명.유연하고 깨지지 않는 특성이 요구되고 있다. 이러한 부가적인 특성을 갖춘 기기들의 제조를 위해서는 전극의 투명성과 유연성을 동시에 갖고 있어야 하지만, 현재 가장 대표적으로 이용되는 투명전극인 ITO (Indium Tin Oxide)는 유연하지 못하다는 단점과 자원적인 한계를 갖고 있다. 이에 따라 ITO의 한계를 극복하기 위해 다양한 물질들을 이용한 대체 재료 개발이 활발히 연구되고 있으며 대체 물질들의 복합화를 통해 더 향상된 물성을 발현시키기 위한 연구가 진행되고 있다. 본 총설에서는 ITO의 한계를 극복하고 투명전극으로서의 응용 가능한 대체 물질들에 대한 연구 현황을 정리하였다.
Flexibility of a transparent device has been required in accordance with miniaturization and mobilization needs in recent industry. The most representative material used as a transparent electrode is indium tin oxide (ITO). However, a couple of disadvantages of ITO are the exhaustion of natural resource of indium and its inflexibility due to inorganic substance. To overcome the limit of ITO, a variety of alternative materials have been researched on development of transparent electrodes and its properties through composite materials. In this review, we classify some of emerged materials with their general studies.
Keywords:Transparent electrode;Transparent conducting oxide;Carbon materials;Conducting polymer;Metal nanowire
- Wassei JK, Kaner RB, Materialstoday, 13, 52 (2010)
- Lee KH, Kim SM, Jeong H, Pak Y, Song H, Park J, Lim KH, Kim JH, Kim YS, Ko HC, Kwon IK, Jung GY, Adv. Mater., 25(23), 3209 (2013)
- Nakashima K, Kumahara Y, Vacuum, 66, 221 (2002)
- Manavizadeh N, Boroumand FA, Asl-Soleimani E, Raissi F, Bagherzadeh S, Khodayari A, Rasouli MA, Thin Solid Films, 517(7), 2324 (2009)
- Hecht DS, Hu LB, Irvin G, Adv. Mater., 23(13), 1482 (2011)
- Sierros KA, Morris NJ, Ramji K, Cairns DR, Thin Solid Films, 517(8), 2590 (2009)
- Potoczny GA, Bejitual TS, Abell JS, Sierros KA, Cairns DR, Kukureka SN, Thin Solid Films, 528, 205 (2013)
- Hu L, Kim HS, Lee JY, Peumans P, Cui Y, ACS Nano, 4, 2955 (2010)
- Kumar ABVK, Bae CW, Piao L, Kim SH, Mater. Res. Bull., 48(8), 2944 (2013)
- Choi DY, Kang HW, Sung HJ, Kim SS, Nanoscale, 5, 977 (2013)
- Zhu R, Chung CH, Cha KC, Yang W, Zheng YB, Zhou H, Song TB, Chen CC, Weiss PS, Li G, Yang Y, ACS Nano, 5, 9877 (2011)
- Song MK, You DS, Lim K, Park S, Jung S, Kim CS, Kim DH, Kim DG, Kim JK, Park J, Kang YC, Heo J, Jin SH, Park JH, Kang JW, Adv. Funct. Mater., 23, 4177 (2013)
- Bolotin KI, Sikes KJ, Jiang Z, Klima M, Fudenberg G, Hone J, Kim P, Stormer HL, Solid State Communications, 146, 351 (2008)
- Novoselov KS, Geim AK, Morozov SV, Jiang D, Zhang Y, Dubonos SV, Grigorieva IV, Firsov AA, Science, 306, 666 (2004)
- Kim KS, Zhao Y, Jang H, Lee SY, Kim JM, Kim KS, Ahn JH, Kim P, Choi JY, Hong BH, Nature, 457, 706 (2009)
- Bae S, Kim H, Lee Y, Xu XF, Park JS, Zheng Y, Balakrishnan J, Lei T, Kim HR, Song YI, Kim YJ, Kim KS, Ozyilmaz B, Ahn JH, Hong BH, Iijima S, Nat. Nanotechnol., 5(8), 574 (2010)
- Pang SP, Hernandez Y, Feng XL, Mullen K, Adv. Mater., 23(25), 2779 (2011)
- Hecht DS, Heintz AM, Lee RS, Hu L, Moore B, Cucksey C, Risser S, High conductivity transparent carbon nanotube films deposited from superacid, Nanotechnology, 22, 075201 (2011)
- Li J, Hu L, Wang L, Zhou Y, Gruner G, Marks TJ, Nano Lett., 6, 2472 (2006)
- Groenendaal BL, Jonas F, Freitag D, Pielartzik H, Reynolds JR, Adv. Mater., 12(7), 481 (2000)
- Ouyang J, Displays, 34, 423 (2013)
- Alemu D, Wei HY, Ho KC, Chu CW, Energy Environ. Sci., 5, 9662 (2012)
- Badre C, Marquant L, Alsayed AM, Hough LA, Adv. Funct. Mater., 22(13), 2723 (2012)
- Kim N, Kee S, Lee SH, Lee BH, Kahng YH, Jo YR, Kim BJ, Lee K, Adv. Mater., 26, 2268 (2014)
- Xia YJ, Sun K, Ouyang JY, Adv. Mater., 24(18), 2436 (2012)
- Pei QB, Zuccarello G, Ahlskog M, Inganas O, Polymer, 35(7), 1347 (1994)
- Nardes AM, Kemerink M, de Kok MM, Vinken E, Maturova K, Janssen RAJ, Organic electronics, 9, 727 (2008)
- Yun JH, Kim J, Materials Letters, 70, 4 (2012)
- Wu HW, Chu CH, Materials Letters, 105, 65 (2013)
- Li F, Zhang Y, Wu C, Lin Z, Zhang B, Guo T, Vacuum, 86, 1895 (2012)
- Lee MS, Lee K, Kim SY, Lee H, Park J, Choi KH, Kim HK, Kim DG, Lee DY, Nam SW, Park JU, Nano Lett., 13, 2814 (2013)
- Lee J, Lee P, Lee HB, Hong S, Lee I, Yeo J, Lee SS, Kim TS, Lee D, Ko SH, Adv. Funct. Mater., 23, 4171 (2013)
- Yoo D, Kim J, Kim JH, Direct synthesis of highly conductive PEDOT:PSS/graphene composites and their applications in energy harvesting systems, Nano Res., DOI: 10.1007/s12274-014-0433-z.
- Kim YK, Min DH, Langmuir, 25(19), 11302 (2009)
- De S, Lyons PE, Sorel S, Doherty EM, King PJ, Blau WJ, Nirmalraj PN, Boland JJ, Scardaci V, Joimel J, Coleman JN, ACS Nano, 3, 714 (2009)
- Ho X, Lu H, Liu W, Tey JN, Cheng CK, Kok E, Wei J, J. Mater. Res., 28, 620 (2013)