화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.20, No.3, 775-780, May, 2014
DOI10.1016/j.jiec.2013.06.006  Export Citation
Selective hydroisomerization of n-dodecane over platinum supported on SAPO-11
Eunok Lee, Soyoung Yun, Young-Kwon Park1, Soon-Yong Jeong2, Jeongsik Han3, and Jong-Ki Jeon†
  • Department of Chemical Engineering, Kongju National University, Cheonan 331-717, Republic of Korea
  • 1School of Environmental Engineering, University of Seoul, Seoul 130-743, Republic of Korea
  • 2Green Chemistry Research Division, Korea Research Institute of Chemical Technology, Daejeon 305-600, Republic of Korea
  • 3Agency for Defense Development, Yuseong, Daejeon 305-152, Republic of Korea
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Effects of loading method and amount of platinum on the hydroisomerization of n-dodecane were investigated. Platinum was supported on SAPO-11 by incipient wetness, ion exchange, or atomic layer deposition. Characterization of catalysts was carried out using N2 adsorption, XRD, NH-TPD, TPR, and pyridine-IR. The dispersion of the Pt (IE 0.2)/SAPO-11 and the Pt (ALD 0.6)/SAPO-11 are 0.65 and 0.59, respectively, which are much higher than those of the catalysts prepared by incipient wetness method. The Pt(IW)/SAPO-11 catalyst exhibited the best isomerization activity in the hydroisomerization of ndodecane, which is attributed to the highest reducibility.
Keywords:Hydroisomerization;n-Dodecane;Pt;SAPO-11;Loading method
  1. Pour AN, Housaindokht MR, Zarkesh J, Tayyari SF, J. Ind. Eng. Chem., 16(6), 1025 (2010)
  2. Atashi H, Mansouri M, Hosseini SH, Khorram M, Mirzaei AA, Karimi M, Mansouri G, Korean J. Chem. Eng., 29(3), 304 (2012)
  3. Deldari H, Appl. Catal. A: Gen., 293, 1 (2005)
  4. Seo G, Kim NH, Lee YH, Kim JH, Catal. Lett., 51(1-2), 101 (1998)
  5. Calemma V, Peratello S, Perego C, Appl. Catal. A: Gen., 190(1-2), 207 (2000)
  6. Iglesia E, Soled SL, Kramer GM, J. Catal., 144, 238 (1993)
  7. Jimenez C, Romero FJ, Roldan R, Marinas JM, Gomez JP, Appl. Catal. A: Gen., 249(1), 175 (2003)
  8. De Lucas A, Sanchez P, Funez A, Ramos M, Valverde JL, J. Mol. Catal. A-Chem., 259(1-2), 259 (2006)
  9. Liu P, Zhang XG, Yao Y, Wang J, Appl. Catal. A: Gen., 371(1-2), 142 (2009)
  10. Fan Y, Bao XJ, Shi G, Wei WS, Xu H, Appl. Catal. A: Gen., 275(1-2), 61 (2004)
  11. Wang G, Liu Q, Su W, Li X, Jiang Z, Fang X, Han C, Li C, Appl. Catal. A: Gen., 335(1), 20 (2008)
  12. Ravishankar R, Sivasanker S, Appl. Catal. A: Gen., 142(1), 47 (1996)
  13. Liu P, Ren J, Sun YH, J. Fuel Chem. Technol., 36, 610 (2008)
  14. Zhang S, Chen SL, Dong P, Ji Z, Zhao J, Xu K, Chin. J. Catal., 28, 857 (2007)
  15. Geng CH, Zhang F, Gao ZX, Zhao LF, Zhou JL, Catal. Today, 93, 485 (2004)
  16. Nawaz Z, Wei F, J. Ind. Eng. Chem., 17(3), 389 (2011)
  17. Ren XT, Li N, Cao JQ, Wang ZY, Liu SY, Xiang SH, Appl. Catal. A: Gen., 298, 144 (2006)
  18. Park KC, Ihm SK, Appl. Catal. A: Gen., 203(2), 201 (2000)
  19. Polczmann Gy, Valyon J, Szegedi A, Miha´lyi RM, Hancso´k J, Top. Catal., 54, 1079 (2011)
  20. Boudjahem AG, Redjel A, Mokrane T, J. Ind. Eng. Chem., 18(1), 303 (2012)
  21. Yang X, Ma H, Xu Z, Xu Y, Tian Z, Lin L, Catal. Commun., 8, 1232 (2007)
  22. Welters WJ, Vanderwaerden OH, Debeer VH, Vansanten RA, Ind. Eng. Chem. Res., 34(4), 1166 (1995)
  23. Hancso´k J, Kova´cs S, Polczmann Gy, Kasza T, Top. Catal., 54, 1094 (2011)
  24. Meriaudeau P, Tuan VA, Sapaly G, Nghiem VT, Naccache C, Catal. Today, 49(1-3), 285 (1999)
  25. Jeon JK, Ihm SK, Catal. Lett., 31(4), 341 (1995)
  26. Herrera JE, Kwak JH, Hu JZ, Wang Y, Peden CHF, Macht J, Iglesia E, J. Catal., 239(1), 200 (2006)
  27. Herrera JE, Kwak J, Hu J, Wang Y, Peden CHF, Top. Catal., 39, 245 (2006)
  28. Park YK, Kim SJ, You N, Cho J, Lee SJ, Lee JH, Jeon JK, J. Ind. Eng. Chem., 17(2), 186 (2011)
  29. Sakwarathorn T, Luengnaruemitchai A, Pongstabodee S, J. Ind. Eng. Chem., 17(4), 747 (2011)
  30. Park HJ, Park SH, Sohn JM, Park J, Jeon JK, Kim SS, Park YK, Bioresour. Technol., 101, 101 (2010)
  31. Lopez CM, De Sousa M, Campos Y, Hern ndez L, Garcia L, Appl. Catal. A: Gen., 258(2), 195 (2004)
  32. Castano P, Pawelec B, Fierro JLG, Arandes JM, Bilbao J, Appl. Catal. A: Gen., 315, 101 (2006)
  33. Yuvaraj S, Chang TH, Yeh CT, J. Catal., 221(2), 466 (2004)