MoO3/SiO2 catalysts for double bond migration of 2-butene

Young-Kwon Park; So Jeong Kim; Nansuk You; Jungho Cho; Seong Jun Lee; Jae Ho Lee; Jong-Ki Jeon

Journal of Industrial and Engineering Chemistry, Vol.17, No.2, 186-190, March, 2011

DOI10.1016/j.jiec.2011.02.007 Export Citation

MoO3/SiO2 catalysts for double bond migration of 2-butene

Young-Kwon Park^{1, 2}, So Jeong Kim³, Nansuk You³, Jungho Cho³, Seong Jun Lee⁴, Jae Ho Lee⁴, and Jong-Ki Jeon^{3, †}

¹Graduate School of Energy and Environmental System Engineering, University of Seoul, Seoul 130-743, Republic of Korea
²School of Environmental Engineering, University of Seoul, Seoul 130-743, Republic of Korea
³Department of Chemical Engineering, Kongju National University, Chungnam, Korea 275 Budae-dong, Seobuk-gu, Cheonan 330-717, Republic of Korea
⁴Chemicals R&D Center, SK Energy, Daejeon 305-712, Republic of Korea

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The objective of the present study is to investigate the performance of MoO3/SiO2 as a catalyst for double bond migration from 2-butene to 1-butene. The effects of MoO3 addition on catalytic properties over SiO2 were analyzed through BET surface area, XRD, ammonia-temperature programmed desorption (NH3-TPD) and FT-IR of adsorbed pyridine. The highest activity of the 10% MoO3/SiO2 catalyst in double bond migration of 2-butene can be explained by the highest number of the weak acid sites. Based on the NH3 TPD and the FT-IR of pyridine adsorption results, the increase in the overall number of acid sites can be ascribed to an increase in the number of Lewis sites by the addition of MoO3.

Keywords:2-Butene;Double bond migration;MoO3;1-Butene;Acid sites

[References]

Ko MS, Jeon JK, Cho J, Lee SJ, Lee JH, Korean Chem. Eng. Res., 46(4), 692 (2008)
Jeon JK, Lee H, Yim JH, Kim YS, Lee SJ, Park YK, Shon JK, Kim JM, Catal. Lett., 119(1-2), 179 (2007)
Lee K, Jeon JK, Hwang EH, Ko YS, Park YK, Lee SJ, Lee JH, J. Ind. Eng. Chem., 13(7), 1062 (2007)
Pavlov OS, Karsakov SA, Pavlov SY, Russ. J. Appl. Chem., 82, 1117 (2009)
Forlani F, Ancillotti O, Jover B, Resofski G, Gati G, Appl. Catal., 67, 249 (1990)
Hsing HH, US Patent 5,043,523 (1991)
Moronta A, Luengo J, Ramı´rez Y, Quino´nez J, Gonza´ lez E, Sa´nchez J, Appl. Clay Sci., 29, 117 (2005)
Powers DH, US Patent 6,768,038 (2004)
Seo G, Catal. Surv. Asia., 9, 139 (2005)
Philips Petroleum, Co., US Patent 4,217,244 (1980)
Philips Petroleum, Co., US Patent 4,289,919 (1981)
Philips Petroleum, Co., US Patent 4,409,418 (1983)
Ancillotti F, Forlani O, Jover B, Resofszki G, Gati G, Appl. Catal., 67, 249 (1991)
Texas Petrochemicals, Co., US Patent 5,043,523 (1991)
You N, Yim JH, Lee SJ, Lee JH, Park YK, Jeon JK, J. Nanosci. Nanotechnol., 7, 3800 (2007)
Equistar Chemicals, US Patent 6,758,038 (2004)
Cho J, Jeon JK, Song Y, Lee SJ, Lee JH, Korean Chem. Eng. Res., 45(4), 351 (2007)
Kim JG, J. Korean Ind. Eng. Chem., 7(5), 861 (1996)
Chai SH, Wang XP, Wang YJ, Cai TX, Chin. Chem. Lett., 14, 748 (2003)
Matsuda T, Shiro H, Sakagami H, Takahashi N, Catal. Lett., 47(2), 99 (1997)
Galadima A, Anderson JA, Wells RPK, Sci. World J., 4, 15 (2009)
Ma X, Gong J, Wang S, Gao N, Wang D, Yang X, He F, Catal. Commun., 5, 101 (2004)
Biradar AV, Umbarkar SB, Dongare MK, Appl. Catal. A: Gen., 285(1-2), 190 (2005)
Miao Y, Lu G, Liu X, Guo Y, Wang Y, Guo Y, J. Ind. Eng. Chem., 16(1), 45 (2010)
Chakraborty B, Viswanathan B, Catal. Today, 49(1-3), 253 (1999)
Palomino GT, Pascual JJC, Delgado MR, Parra JB, Arean CO, Mater. Chem. Phys., 85(1), 145 (2004)
Lundie DT, McInroy AR, Marshall R, Winfield JM, Jones P, Dudman CC, Parker SF, Mitchell C, Lennon D, J. Phys. Chem. B, 109(23), 11592 (2005)
Desikan AN, Huang L, Oyama ST, J. Phys. Chem., 95, 10050 (1991)

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[5] Forlani F, Ancillotti O, Jover B, Resofski G, Gati G, Appl. Catal., 67, 249 (1990)

[6] Hsing HH, US Patent 5,043,523 (1991)

[7] Moronta A, Luengo J, Ramı´rez Y, Quino´nez J, Gonza´ lez E, Sa´nchez J, Appl. Clay Sci., 29, 117 (2005)

[8] Powers DH, US Patent 6,768,038 (2004)

[9] Seo G, Catal. Surv. Asia., 9, 139 (2005)

[10] Philips Petroleum, Co., US Patent 4,217,244 (1980)

[11] Philips Petroleum, Co., US Patent 4,289,919 (1981)

[12] Philips Petroleum, Co., US Patent 4,409,418 (1983)

[13] Ancillotti F, Forlani O, Jover B, Resofszki G, Gati G, Appl. Catal., 67, 249 (1991)

[14] Texas Petrochemicals, Co., US Patent 5,043,523 (1991)

[15] You N, Yim JH, Lee SJ, Lee JH, Park YK, Jeon JK, J. Nanosci. Nanotechnol., 7, 3800 (2007)

[16] Equistar Chemicals, US Patent 6,758,038 (2004)

[17] Cho J, Jeon JK, Song Y, Lee SJ, Lee JH, Korean Chem. Eng. Res., 45(4), 351 (2007)

[18] Kim JG, J. Korean Ind. Eng. Chem., 7(5), 861 (1996)

[19] Chai SH, Wang XP, Wang YJ, Cai TX, Chin. Chem. Lett., 14, 748 (2003)

[20] Matsuda T, Shiro H, Sakagami H, Takahashi N, Catal. Lett., 47(2), 99 (1997)

[21] Galadima A, Anderson JA, Wells RPK, Sci. World J., 4, 15 (2009)

[22] Ma X, Gong J, Wang S, Gao N, Wang D, Yang X, He F, Catal. Commun., 5, 101 (2004)

[23] Biradar AV, Umbarkar SB, Dongare MK, Appl. Catal. A: Gen., 285(1-2), 190 (2005)

[24] Miao Y, Lu G, Liu X, Guo Y, Wang Y, Guo Y, J. Ind. Eng. Chem., 16(1), 45 (2010)

[25] Chakraborty B, Viswanathan B, Catal. Today, 49(1-3), 253 (1999)

[26] Palomino GT, Pascual JJC, Delgado MR, Parra JB, Arean CO, Mater. Chem. Phys., 85(1), 145 (2004)

[27] Lundie DT, McInroy AR, Marshall R, Winfield JM, Jones P, Dudman CC, Parker SF, Mitchell C, Lennon D, J. Phys. Chem. B, 109(23), 11592 (2005)

[28] Desikan AN, Huang L, Oyama ST, J. Phys. Chem., 95, 10050 (1991)