화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.20, No.4, 1741-1751, July, 2014
DOI10.1016/j.jiec.2013.08.026  Export Citation
Synthesis, characterization and As(III) adsorption behavior of β-cyclodextrin modified hydrous ferric oxide
Indranil Saha1, 2, Kaushik Gupta1, Sudipta Chakraborty3, Debashis Chatterjee4, and Uday Chand Ghosh1, †
  • 1Department of Chemistry and Biochemistry, Presidency University, 86/1 College Street, Kolkata, 700073, India
  • 2Department of Chemistry, Sripat Singh College, Jiaganj, Murshidabad, PIN-742123, India
  • 3Department of Chemistry, Kanchrapara College, N-24-Parganas, PIN-743145, India
  • 4Department of Chemistry (Analytical), University of Kalyani, Nadia, PIN-741235, India
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This study investigates the adsorption of As(III) on β-cyclodextrin modified hydrous ferric oxide (HCC). This is characterized by XRD, FESEM, AFM, XPS, BET, surface site concentration and FTIR. The modification of hydrous ferric oxide (HFO) surface by β-cyclodextrin provides ample -OH groups which in turn increase As(III) adsorption on HCC compared to HFO. The adsorption remains almost constant in pH range 3-8 which decreases at higher pH (>8) and followed monolayer and pseudo first order kinetics. It is spontaneous at 303 K with increasing entropy and decreasing enthalpy. Thus HCC is found to be more efficient adsorbent than HFO.
Keywords:Arsenic;Adsorption;β-cyclodextrin;Hydrous ferric oxide;Groundwater
  1. Smedley PL, Kinniburgh DG, Appl. Geochem., 17, 517 (2002)
  2. Ritchie JA, N.Z.J. Sci., 4, 218 (1961)
  3. Wang L, Chen ASC, Tong N, Coonfare CT, EPA/600/R-07/017, U.S. EPA, Water Supply and Water Resources Division, National Risk Management Research Laboratory, Cincinnati, OH, 2007.
  4. Mazumder DNG, Ghosh A, Majumdar KK, Ghosh N, Saha C, Mazumder RNG, Ind. J. Community Med., 35(2), 331 (2010)
  5. Vaughan DJ, Elements, 2, 71 (2006)
  6. Biswas BK, Dhar RK, Samanta G, Mandal BK, Faruk I, Islam KS, Chowdhury MM, Islam A, Roy S, Chakraborti D, Curr. Sci., 74(2), 134 (1998)
  7. Chakraborti D, Rahman MM, Paul K, Chowdhury UK, Sengupta MK, Lodh D, Chanda CR, Saha KC, Mukherjee SC, Talanta, 58, 2002 (3)
  8. De Chaudhuri SP, Ghosh N, Sarma P, Majumdar TJ, Sau S, Roychoudhury S, Basu K, Giri AK, Environ. Health Persp., 116, 501 (2008)
  9. Bhattacharya P, Chatterjee D, Jacks G, Water Resour. Res., 13, 79 (1997)
  10. Chowdhury UK, Rahman MM, Mondal BK, Paul K, Lodh D, Biswas BK, Basu GK, Chanda CR, Saha KC, Mukherjee SC, Roy S, Das R, Kaies I, Barua AK, Palit SK, Quamruzzaman Q, Chakraborti D, Environ. Sci., 8(5), 393 (2001)
  11. Akter K, Naidu R, in: Naidu R, Smith E, Owens G, et al. (Eds.), Arsenic Speciation in the Environment, in Managing Arsenic in the Environment: From Soil to Human health, CSIRO Publishing, Collingwood, 2009, p. 61.
  12. Ferguson JF, Davis J, Water Res., 6, 1259 (1972)
  13. Cullen WR, Reimer KJ, Chem. Rev., 89, 713 (1989)
  14. Jain CK, Ali I, Water Res., 34(17), 4304 (2000)
  15. Masscheleyn PH, Delaune RD, Patrick WH, Environ. Sci. Technol., 25, 1414 (1991)
  16. Gulledge JH, O’Connor JT, J. Am. Water Works Ass., 65, 548 (1973)
  17. Pierce ML, Moore CB, Water Res., 16(7), 1247 (1982)
  18. Wilkie JA, Hering JG, Colloids Surf. A: Physicochem. Eng. Asp., 107, 97 (1996)
  19. Dixit S, Hering JG, Environ. Sci. Technol., 37, 4182 (2003)
  20. Manna BR, Dey S, Debnath S, Ghosh UC, Water Qual. Res. J. Can., 38(1), 193 (2003)
  21. Ghosh UC, Bandhyapadhyay D, Manna B, Mandal B, Water Qual. Res. J. Can., 41(2), 198 (2006)
  22. Gupta K, Biswas K, Ghosh UC, Ind. Eng. Chem. Res., 47(24), 9903 (2008)
  23. Singh R, Bharti N, Madan J, Hiremath SN, J. Pharm. Sci. Technol., 2(3), 171 (2010)
  24. Loftsson T, Duchene D, Int. J. Pharm., 329(1-2), 1 (2007)
  25. Szejtli J, Starch, 34(11), 379 (1982)
  26. Inoue Y, Hakushi T, Liu Y, Tong LH, Shen BJ, Jin DS, J. Am. Chem. Soc., 115, 475 (1993)
  27. Patel VP, Patel NM, Iran. J. Pharm. Sci., 5(4), 191 (2009)
  28. Norkus E, J. Incl. Phenom. Macro., 65, 237 (2009)
  29. Bonacchia D, Caneschia A, Gatteschia D, Sangregorioa C, Sessolia R, Falqui A, J. Phys. Chem. Solids, 65, 719 (2004)
  30. Badruddoza AZM, Tay ASH, Tan PY, Hidajat K, Uddin MS, J. Hazard. Mater., 185(2-3), 1177 (2011)
  31. Cooper RJ, Camp PJ, Gordon RJ, Henderson DK, Henry DC, McNab H, De Silva SS, Tackley D, Tasker PA, Wight P, Dalton Trans., 23, 2785 (2006)
  32. Bibby A, Mercier L, Green Chem., 5, 15 (2003)
  33. Wang X, Brusseau ML, Environ. Sci. Technol., 29, 2632 (1995)
  34. Badruddoza A, Hazel GSS, Hidajat K, Uddin MS, Colloids Surf. A: Physicochem. Eng. Asp., 367, 85 (2010)
  35. Clesceri LS, Greenberg AE, Eaton AD, Standard Methods for the Examination of Water and Wastewater, 20th edition, American Public Health Association (APHA), American Water Works Association (AWWA), Water Environment Federation (WEF), Washington, DC, 1998p. 4.
  36. Babic MB, Milonjic MJ, Kaludierovic BV, Carbon, 37, 477 (1999)
  37. Mayant C, Grambow B, Abdelouas A, Ribet S, Leclercq S, Phys. Chem. Earth, 33, 991 (2008)
  38. Wang Z, Wei H, Ji L, Xu L, Zou C, Xie J, Transfus. Apher. Sci., 47(2), 159 (2012)
  39. Caddeo C, Manconi M, Valenti D, Pini E, Sinico C, J. Incl. Phenom. Macro., 59, 293 (2007)
  40. Beloshe SP, Chougule DD, Shah RR, Ghodke DS, Pawar ND, Ghaste RP, Asian J. Pharm. Sci., 4, 168 (2010)
  41. Nakamoto K, Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part B: Applications in Coordination, Organometallic, and Bioinorganic Chemistry, 6th edition, Wiley Publications, 2008.
  42. Uyar T, Havelund R, Nur Y, Hacaloglu J, Besenbacher F, Kingshott P, J. Membr. Sci., 332(1-2), 129 (2009)
  43. Wilson LD, Mohamed MH, Berhaut CL, Materials, 4, 1528 (2011)
  44. Ponchel A, Abramson S, Quartararo J, Bormann D, Barbaux Y, Monflier E, Microporous Mesoporous Mater., 75, 261 (2004)
  45. Ankomah AB, Clay Clay Min., 39, 100 (1991)
  46. Arnold PW, Surface-electrolyte interactions, in: Greenland DJ, Hayes MHB (Eds.), The Chemistry of Soil Constituents, Wiley Publications, Chichester, 1978, p. 355.
  47. Gupta K, Maity A, Ghosh UC, J. Hazard. Mater., 184(1-3), 832 (2010)
  48. Singh TS, Pant KK, Sep. Purif. Technol., 36(2), 139 (2004)
  49. Lagergren S, Zur theorie der sogenannten adsorption geloster stoffe K Sven Ventenskapsakad Handl. 24 (1898) 1.
  50. Ho YS, Adsorption, 10, 151 (2004)
  51. Pokhrel D, Viraraghavan T, J. Hazard. Mater., 150, 818 (2008)
  52. Gupta K, Ghosh UC, J. Hazard. Mater., 161(2-3), 884 (2009)
  53. Manna BR, Dasgupta M, Ghosh UC, J. Water SRT-Aqua, 53, 483 (2004)
  54. Kanel SR, Manning B, Charlet L, Choi H, Environ. Sci. Technol., 39, 1291 (2005)
  55. Yuan C, Lien HL, Water Qual. Res. J. Can., 41(2), 210 (2006)
  56. Thomas WJ, Crittenden B, Adsorption Technology and Design, Butterworth-Heinemann, Oxford, UK, 1998.
  57. Vaishya RC, Gupta SK, J. Chem. Technol. Biotechnol., 78, 73 (2002)
  58. Krishna BS, Murty DSR, Prakash BSJ, J. Colloid Interface Sci., 229(1), 230 (2000)
  59. Atkins P, de Paula J, Atkins’ Physical Chemistry, 8th edition, Oxford University Press, 2006.