Herein, we introduce a modification of the sulfur electrode by electrodepositing a covering layer of polyaniline nanowires at the top end for Li-S batteries. The as-fabricated electrodes are evaluated via SEM, FTIR, EDAX, EIS, CV and charge-discharge tests. The SEM images combined with FTIR spectra show that the surface of the electrode is covered by the PANI nanowires. The charge-discharge tests of PANI5 display the best cyclic performance, delivering the initial discharge capacity of 1304 mAh g(-1), and 725 mAh g(-1) after 100 cycles at the current density of 320 mAg(-1). The CV results of the PANI-5 present an overlapping of cathodic/anodic peaks, indicating that the suitable mass of PANI coating can increase the reversibility of the electrode. SEM combined with EDAX tests of the electrodes after cycles show that the sulfur species are trapped by the PANI nanowires. These results demonstrate that the PANI covering layer plays a barrier to restrain the dissolution of the polysulfides, and provide spaces as well as conductive media for sulfur species. (C) 2013 Elsevier B.V. All rights reserved.