Core-shell structured poly(methyl methacrylate)-coated zirconium dioxide nanoparticle and its dispersion stability

Min Ji Kim; Hyun Sik Chae; Hyoung Jin Choi

Journal of Industrial and Engineering Chemistry, Vol.21, 145-150, January, 2015

DOI10.1016/j.jiec.2014.03.028 Export Citation

Core-shell structured poly(methyl methacrylate)-coated zirconium dioxide nanoparticle and its dispersion stability

Min Ji Kim, Hyun Sik Chae, and Hyoung Jin Choi^†

Department of Polymer Science and Engineering, Inha University, Incheon 402-751, Republic of Korea

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To improve dispersion stability of ZrO2 nanoparticles dispersed in a poly(4-vinylphenol-co-methyl methacrylate) (PVP-co-PMMA)/2-methoxyethanol solution, they were coated with poly(methyl methacrylate) (PMMA) by dispersion polymerization. Cross-linked PMMA-coated ZrO2 particles were characterized by SEM and TEM. Chemical composition was examined by FT-IR spectroscopy. Mass ratio of PMMA to the ZrO2 was analyzed by TGA. Density (1.97 g/cm3) of the PMMA coated ZrO2 particles was much lowered compared to 5.46 g/cm3 of ZrO2, and the improved dispersion stability of the coated particles in the PVP-co-PMMA/2-methoxyethanol solution was demonstrated using a Turbiscan.

Keywords:Core-shell structure;Dispersion stability;Organic-inorganic nanocomposite

[References]

Hoffmann F, Cornelius M, Morell J, Froba M, Angew. Chem. Int. Ed., 45, 3216 (2006)
Prusty G, Swain SK, Mater. Sci. Semicond. Process., 16, 2039 (2013)
Park HY, Schadt MJ, Wang L, Lim IIS, Njoki PN, Kim SH, Jang MY, Luo J, Zhong CJ, Langmuir, 23(17), 9050 (2007)
Zheng W, Wong SC, Compos. Sci. Technol., 63, 225 (2003)
Haas U, Haase A, Satzinger V, Pichler H, Leising G, Jakopic G, Stadlober B, Houbertz R, Domann G, Schmitt A, Phys. Rev. B: Condens. Matter, 73, 235339 (2006)
Liu YD, Zhang K, Zhang WL, Choi HJ, Aust. J. Chem., 65, 1195 (2012)
Jung T, Dodabalapur A, Wenz R, Mohapatra S, Appl. Phys. Lett., 87, 182109 (2005)
Roberts ME, Queralto N, Mannsfeld SCB, Reinecke BN, Knoll W, Bao ZN, Chem. Mater., 21, 2292 (2009)
Kwon JH, Chung MH, Oh TY, Bae HS, Park JH, Ju BK, Yakuphanoglu F, Sens. Actuators, A: Phys., 156, 312 (2009)
Rahulan KM, Vinitha G, Stephen LD, Kanakam CC, Ceram. Int., 39, 5281 (2013)
Klauk H, Halik M, Zschieschang U, Schmid G, Radlik W, Weber W, J. Appl. Phys., 92, 5259 (2002)
Jiang L, Zhang J, Gamota D, Takoudis CG, Org. Electron., 11, 959 (2010)
Park BJ, Sung JH, Park JH, Choi JS, Choi HJ, J. Nanosci. Nanotechnol, 8, 2676 (2008)
Buron H, Mengual O, Meunier G, Cayre I, Snabre P, Polym. Int., 53, 1205 (2004)
Lee J, Hong CK, Choe S, Shim SE, J. Colloid Interface Sci., 310(1), 112 (2007)
Lee KH, Park BJ, Choi HJ, Park J, Choi JS, Mol. Cryst. Liq. Cryst., 471, 173 (2007)
Liu GY, Yang XL, Wang YM, Polymer, 48(15), 4385 (2007)
Yu DG, An JH, Bae JY, Kim S, Lee YE, Ahn SD, Kang SY, Suh KS, Colloids Surf., A: Physicochem. Eng. Aspects, 245, 29 (2004)
Liu YD, Fang FF, Choi HJ, Colloid. Polym. Sci., 289, 1295 (2011)
Kim YJ, Liu YD, Seo Y, Choi HJ, Langmuir, 29(16), 4959 (2013)
Sahoo BK, Dea S, Carsky M, Meikap BC, J. Ind. Eng. Chem., 17(1), 62 (2011)

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[3] Park HY, Schadt MJ, Wang L, Lim IIS, Njoki PN, Kim SH, Jang MY, Luo J, Zhong CJ, Langmuir, 23(17), 9050 (2007)

[4] Zheng W, Wong SC, Compos. Sci. Technol., 63, 225 (2003)

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