화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.21, 760-767, January, 2015
DOI10.1016/j.jiec.2014.04.009  Export Citation
Local, cheep and nontoxic activated carbon as efficient adsorbent for the simultaneous removal of cadmium ions and malachite green: Optimization by surface response methodology
S. Hajati†, M. Ghaedi1, †, and S. Yaghoubi1
  • Department of Physics, Yasouj University, Yasouj 75918-74831, Iran
  • 1Chemistry Department, Yasouj University, Yasouj 75918-74831, Iran
E-mail:,
The focus of present study is on the optimization of variables influencing the simultaneous removal of Cd2+ ion and malachite green (MG) from aqueous solution by activated carbon (AC).The AC was prepared from oak wood and then it was characterized using different techniques such as SEM, BET, FT-IR and Boehm titration. The effects of variables such as pH, initial dye concentration, cadmium ion concentration, adsorbent mass (g) and contact time on the adsorption of Cd2+ ion and MG were examined by central composite design (CCD). The experimental data for single solution of either of Cd2+ ion and MG followed the Langmuir model. The adsorption of Cd2+ ion in binary mixture followed the Freundlich model. The rate of adsorption and mass transfer kinetics exactly can be elucidated by pseudo second order model.
Keywords:Malachite green;Activated carbon;Kinetics and isotherm study;Cadmium(II) ions;Central composite design
  1. Mass R, Chaudhari S, Process Biochem., 40, 699 (2005)
  2. Visa M, Duta A, J. Hazard. Mater., 244-245, 773 (2013)
  3. Shen DZ, Fan JX, Zhou WZ, Gao BY, Yue QY, Kang Q, J. Hazard. Mater., 172(1), 99 (2009)
  4. Saygi KO, Tuzen M, Soylak M, Elci L, J. Hazard. Mater., 153(3), 1009 (2008)
  5. Narin I, Soylak M, Kayakirilmaz K, Elci L, Dogan M, Anal. Lett., 36, 641 (2003)
  6. Serencam H, Gundogdu A, Uygur Y, Kemer B, Bulut VN, Duran C, Soylak M, Tufekci M, Bioresour. Technol., 99(6), 1992 (2008)
  7. Narin I, Soylak M, Elci L, Dogan M, Talanta, 52, 1041 (2000)
  8. Bernard A, Indian J. Med. Res., 128, 557 (2008)
  9. Ghaedi M, Hajati S, Barazesh B, Karimi F, Ghezelbash G, J. Ind. Eng. Chem., 19(1), 227 (2013)
  10. Ghaedi M, Hajati S, Karimi F, Barazesh B, Ghezelbash G, J. Ind. Eng. Chem., 19(3), 987 (2013)
  11. Sari A, Mendil D, Tuzen M, Soylak M, J. Hazard. Mater., 162(2-3), 874 (2009)
  12. Sari A, Tuzen M, J. Hazard. Mater., 160(2-3), 349 (2008)
  13. Sari A, Mendil D, Tuzen M, Soylak M, Chem. Eng. J., 144(1), 1 (2008)
  14. Uluozlu OD, Sari A, Tuzen M, Soylak M, Bioresour. Technol., 99(8), 2972 (2008)
  15. Anayurt RA, Sari A, Tuzen M, Chem. Eng. J., 151(1-3), 255 (2009)
  16. Sari A, Tuzen M, J. Hazard. Mater., 164(2-3), 1004 (2009)
  17. Labanda J, Sabate J, Llorens J, Chem. Eng. J., 166(2), 536 (2011)
  18. Turabik M, J. Hazard. Mater., 158(1), 52 (2008)
  19. Martin MJ, Artola A, Balaguer MD, Rigola M, Chem. Eng. J., 94(3), 231 (2003)
  20. Chingombe P, Saha B, Wakeman RJ, Carbon, 43, 3132 (2005)
  21. Ghaedi M, Pakniat M, Mahmoudi Z, Hajati S, Sahraei R, Daneshfar A, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 123, 402 (2014)
  22. Depci T, Kul AR, Onal Y, Chem. Eng. J., 200-202, 224 (2012)
  23. Xue YJ, Hou HB, Zhu SJ, Chem. Eng. J., 147(2-3), 272 (2009)
  24. Ghaedi M, Ansari A, Habibi MH, Habibi AR, J. Ind. Eng. Chem., 20(1), 17 (2014)
  25. Ghead M, Tavallali H, Sharifi M, Kokhdan SN, Asghari A, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 86, 107 (2012)
  26. Roosta M, Ghaedi M, Daneshfar A, Sahraei R, Asghari A, Ultrason. Sonochem., 21, 242 (2014)
  27. Auta M, Hameed BH, Chem. Eng. J., 175, 233 (2011)
  28. Roosta M, Ghaedi M, Shokri N, Daneshfar A, Sahraei R, Asghari A, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr., 118, 55 (2014)
  29. Wong KK, Lee CK, Low KS, Haron MJ, Process Biochem., 39, 437 (2003)
  30. Mopoung S, Nogklai W, Int. J. Phys. Sci., 3, 234 (2008)
  31. Langmuir I, J. Am. Chem. Soc., 40, 1361 (1918)
  32. Freundlich HMF, Z. Phys. Chem., 57, 385 (1906)
  33. Hajati S, Ghaedi M, Karimi F, Barazesh B, Sahraei R, Daneshfar A, J. Ind. Eng. Chem., 20(2), 564 (2014)
  34. Hajati S, Ghaedi M, Barazesh B, Karimi F, Sahraei R, Daneshfar A, Asghari A, J. Ind. Eng. Chem., http://dx.doi.org/10.1016/j.jiec.2013.10.022 (2013)
  35. Ghaedi M, Biyareh MN, Kokhdan SN, Shamsaldini S, Sahraei R, Daneshfar A, Shahriyar S, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 32, 725 (2012)
  36. Srivastava VC, Mall ID, Mishra IM, Colloids Surf. A: Physicochem. Eng. Asp., 312, 172 (2008)
  37. Wang S, Ariyanto E, J. Colloid Interface Sci., 314(1), 25 (2007)
  38. Tovar-Gomez R, Rivera-Ramirez DA, Hernandez-Montoya V, Bonilla-Petriciolet A, Duran-Valle CJ, Montes-Moran MA, J. Hazard. Mater., 199, 290 (2012)
  39. Gupta VK, Srivastava SK, Mohan D, Ind. Eng. Chem. Res., 36(6), 2207 (1997)
  40. Visa M, Bogatu C, Duta A, Appl. Surf. Sci., 256(17), 5486 (2010)