Ni-18%W 코팅의 고온산화막 분석

고재황; 이동복; J.H. Ko; D. B. Lee

Korean Journal of Materials Research, Vol.14, No.4, 281-286, April, 2004

DOI10.3740/MRSK.2004.14.4.281 Export Citation

Ni-18%W 코팅의 고온산화막 분석

aracterization of High Temperature Oxide Scales formed on Ni-18%W Coatings

고재황, 이동복^†

성균관대학교 신소재공학과

J.H. Ko, and D. B. Lee^†

Department of Advanced Materials & Engineering, Sungkyunkwan University, 300 Chungchun-dong, Jangan-gu, Suwon 440-746, South Korea

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The oxide scales formed on Ni-18W(at.%) coating that was electrodeposited on steel were investigated using XRD, SEM and TEM. The oxide scales consisted mainly of an outer NiO layer, and an inner thick ( NiWO 4 +NiO) mixed layer. The unoxidized coating below the oxide scale was rich in Ni and depleted in W, owing to the consumption of Wand the resultant Ni enrichment. The oxidation resistance of Ni-18W coating was poorer than that of the TiN coating, due to the formation of nonprotective NiWO 4 . During oxidation, Ni and the substrate element of Fe diffused outward, while oxygen inward, according to the concentration gradients.

Keywords:Coating;Oxidation;Nickel;Tungsten

[References]

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[1] Lee SK, Yoo HR, Jang SS, Hwang WS, J. Corros. Sci. Korea, 30, 164 (2001)

[2] Lee SK, Moon JY, Yoo HR, Jang SS, Hwang WS, J. Corros. Sci. Korea, 30, 156 (2001)

[3] Yamasaki T, Schlossmacher P, Enrlich K, Ogino Y, NanoStructured Materials, 10, 375 (1998)

[4] Louro C, Cavaleiro A, J. Electrochem. Soc., 144(1), 259 (1997)

[5] Louro C, Cavaleiro A, Surf. Coat. Tech., 116-119, 121 (1999)

[6] Panjan P, Navinsek B, Cvelbar A, Zalar A, Milosev I, Thin Solid Films, 281-282, 298 (1996)

[7] Ichimura H, Kawana A, J. Mater. Res., 9, 15 (1994)

[8] Lee DB, Kim MH, Lee YC, Kwon SK, Surf. Coat. Tech., 141, 232 (2001)

[9] Jones DA, Principle and Prevention of Corrosion, 2nd. ed., Prentice-Hall 416 (1996) (1996)