We previously reported that trapezoid, plate like and mono- or bi-tetrahedral Ag-flag structures arc evolved horn side facets of Ag-nanorod (NR) seeds when AgNO3 was reduced in N,N-dimethylformamide (DMF) in the presence of polyvinylpyrrolidone (PVP). In this study, we examined what shapes are grown by further growth of bitetrahedral flags based on TEM and SEM observations. For this purpose, we initially studied effects of the reaction temperature, concentrations of PVP, and molecular weights of PVP for the shape evolution of flag types of Ag nanostructures from Ag-NR seeds. Results show that shape and size of flags can be controlled by changing these parameters and reaction times. Under an appropriate experimental condition, we found that decahedral and icosahedral flags and their intermediates having {1 1 1} facets were finally grown by stepwise growth of tetrahedral units, although yield of perfect decahedral and icosahedral flags were low because of occurrence of homogenous nucleation at high AgNO3 concentration. (C) 2014 Elsevier B.V. All rights reserved.