A simple but efficient microwave assisted method with high yield products was applied to synthesize regular hexagon Bi2Te3 nanosheets. Rhombohedral Bi2Te3 with pure single crystalline phase was demonstrated by XRD pattems, HRTEM images, and SAED figures. The SEM and TEM images showed that the Bi2Te3 nanosheets were uniform, and that the average lengths of the hexagon sides were approximately 320 nm. The growth mechanisms and morphological transformations were systematically studied by controlling the reaction time, KOH concentration, and polyvinylpyrrolidone (PVP) dosage. This work has indicated that abundant KOH benefited the formation of uniform Bi2Te3 nanosheets without Te nanorods. Meanwhile, long reaction time and abundant PVP favored the formation of regular hexagon nanosheets with smooth surfaces. (C) 2014 Elsevier B.V. All rights reserved.