Hydrothermal synthesis of different morphologies of MgFe2O4 and magnetic cellulose acetate nanocomposite

Davood Ghanbari; Masoud Salavati-Niasari

Korean Journal of Chemical Engineering, Vol.32, No.5, 903-910, May, 2015

DOI10.1007/s11814-014-0306-x Export Citation

Hydrothermal synthesis of different morphologies of MgFe2O4 and magnetic cellulose acetate nanocomposite

Davood Ghanbari, and Masoud Salavati-Niasari^†

Institute of Nano Science and Nano Technology, University of Kashan, Kashan, P. O. Box 87317-51167, Iran, Korea

E-mail:

MgFe2O4 nanostructures were synthesized via a facile hydrothermal reaction. The effect of various surfactants such as cationic, anionic and polymeric on the morphology of the product was investigated. Magnetic nanoparticles were added to cellulose acetate (CA) to make magnetic nanocomposite. Nanoparticles appropriately enhanced flame retardant property of the CA matrix. Application of the most conventional flame retardants is limited with respect to the environmental requirements. The most important novelty of this work is the preparation of a nontoxic magnetic and flame retardant cellulose acetate nanocomposite. Dispersed nanoparticles play the role of a magnetic barrier layer, which slows down product volatilization and prevents flame and oxygen from reaching the sample during decomposition of the polymer. In the presence of flame, magnetic nanoparticles remain together (show resistance to drop falling) and build a barrier. Also, distribution of the magnetic nanoparticles into cellulose acetate matrix increases the coercivity.

Keywords:Nanoparticles;Magnetic;Nanocomposite;Flame Retardancy

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[2] Pullar RC, Bdikin IK, Bhattacharya AK, J. Eur. Ceram. Soc., 32, 905 (2012)

[3] Ghanbari D, Salavati-Niasari M, Ghasemi-Kooch M, J. Ind. Eng. Chem., 20(6), 3970 (2014)

[4] Cernea M, Sandu SG, Galassi C, Radu R, Kuncser V, J. Alloys Compd., 561, 121 (2013)

[5] Lisjak D, Drofenik M, J. Eur. Ceram. Soc., 26, 3681 (2006)

[6] Topal U, Ozkan H, Sozeri H, J. Magn. Magn. Mater., 284, 416 (2004)

[7] Verma S, Joy PA, Khollam YB, Potdar HS, Deshpande SB, Mater. Lett., 58, 1092 (2004)

[8] Shen Y, Wu Y, Li X, Zhao Q, Hou Y, Mater. Lett., 96, 85 (2013)

[9] Huang YJ, Tang Y, Wang J, Chen QW, Mater. Chem. Phys., 97(2-3), 394 (2006)

[10] Gong C, Bai YJ, Qi YX, Lun N, Feng J, Electrochim. Acta, 90, 119 (2013)

[11] Durmus Z, Unal B, Toprak MS, Aslan A, Baykal A, Phys. B., 406, 2298 (2011)

[12] Unal B, Durmus Z, Baykal A, Toprak MS, Sozeri H, Bozkurt A, J. Alloy Compd., 509, 8199 (2011)

[13] Durmus Z, Kavas H, Sozeri H, Toprak MS, Aslan A, Baykal A, J. Supercond. Nov. Magn., 25, 1185 (2012)

[14] Gholamian F, Salavati-Niasari M, Ghanbari D, Sabet M, J. Clust. Sci., 24, 73 (2013)

[15] Jamshidi P, Ghanbari D, Salavati-Niasari M, J. Ind. Eng. Chem., 20(5), 3507 (2014)

[16] Yousefi M, Noori E, Ghanbari D, Salavati-Niasari M, Gholami T, J. Clust. Sci., 25, 397 (2014)

[17] Ghanbari D, Salavati-Niasari M, Sabet M, Compos. Part B Eng., 45, 550 (2013)

[18] Sobhani A, Salavati-Niasari M, Mater. Res. Bull., 53, 7 (2014)

[19] Sobhani A, Salavati-Niasari M, Superlattice Microstruct., 65, 79 (2014)

[20] Sobhani A, Salavati-Niasari M, Mater. Res. Bull., 48(9), 3204 (2013)

[21] Ghanbari D, Salavati-Niasari M, J. Ind. Eng. Chem., In Press (2014)