화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.23, 321-327, March, 2015
DOI10.1016/j.jiec.2014.08.036  Export Citation
Performance of Au/FeOx-TiO2 catalyst for liquid phase selective hydrogenation of phthalic anhydride to phthalide
Yingxin Liu†, Zuojun Wei1, Tiefeng Xing, Meng Lu, and Xiaonian Li2, †
  • Research and Development Base of Catalytic Hydrogenation, College of Pharmaceutical Science, Zhejiang University of Technology, Hangzhou 310014, China
  • 1Key Laboratory of Biomass Chemical Engineering of Ministry of Education, Department of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China
  • 2Institute of Industrial Catalysis, College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, China
E-mail:,
Gold catalysts supported on FeOx-TiO2 with various Fe2O3 contents were prepared by deposition-precipitation method and used for phthalic anhydride hydrogenation to phthalide. The effect of Fe2O3 on the physico-chemical property and the performance of Au/TiO2 were investigated. The reaction conditions were optimized. Adding 5 wt.% Fe2O3 on Au/TiO2 could enhance the activity and stability, which was contributed to the increase in the strength of the catalyst structure and the decrease in the loss of gold from catalyst. Using Au/5%FeOx-TiO2, phthalic anhydride conversion and phthalide selectivity reached 95.4% and 94.5%, respectively, at 190 °C and 3.0 MPa H2 for 7 h.
Keywords:Au/FeOx-TiO2 catalyst;Phthalic anhydride;Liquid phase selective hydrogenation;Phthalide
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