Extraction of natural dye from Gardenia and chromaticity analysis according to chi parameter

In Kwon Hong; Hyeon Jeon; Seung Bum Lee

Journal of Industrial and Engineering Chemistry, Vol.24, 326-332, April, 2015

DOI10.1016/j.jiec.2014.10.004 Export Citation

Extraction of natural dye from Gardenia and chromaticity analysis according to chi parameter

In Kwon Hong , Hyeon Jeon, and Seung Bum Lee^†

Department of Chemical Engineering, Dankook University, Yongin-si 448-701, Gyeonggi-do, Republic of Korea

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Various methods of extracting natural dyes have been studied because of the increase of eco-friendly, non-toxic natural dyes. In this study, the natural dyes extraction process was optimized using Gardenia jasminoides Ellis containing crocin. Hansen solubility parameter values and chi parameter values (χ12)(χ12) of various organic solvents and crocin were calculated, and the extracted pigments were analyzed by experiments. Comparing to calculated values and analyzed values, the relevancy was found and the solvents yielding color close to the target color were selected. Four kinds of solvents (methanol, ethanol, 1-propanol, and 2-propanol) having color close to the target color were selected because their χ12χ12 values were small and their Hansen solubility parameter values were similar to the Hansen solubility parameter value of crocin. These selected solvents were each mixed with distilled water at various volume ratios, and the extraction process was conducted. The results showed that L,a,bL,a,b values closest to the target color were obtained when using 40?60 vol% of the solvents. Also, trends of χ12χ12 values and the color difference View the MathML source(ΔE*) values were well matched up with UV absorbance.

Keywords:Chromaticity;Crocin;Solubility parameter;Chi parameter;UV absorbance

[References]

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Tseng TH, Chu CY, Huang JM, Shiow, Wang CJ, Cancer Lett., 97(1), 61 (1995)
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[9] Kok A, Lichenologist, 3, 248 (1966)

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[11] Ali S, Hussain T, Nawaz R, Hournal Cleaner Prod., 17(1), 61 (2009)

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[16] Calsteren MRV, Bissonnette MC, Cormier F, Dufresne C, Ichi T, Leblanc JCY, Perreault D, Roewer I, J. Agric. Food Chem., 45(4), 1055 (1997)

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[18] He SY, Qian ZY, Tang FT, Wen NG, Xu L, Sheng L, Life Sci., 77(8), 907 (2005)

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[23] Tseng TH, Chu CY, Huang JM, Shiow, Wang CJ, Cancer Lett., 97(1), 61 (1995)

[24] Chen Y, Zhang H, Tian X, Zhao C, Cai L, Liu Y, Jia L, Yin HX, Chen C, Food Chem., 109(3), 484 (2008)

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[27] Park KA, Lee HJ, Hong IK, J. Ind. Eng. Chem., 16(3), 490 (2010)

[28] Vankar PS, Resonance, 5(10), 74 (2000)

[29] Hansen CM, Hansen Solubility Parameter: A User Hand Book, second ed., CRC Press, Boca Raton, New York, 2007.

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[31] Siwawej S, Jarayapun A, Kasetsart J.: Nat. Sci., 32, 520 (1998)

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