화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.27, 297-306, July, 2015
DOI10.1016/j.jiec.2015.01.004  Export Citation
Highly selective Me-ZSM-5 catalyst for methanol to propylene (MTP)
Mohammad Rostamizadeh1, 2, †, and Abbas Taeb1, 3
  • 1Faculty of Chemical Engineering, Iran University of Science and Technology (IUST), Narmak, Tehran, Iran
  • 2Chemical Engineering Department, Ecole Polytechique of Montreal, Canada
  • 3, Iran
E-mail:
Methanol dehydration over ZSM-5 catalyst produces propylene and varied hydrocarbons. We synthesized high silica HZSM-5 catalyst (Si/Al = 200) and impregnated with different promoters (P, Mn, Mg and Cs). SEM, XRD, BET, FTIR and NH3-TPD techniques characterized the catalysts. The parent catalyst is stable during the impregnation and the modified catalysts include high crystallinity (>92%) and BET surface area (>303 m2/g). Mn incorporation adjusts the acidity better (strong/weak ratio = 1). Mn-ZSM-5 and P-ZSM-5 catalysts represent the highest methanol conversion (100%) and long term life time (120 h) as well as the parent catalyst. Mn-ZSM-5 catalyst represents the highest reported propylene selectivity (58.4%) over ZSM-5 catalyst in the methanol to propylene (MTP) reaction. The developed catalyst has high potential to apply in the industrial scale MTP process.
Keywords:ZSM-5;Catalyst;Propylene;Methanol;Selectivity
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