Vapor-liquid equilibria for the binary mixtures of dimethyl ether (DME)+dimethyl carbonate (DMC)

Wan Ju Jeong; Jong Sung Lim

Korean Journal of Chemical Engineering, Vol.33, No.1, 248-254, January, 2016

DOI10.1007/s11814-015-0129-4 Export Citation

Vapor-liquid equilibria for the binary mixtures of dimethyl ether (DME)+dimethyl carbonate (DMC)

Wan Ju Jeong, and Jong Sung Lim^†

Department of Chemical and Biomolecular Engineering, Sogang University, C. P. O. Box 1142, Seoul 100-611, Korea

E-mail:

Isothermal vapor-liquid equilibrium data for the binary system of dimethyl ether (DME)+dimethyl carbonate (DMC) were measured at 303.15, 313.15, 323.15, 333.15 and 343.15 K using a circulation-type equilibrium apparatus with on-line gas chromatography analysis. The experimental data were correlated with the Peng-Robinson equation of state (PR-EoS) using the van der Waals one fluid mixing rule and the Peng-Robinson equation of state (PR-EoS) using the Wong-Sandler mixing rule combined with the NRTL excess Gibbs free energy model. This system showed negative deviation from Raoult’s law, and no azeotropic behavior was observed for all the temperature ranges studied here. Calculated results with PR-EoS using both two mixing rules showed good agreement with experimental data.

Keywords:Vapor Liquid Equilibria;Dimethyl Ether (DME);Dimethyl Carbonate (DMC);Peng-Robinson Equation of State (PR-EoS)

[References]

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Fang SN, Fujimoto K, Appl. Catal. A: Gen., 142(1), L1 (1996)
Li CF, Zhong SH, Catal. Today, 82(1-4), 83 (2003)
Hong ST, Park HS, Lim JS, Lee YW, Anpo M, Kim JD, Res. Chem. Intermed., 32, 737 (2006)
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Almusaiteer K, Catal. Commun., 10, 1127 (2009)
Tomishige K, Kunimori K, Appl. Catal. A: Gen., 237(1-2), 103 (2002)
Kim SA, Yim JH, Byun HS, Lim JS, Korean J. Chem. Eng., 28(12), 2324 (2011)
Lee MH, Yim JH, Kang JW, Lim JS, Fluid Phase Equilib., 318, 77 (2012)
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Cho H, Yim JH, Lim JS, J. Supercrit. Fluids, 81, 7 (2013)
Cho H, Kim JE, Lim JS, Fluid Phase Equilib., 379, 52 (2014)
Peng DY, Robinson DB, Ind. Eng. Chem. Fundam., 15, 59 (1976)
Shibata SK, Sandler SI, Ind. Eng. Chem. Res., 28, 1893 (1989)
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[Referenced By]

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[2] Ono Y, Appl. Catal. A: Gen., 155(2), 133 (1997)

[3] Pacheco MA, Marshall CL, Energy Fuels, 11(1), 2 (1997)

[4] Ono Y, Catal. Today, 35(1-2), 15 (1997)

[5] Shaikh AA, Sivaram S, Chem. Rev., 96(3), 951 (1996)

[6] Ein-Eli Y, Electrochem. Commun., 4, 644 (2002)

[7] Delledonne D, Rivetti F, Romano U, Appl. Catal. A: Gen., 221(1-2), 241 (2001)

[8] Romano U, Tesel R, Mauri MM, Ind. Eng. Chem. Prod. Res. Dev., 19, 396 (1980)

[9] Matsuzaki T, Nakamura A, Catal. Surv. Asia, 1, 77 (1997)

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[11] Li CF, Zhong SH, Catal. Today, 82(1-4), 83 (2003)

[12] Hong ST, Park HS, Lim JS, Lee YW, Anpo M, Kim JD, Res. Chem. Intermed., 32, 737 (2006)

[13] Hong ST, Park HS, Lim JS, Yoo KP, Korean Chem. Eng. Res., 46(3), 550 (2008)

[14] Tomishige K, Sakaihori T, Ikeda Y, Fujimoto K, Catal. Lett., 58(4), 225 (1999)

[15] Almusaiteer K, Catal. Commun., 10, 1127 (2009)

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[17] Kim SA, Yim JH, Byun HS, Lim JS, Korean J. Chem. Eng., 28(12), 2324 (2011)

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[20] Cho H, Yim JH, Lim JS, J. Supercrit. Fluids, 81, 7 (2013)

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[23] Shibata SK, Sandler SI, Ind. Eng. Chem. Res., 28, 1893 (1989)

[24] Im J, Kim M, Lee J, Kim H, J. Chem. Eng. Data, 49(2), 243 (2004)

[25] Wong DSH, Sandler SI, AIChE J., 38, 671 (1992)

[26] Abrams DS, Prausnitz JM, AIChE J., 21, 116 (1975)

[27] Renon H, Prausnitz JM, AIChE J., 14, 135 (1968)

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