화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.35, 253-261, March, 2016
DOI10.1016/j.jiec.2015.12.039  Export Citation
Stainless steel grid mesh-supported CVD made Co3O4 thin films for catalytic oxidation of VOCs of olefins type at low temperature
Patrick Mountapmbeme Kouotou1, 2, †, Guan-Fu Pan1, 3, Jun-Jie Weng1, 4, Shi-Bin Fan1, 3, and Zhen-Yu Tian1, 3, †
  • 1Institute of Engineering Thermophysics, Chinese Academy of Sciences, Beisihuanxi 11, 100190 Beijing, China
  • 2Higher Institute of the Sahel, University of Maroua, P.O. Box 46, Maroua, Cameroon
  • 3University of Chinese Academy of Sciences, Beijing 100049, China
  • 4, China
E-mail:,
The effective evaluation of the catalytic performance of Co3O4 supported on an inert carrier was investigated toward the deep oxidation of light olefins. Thin Co3O4 films were deposited on grid mesh of stainless steel using one-step chemical vapor deposition method. The as-deposited materials were characterized in terms of structure, morphology and composition. Co3O4 crystals with cubic spinel structures composed of Co2+, Co3+ and nucleophilic oxygen species (O2-) were obtained. The catalytic results indicated that Co3O4 supported on steel mesh was highly active to enable the complete conversion of C3H6 and n-C4H8 with a Mars-van Krevelen type mechanism.
Keywords:Chemical vapor deposition;Cobalt spinel;Stainless steel;Catalytic oxidation;VOCs
  1. Amann M, Lutz M, J. Hazard. Mater., 78(1-3), 41 (2000)
  2. Heck RM, Farrauto RJ, Catalytic Pollution Control, 2nd ed., Wiley-interscience, New York, 2002.
  3. Li WB, Wang JX, Gong H, Catal. Today, 148(1-2), 81 (2009)
  4. Choi BS, Yi J, Chem. Eng. J., 76(2), 103 (2000)
  5. Everaert K, Baeyens J, Creemers C, Proc. CHISA Int. Conf., 2, 23 (2002)
  6. Li WB, Chu WB, Zhuang A, Hua J, Catal. Today, 93-95, 205 (2004)
  7. Gluhoi AC, Nieutwenhuys BE, Catal. Today, 119(1-4), 305 (2007)
  8. Abbasi Z, Haghighi M, Fatehifar E, Saedy S, J. Hazard. Mater., 186(2-3), 1445 (2011)
  9. Li Y, Zhang XL, He H, Yu YB, Yuan T, Tian ZY, Wang J, Li YY, Appl. Catal. B: Environ., 89(3-4), 659 (2009)
  10. Wu JCS, Chang TY, Catal. Today, 44(1-4), 111 (1998)
  11. Kouotou PM, Tian ZY, Vieker H, Bayer A, Golzhauser A, Kohse-Hoinghaus K, J. Mater. Chem. A, 1, 10495 (2013)
  12. Tian ZY, Vieker H, Kouotou PM, Bayer A, Faraday Discuss., 177, 249 (2015)
  13. Bhat PB, Rajaroa R, Sahajwalla V, Bhat BR, J. Mol. Catal. A-Chem., 409, 42 (2015)
  14. Ma C, Wang D, Xue W, Dou B, Wang H, Hao Z, Environ. Sci. Technol., 45, 3628 (2011)
  15. Zeng T, Zhang X, Wang S, Niu H, Cai Y, Environ. Sci. Technol., 49, 2350 (2015)
  16. Piumetti M, Fino D, Russo N, Appl. Catal. B: Environ., 163, 277 (2015)
  17. Lee DW, Yoo BR, J. Ind. Eng. Chem., 20(6), 3947 (2014)
  18. Zhou G, He X, Liu S, Xie H, Fu M, J. Ind. Eng. Chem., 21, 932 (2015)
  19. Wang CH, Lin SS, Appl. Catal. A: Gen., 268 (2004)
  20. Zwinkels MFM, Jaras SG, Menon PG, Griffin TA, Catal. Rev. Sci. Eng., 35, 319 (1993)
  21. Delimaris D, Ioannides T, Appl. Catal. B: Environ., 89(1-2), 295 (2009)
  22. Zhu Z, Lu G, Zhang Z, Guo Y, Guo Y, Wang Y, ACS Catal., 3, 1154 (2013)
  23. Deng X, Tuysuz H, ACS Catal., 4, 3701 (2014)
  24. Liu C, Liu Q, Bai L, Dong A, Liu G, Wen S, J. Mol. Catal. A-Chem., 67, 1 (2013)
  25. Carrillo AM, Carriazo JG, Appl. Catal. B: Environ., 164 (2015)
  26. Carabineiro SAC, Chen X, Konsolakis M, Psarras AC, Tavares PB, Orfao JJM, Pereira MFR, Figueiredo JL, Catal. Today, 244, 161 (2015)
  27. Wang L, Chen JL, Ge L, Zhu ZH, Rudolph V, Energy Fuels, 25(8), 3408 (2011)
  28. Cai ZY, Zhu MQ, Dai H, Liu Y, Mao JX, Chen XZ, He CH, Adv. Chem. Eng. Sci., 1, 15 (2011)
  29. Papoulis D, Komarneni S, Panagiotaras D, Stathatos E, Toli D, Christoforidis KC, Fernandez-Garcia M, Li H, Yin S, Sato T, Katsuki H, Appl. Catal. B: Environ., 132-133, 416 (2013)
  30. Zhang Y, Ouyang J, Yang H, Appl. Clay Sci., 95, 252 (2014)
  31. Hou XD, Wang YZ, Zhao YX, Catal. Lett., 123(3-4), 321 (2008)
  32. Tang CW, Wang CB, Chien SH, Catal. Lett., 131(1-2), 76 (2009)
  33. Kang M, Song MW, Lee CH, Appl. Catal. A: Gen., 251(1), 143 (2003)
  34. Wyrwalski F, Lamonier JF, Perez-Zurita MJ, Siffert S, Aboukais A, Catal. Lett., 108(1-2), 87 (2006)
  35. Assebban M, Tian ZY, El Kasmi A, Bahlawane N, Harti S, Chafik T, Chem. Eng. J., 262, 1252 (2015)
  36. Zaitan H, Bianchi D, Achak O, Chafik T, J. Hazard. Mater., 153(1-2), 852 (2008)
  37. Jarraya I, Fourmentin S, Benzina M, Bouaziz S, Chem. Geol., 275, 1 (2010)
  38. Nogueira FGE, Lopes JH, Silva AC, Lago RM, Fabris JD, Oliveira LCA, Appl. Clay Sci., 51, 385 (2011)
  39. Aznarez A, Assis FCC, Gil A, Korili SA, Catal. Today, 176(1), 328 (2011)
  40. Groppi G, Ibashi W, Tronconi E, Forzatti P, Catal. Today, 69(1-4), 399 (2001)
  41. Gatica JM, Vidal H, J. Hazard. Mater., 181(1-3), 9 (2010)
  42. del Rıo L, Lopez I, Marban G, Appl. Catal. B: Environ., 150-151, 370 (2014)
  43. Klyushina A, Pacultova K, Krejcova S, Slowik G, Jiratova K, Kovanda F, Ryczkowski J, Obalova L, Catal. Today, 257, 2 (2015)
  44. Tian ZY, Ngamou PHT, Vannier V, Kohse-Hoinghaus K, Bahlawane N, Appl. Catal. B: Environ., 117-118, 125 (2012)
  45. Meille V, Appl. Catal. A: Gen., 315, 1 (2006)
  46. Matatov-Meytal Y, Sheintuch M, Appl. Catal. A: Gen., 231(1-2), 1 (2002)
  47. Kim KJ, Ahn HG, J. Ind. Eng. Chem., 18(2), 668 (2012)
  48. Vannier V, Schenk M, Kohse-Hoinghaus K, Bahlawane N, J. Mater. Sci., 47(3), 1348 (2012)
  49. Kouotou PM, Tian ZY, Phys. Status Solidi A-Appl. Res., 212, 1508 (2015)
  50. Jiang J, Li LC, Mater. Lett., 61, 4894 (2007)
  51. Tian ZY, Kouotou PM, Kasmi AE, Ngamou PHT, Kohse-Hoinghaus K, Vieker H, Beyer A, Golzhauser A, Proc. Combust. Inst., 35, 2207 (2015)
  52. Ramana CV, Massot M, Julien CM, Surf. Interface Anal., 37, 412 (2005)
  53. Schenck CV, Dillard JG, Murray JW, J. Colloid Interface Sci., 95, 398 (1983)
  54. Oku M, Sato Y, Appl. Surf. Sci., 55, 37 (1992)
  55. Xu J, Gao P, Zhao TS, Energy Environ. Sci., 5, 5333 (2012)
  56. Cao AM, Hu JS, Liang HP, Song WG, Wan LJ, He XL, Gao XG, Xia SH, J. Phys. Chem. B, 110(32), 15858 (2006)
  57. Fu L, Liu ZM, Liu YQ, Han BX, Hu PG, Cao LC, Zhu DB, Adv. Mater., 17(2), 217 (2005)
  58. Langell MA, Anderson MD, Carson GA, Peng L, Smith S, Phys. Rev. B, 59, 4791 (1999)
  59. Armelao L, Barreca D, Gross S, Tondello E, Surf. Sci. Spectra, 8, 14 (2001)
  60. Tian ZY, Bahlawane N, Qi F, Kohse-Hoinghaus K, Catal. Commun., 11, 118 (2009)
  61. Kouotou PM, Vieker H, Tian ZY, Ngamou PHT, Kasmi AE, Beyer A, Golzhauser A, Kohse-Hoinghaus K, Catal. Sci. Technol., 4, 3359 (2014)
  62. Hu L, Sun K, Peng Q, Xu B, Li Y, Nano Res., 3, 363 (2010)
  63. Xiao XL, Liu XF, Zhao H, Chen DF, Liu FZ, Xiang JH, Hu ZB, Li YD, Adv. Mater., 24(42), 5762 (2012)
  64. Liotta LF, Ousmane M, Di Carlo G, Pantaleo G, Deganello G, Marci G, Retailleau L, Giroir-Fendler A, Appl. Catal. A: Gen., 347(1), 81 (2008)
  65. Gennequin C, Lamallem M, Cousin R, Siffert S, Aissi F, Aboukais A, Catal. Today, 122(3-4), 301 (2007)
  66. Gluhoi AC, Bogdanchikova N, Nieuwenhuys BE, J. Catal., 232(1), 96 (2005)
  67. Ivanova S, Petit C, Pitchon V, Gold Bull., 39, 3 (2006)
  68. Zhizhina EG, Simonova MV, Odyakov VF, Matveev KI, Appl. Catal. A: Gen., 319, 91 (2007)
  69. Zhizhina EG, Odyakov VF, Chem. Eng. J., 230, 308 (2013)
  70. Busca G, Lorenzelli V, J. Chem. Soc.-Faraday Trans., 88, 2783 (1992)
  71. Park JH, Noh H, Park JW, Row K, Jung KD, Shin CH, Appl. Catal. A: Gen., 431-432, 137 (2012)
  72. Jung JC, Lee H, Kim H, Park S, Chung YM, Kim TJ, Lee SJ, Oh SH, Kim YS, Song IK, Catal. Commun., 9, 2059 (2008)
  73. Bruckner A, Bentrup U, Fait M, Kubias B, Catal. Today, 99(1-2), 123 (2005)
  74. Park JH, Shin CH, J. Ind. Eng. Chem., 21, 683 (2015)
  75. Davies TE, Garcia T, Solsona B, Taylor SH, Chem. Commun., 32, 3417 (2006)
  76. Liu Q, Wang LC, Chen M, Cao Y, He HY, Fan KN, J. Catal., 263(1), 104 (2009)
  77. Liotta LF, Wu H, Pantaleo G, Venezia AM, Catal. Sci. Technol., 3, 3085 (2013)
  78. Mars P, van Krevelen DW, Chem. Eng. Sci., 3, 41 (1954)
  79. Wragg RD, Ashmore PG, Hockey JA, J. Catal., 22, 49 (1971)
  80. Sancier KM, Wentrcek PR, Wise H, J. Catal., 39, 141 (1975)
  81. Krenzke LD, Keulks GW, J. Catal., 295 (1980)
  82. Finocchio E, Willey RJ, Busca G, Lorenzelli V, J. Chem. Soc.-Faraday Trans., 93, 175 (1997)
  83. Pan GF, Fan SB, Liang J, Liu YX, Tian ZY, RSC Adv., 5, 42477 (2015)
  84. Liang J, Pan GF, Fan SB, Cheng WL, Tian ZY, Phys. Status Solidi A-Appl. Res., 12, 1001 (2015)
  85. Tian ZY, Kouotou PM, Bahlawane N, Ngamou PHT, J. Phys. Chem. C, 117, 6218 (2013)
  86. Baussart H, Delobel R, Bras ML, Leroy JM, J. Chem. Soc.-Perkin Trans. 1, 75, 1337 (1979)
  87. Machida M, Ochiai K, Ito K, Ikeue K, J. Catal., 238, 68 (2006)
  88. Zhang R, Alamdari H, Kaliaguine S, Catal. Lett., 119(1-2), 108 (2007)