화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.35, 388-399, March, 2016
DOI10.1016/j.jiec.2016.01.021  Export Citation
Development of sustainable elastomeric engineering nanocomposites from linseed oil with improved mechanical stability and thermally induced shape memory properties
Rakesh Das, Sovan Lal Banerjee, Rajesh Kumar1, and P.P. Kundu†
  • Department of Polymer Science and Technology, University of Calcutta, 92, A.P.C. Road, Kolkata 700009, India
  • 1Precision Metrology Laboratory, Department of Mechanical Engineering, Sant Longowal Institute of Engineering & Technology, Sangrur, Punjab 148106, India
E-mail:
The elastomeric nanocomposites having high mechanical stability and shape memory property were fabricated via in situ cationic polymerization of vegetable oil (linseed oil) in the presence of nano fly ash (NFA). The enhanced dynamic moduli and Young’s modulus of nanocomposites with respect to matrix elastomers were witnessed. The vibration damping behavior of nanocomposites in wide frequency region, observed under a laboratory fabricated machine reveals their effectiveness to attenuate hazardous vibration in broad application regions. Under thermally stimulated shape memory test, the nanocomposites exhibit 100% shape recovery, and the shape recovery time improves when the content of NFA filler increases.
Keywords:Polymer nanocomposites;Shape memory property;Dynamic mechanical analysis;Vibration damping
  1. Mohanty AK, Misra M, Hinrichen G, Macromol. Mater. Eng., 276-277, 1 (2000)
  2. Ronda JC, Lligadas G, Galia M, Cadiz V, Eur. J. Lipid Sci. Technol., 113, 46 (2011)
  3. Ray SS, Bousmina M, Prog. Mater. Sci., 50(8), 962 (2005)
  4. Messersmith PB, Giannelis EP, J. Polym. Sci. A: Polym. Chem., 33(7), 1047 (1995)
  5. Okamoto M, Mater. Sci. Technol. Lond., 22, 756 (2006)
  6. Divya VC, Pattanshetti VV, Suresh R, Sailaja RPN, J. Polym. Res., 20, 51 (2013)
  7. Giannelis EP, Adv. Mater., 8(1), 29 (1996)
  8. Paul DR, Robeson LM, Polymer, 49(15), 3187 (2008)
  9. Youssef AM, Polym. Plast. Technol., 52, 52 (2013)
  10. Zou H, Wu SS, Shen J, Chem. Rev., 108(9), 3893 (2008)
  11. Lu Y, Larock RC, ChemSusChem, 2, 136 (2009)
  12. Xia Y, Larock RC, Green Chem., 12, 1893 (2010)
  13. Khot SN, Lascala JJ, Can E, Morye SS, Williams GI, Palmese GR, Kusefoglu SH, Wool RP, J. Appl. Polym. Sci., 82(3), 703 (2001)
  14. Mosiewicki MA, Aranguren MI, Eur. Polym. J., 49, 1243 (2013)
  15. Tan SG, Ahmad Z, Chow WS, Appl. Clay Sci., 90, 11 (2014)
  16. Lu YS, Larock RC, J. Appl. Polym. Sci., 102(4), 3345 (2006)
  17. Reddy MM, Vivekanandhan S, Misra M, Bhatia SK, Mohanty AK, Prog. Polym. Sci, 38, 1653 (2013)
  18. Pfister DP, Larock RC, J. Appl. Polym. Sci., 123(3), 1392 (2012)
  19. Quirino RL, Woodford J, Larock RC, J. Appl. Polym. Sci., 124(2), 1520 (2012)
  20. Pardo SG, Bernat C, Abad MJ, Caro J, Polym. Compos., 31, 1722 (2010)
  21. Ray D, Bhattacharya D, Mohanty AK, Drzal LT, Misra M, Macromol. Mater. Eng., 291, 784 (2006)
  22. Ahmaruzzaman M, Prog. Energy Combust. Sci., 36(3), 327 (2010)
  23. Iyer R, J. Hazard. Mater., 93(3), 321 (2002)
  24. Sreekanth MS, Joseph S, Mhaske ST, Mahanwar PA, Bambole VA, J. Thermoplast. Compos. Mater., 24, 317 (2011)
  25. Deepthi MV, Sharma M, Sailaja RRN, Anantha P, Sampathkumaran P, Seetharamu S, Mater. Des., 31, 2051 (2010)
  26. Kulkarni SM, Kishore, J. Mater. Sci., 37(20), 4321 (2002)
  27. Thongsang S, Sombatsompop N, Polym. Compos., 27, 30 (2006)
  28. Kishore SM, Kulkarni D, Sunil S, Sarathchandra, Polym. Int., 51, 1378 (2002)
  29. Yu-Fen Y, Guo-Shen G, Zhen-Fang C, Qing-Ru C, J. Hazard. Mater., 133, 276 (2000)
  30. Nielson LE, Mechanical Properties of Polymer and Composites, 2nd ed., Marcel Dekker, New York, 1994.
  31. Xie T, Polymer, 52(22), 4985 (2011)
  32. Lu H, Huang WM, Appl. Phys. Lett., 102, 231910 (2013)
  33. Xu B, Huang WM, Pei YT, Chen ZG, Kraft A, Reuben R, De Hosson JTM, Fu YQ, Eur. Polym. J., 45, 1904 (2009)
  34. Wu XL, Huang WM, Tan HX, J. Polym. Res., 20, 150 (2013)
  35. Li FK, Larock RC, J. Appl. Polym. Sci., 84(8), 1533 (2002)
  36. Meiorin C, Aranguren MI, Mosiewicki MA, Eur. Polym. J., 67, 67 (2015)
  37. Tsujimoto T, Uyama H, ACS Sustain. Chem. Eng., 2, 2057 (2014)
  38. Tsujimoto T, Ohta E, Uyama H, Express Polym. Lett., 9, 757 (2015)
  39. Zhang C, Madbouly SA, Kessler MR, ACS Appl. Mater. Interfaces, 7, 1226 (2015)
  40. Saralegi A, Foster EJ, Weder C, Eceizaand A, Corcuera MA, Smart Mater. Struct., 23, 025033 (2014)
  41. Thakur S, Karak N, J. Mater. Chem. A, 2, 14867 (2014)
  42. ASTM E756-05, Standard Test Method for Measuring Vibration-Damping Properties of Materials, American Society for Testing and Materials, 2010.
  43. Hameed BH, Lai LF, Chin LH, Fuel Process. Technol., 90(4), 606 (2009)
  44. De Silva CW, Vibration Damping Control and Design, CRC Press, USA, 2007.
  45. Harris M, Piersol AG, Harris’ Shock and Vibration Handbook, McGraw-Hill, New York, 2002.
  46. Paul KT, Satpathy SK, Manna I, Chakraborty KK, Nando GB, Nanoscale Res. Lett., 2, 397 (2007)
  47. Vlachos N, Skopelitis Y, Psaroudaki M, Konstantinidou V, Chatzilazarou A, Tegou E, Anal. Chim. Acta, 573-574, 459 (2006)
  48. Kumar G, Nisha N, Mageswari S, Subramanian K, J. Polym. Res., 18, 18 (2011)
  49. Das R, Kumar R, Banerjee SL, Kundu PP, RSC Adv., 4, 59265 (2014)
  50. Trakulsujaritchok T, Hourston DJ, Eur. Polym. J., 42, 2968 (2006)
  51. Chung DDL, J. Mater. Sci., 36(24), 5733 (2001)
  52. Schnell HF, Goritz D, Schmid EJ, J. Mater. Sci., 26, 661 (1991)
  53. Russel DL, Remarks on experimental determination of modal damping rates in elastic beams, in: Chen G, Zhou J (Eds.), Vibration and Damping in Distributed Systems - WKB and Wave Methods, Visualization and Experimentation, vol. 2, CRC Press, Tokyo, Japan, 1993 (Chapter 5).
  54. Huang WM, Zhao Y, Wang CC, Ding Z, Purnawali H, Tang C, Zhang JL, J. Polym. Res., 19, 9952 (2012)
  55. Karger-Kocsis J, Keki S, Express Polym. Lett., 8, 397 (2014)