Chemical Engineering and Processing, Vol.104, 75-83, 2016
Simulated moving bed reactor for p-xylene production: Dual-bed column
A dual-bed Simulated Moving Bed Reactor (SMBR) is developed under the framework of a proposed aromatics complex where the extract product, with 70 wt% p-xylene, is further purified by a crystallization unit to obtain the final product. Each column within the unit contains an adsorbent/catalyst homogeneous mixture as first bed followed by another bed of just adsorbent. A method of dynamic optimization is applied to estimate the optimum adsorbent/catalyst proportion within the first bed so p-xylene production is equal to its adsorption. Afterwards, the unit is optimized through successive simulations using the SMBR model giving a productivity of 226.27kg/m(3) h (produced p-xylene per volume of adsorbent and catalyst within the columns), a desorbent consumption of 0.07 m(3)/kg (volume of desorbent per produced p-xylene), and a produced p-xylene to fed p-xylene ratio of 1.75 at 200 degrees C. Finally, using the commercial software gPROMS, an integrated method that combines less time-consuming results from True Moving Bed Reactor (TMBR) approach with the rigorous SMBR calculations to develop the dual-bed SMBR unit is presented. (c) 2016 Elsevier B.V. All rights reserved.
Keywords:p-Xylene;Simulated moving bed reactor;Isomerization;Multilayer;Adsorbent/catalyst ratio;Optimization