In this study, mass transfer performance and static holdup of dispersed phase in a liquid-liquid extraction column with rotating discs is investigated in presence of nanoparticles. The required nanofluid was prepared by dispersing SiO2 nanoparticles in kerosene, as the base fluid, using ultra sonication. The results show that the presence of nanoparticles increases static holdup of the dispersed phase. Moreover, the mass transfer performance was improved 6-45%. At higher rotor speeds, the effect of nanoparticles is reduced. Taking the heat and mass transfer analogy into account, an equation is presented for prediction of effective diffusivity and dispersed phase mass transfer coefficient in terms of nanoparticles content, Reynolds number and Schmidt number. Finally, the mass transfer coefficients obtained via the proposed equation of this work and the equations given by some other researchers have been compared with experimental data. (c) 2016 Elsevier B.V. All rights reserved.