Monitoring data on air emissions of selected persistent org. pollutants from largest economy sectors in Poland in 1995-2012 were collected. In particular, the emissions of polycyclic arom. hydrocarbons, polychlorinated benzodioxins, dibenzofuranes, biphenyls and C6Cl6 in 2010 in the country regions (voivodships) were estd. by using the top down approach and presented on maps.