Synthesis of environment friendly nonionic surfactants from sugar base and characterization of interfacial properties for detergent application

SuMin Lee; JuYeon Lee; HyonPil Yu; JongChoo Lim

Journal of Industrial and Engineering Chemistry, Vol.38, 157-166, June, 2016

DOI10.1016/j.jiec.2016.04.019 Export Citation

Synthesis of environment friendly nonionic surfactants from sugar base and characterization of interfacial properties for detergent application

SuMin Lee, JuYeon Lee, HyonPil Yu¹, and JongChoo Lim^†

Department of Chemical and Biochemical Engineering, Dongguk University-Seoul, Seoul 100-715, Republic of Korea
¹AK ChemTech Central Research Lab., DaeJeon, Republic of Korea

E-mail:

In this study, environment friendly nonionic surfactants were synthesized from sugar base and their structure was characterized by 1H-NMR, 13C-NMR and FT-IR. The newly synthesized SA08 series surfactants showed excellent interfacial properties such as low CMC, surface tension and interfacial tension, and superior foam stability. Detergency tests using three different types of artificial soils have revealed that the synthesized surfactants showed moderately good detergency presumably due to excellent interfacial properties and stereoscopic molecular structure of SA08 series surfactants. Environmental compatibility test showed that SA08-07 surfactant exhibited low toxicity compared with conventional nonionic and anionic surfactants and excellent biodegradability.

Keywords:Environment friendly;Nonionic surfactant;Interfacial property;Detergent

[References]

Miller CA, Neogi P, Interfacial Phenomena: Equilibrium and Dynamic Effects, Marcel Dekker, New York, 1985.
Frome T, Knepper P, Trends Anal. Chem., 27, 1091 (2008)
Li X, Turanek J, Knotigova P, Kudlackova H, Masek J, Parkin S, Rankin E, Knutson L, Lehmler H, Colloids Surf. B: Biointerfaces, 73, 65 (2009)
Jurado E, Fernandez-Serrano M, Camacho F, Olea JN, Lechuga M, Luzon G, Chem. Eng. J., 150(2-3), 440 (2009)
Wen YP, Xu JK, He HH, Lu BY, Li YZ, Dong B, J. Electroanal. Chem., 634(1), 49 (2009)
Butt M, Berger U, Bossi R, Tomy T, Sci. Total Environ., 408, 2936 (2010)
Negm N, Kandile N, Aiad I, Mohammad M, Colloids Surf. A: Physicochem. Eng. Asp., 391, 224 (2011)
Stoppel L, White C, Horava D, Bhatia R, Roberts C, Acta Biomater., 7, 3988 (2011)
Pietka-Ottlik M, Frackowiak R, Maliszewska I, Kołwzan B, Wilk A, Chemosphere, 89, 1103 (2012)
Madejova J, Palkova H, Jankovic L, Chem. Phys., 134, 768 (2012)
Oldham E, Seelam S, Lema C, Aguilera J, Fiegel J, Rankin E, Knutson L, Lehmler H, Carbohydr. Res., 379, 68 (2013)
Brycki B, Waligorska M, Szulc A, J. Hazard. Mater., 280, 797 (2014)
Negm NA, Tawfik SM, J. Ind. Eng. Chem., 20(6), 4463 (2014)
Lim JC, Lee MC, Lim TK, Kim BJ, Colloids Surf. A: Physicochem. Eng. Asp., 446, 80 (2014)
Park SH, Bae J, J. Ind. Eng. Chem., 30, 1 (2015)
Fatma N, Panda M, Ansari W, Din K, J. Mol. Liq., 211, 247 (2015)
K.S. KSM, 2714 Testing Method for Biodegradability of Synthetic Detergent, 2007.
Lim JC, Han DS, Colloids Surf. A: Physicochem. Eng. Asp., 389, 166 (2011)
Lim JC, Park JM, Park CJ, Lee BM, Colloid Polym. Sci., 291, 855 (2013)
Chung DW, Lim JC, Colloids Surf. A: Physicochem. Eng. Asp., 336, 35 (2009)
Kang EK, Lee BM, Hwang HA, Lim JC, J. Ind. Eng. Chem., 17(5-6), 845 (2011)
Lim JC, Kang EK, Park JM, Kang HC, Lee BM, J. Ind. Eng. Chem., 18(4), 1406 (2012)
Lee BM, Kim JH, Kim SS, Lim JC, Appl. Chem. Eng., 23(5), 433 (2012)
Schroder V, Behrend O, Schubert H, J. Colloid Interface Sci., 202(2), 334 (1998)
Souilem S, Kobayashi I, Neves MA, Jlaiel L, Isoda H, Sayadi S, Nakajima M, Food Res. Int., 62, 467 (2014)
Lim JC, Chung DW, J. Appl. Polym. Sci., 125(2), 888 (2012)
Miller CA, Opin. Curr. Colloid Interface Sci., 13, 177 (2008)
Zhang H, Miller CA, Garrett PR, Raney KH, J. Surf. Deterg., 8, 99 (2005)
Lim JC, J. Ind. Eng. Chem., 15(2), 257 (2009)
Bikerman JJ, Foams, Springer-Verlag, New York, 1973.
Lai BKY, Dixit N, in: Prud’homme RK, Khan SA (Eds.), Foams: Theory, Measurements, and Applications, Marcel Dekker, New York, 1996.
Zhang H, Miller CA, Garrett PR, Raney KH, J. Colloid Interface Sci., 263(2), 633 (2003)
Zhang H, Miller CA, Garrett PR, Raney KH, J. Colloid Interface Sci., 279(2), 539 (2004)
Schick MJ, Fowkes FM, J. Phys. Chem., 61, 1062 (1957)
Lee SM, Kim BJ, Choi KY, Lee HS, Lim JC, in: Proceedings in the 6th Asian Conference on Colloid and Interface Science (ACCIS2015), Sasebo, Japan, November 24, 2015.

[Referenced By]

[1] Miller CA, Neogi P, Interfacial Phenomena: Equilibrium and Dynamic Effects, Marcel Dekker, New York, 1985.

[2] Frome T, Knepper P, Trends Anal. Chem., 27, 1091 (2008)

[3] Li X, Turanek J, Knotigova P, Kudlackova H, Masek J, Parkin S, Rankin E, Knutson L, Lehmler H, Colloids Surf. B: Biointerfaces, 73, 65 (2009)

[4] Jurado E, Fernandez-Serrano M, Camacho F, Olea JN, Lechuga M, Luzon G, Chem. Eng. J., 150(2-3), 440 (2009)

[5] Wen YP, Xu JK, He HH, Lu BY, Li YZ, Dong B, J. Electroanal. Chem., 634(1), 49 (2009)

[6] Butt M, Berger U, Bossi R, Tomy T, Sci. Total Environ., 408, 2936 (2010)

[7] Negm N, Kandile N, Aiad I, Mohammad M, Colloids Surf. A: Physicochem. Eng. Asp., 391, 224 (2011)

[8] Stoppel L, White C, Horava D, Bhatia R, Roberts C, Acta Biomater., 7, 3988 (2011)

[9] Pietka-Ottlik M, Frackowiak R, Maliszewska I, Kołwzan B, Wilk A, Chemosphere, 89, 1103 (2012)

[10] Madejova J, Palkova H, Jankovic L, Chem. Phys., 134, 768 (2012)

[11] Oldham E, Seelam S, Lema C, Aguilera J, Fiegel J, Rankin E, Knutson L, Lehmler H, Carbohydr. Res., 379, 68 (2013)

[12] Brycki B, Waligorska M, Szulc A, J. Hazard. Mater., 280, 797 (2014)

[13] Negm NA, Tawfik SM, J. Ind. Eng. Chem., 20(6), 4463 (2014)

[14] Lim JC, Lee MC, Lim TK, Kim BJ, Colloids Surf. A: Physicochem. Eng. Asp., 446, 80 (2014)

[15] Park SH, Bae J, J. Ind. Eng. Chem., 30, 1 (2015)

[16] Fatma N, Panda M, Ansari W, Din K, J. Mol. Liq., 211, 247 (2015)

[17] K.S. KSM, 2714 Testing Method for Biodegradability of Synthetic Detergent, 2007.

[18] Lim JC, Han DS, Colloids Surf. A: Physicochem. Eng. Asp., 389, 166 (2011)

[19] Lim JC, Park JM, Park CJ, Lee BM, Colloid Polym. Sci., 291, 855 (2013)

[20] Chung DW, Lim JC, Colloids Surf. A: Physicochem. Eng. Asp., 336, 35 (2009)

[21] Kang EK, Lee BM, Hwang HA, Lim JC, J. Ind. Eng. Chem., 17(5-6), 845 (2011)

[22] Lim JC, Kang EK, Park JM, Kang HC, Lee BM, J. Ind. Eng. Chem., 18(4), 1406 (2012)

[23] Lee BM, Kim JH, Kim SS, Lim JC, Appl. Chem. Eng., 23(5), 433 (2012)

[24] Schroder V, Behrend O, Schubert H, J. Colloid Interface Sci., 202(2), 334 (1998)

[25] Souilem S, Kobayashi I, Neves MA, Jlaiel L, Isoda H, Sayadi S, Nakajima M, Food Res. Int., 62, 467 (2014)

[26] Lim JC, Chung DW, J. Appl. Polym. Sci., 125(2), 888 (2012)

[27] Miller CA, Opin. Curr. Colloid Interface Sci., 13, 177 (2008)

[28] Zhang H, Miller CA, Garrett PR, Raney KH, J. Surf. Deterg., 8, 99 (2005)

[29] Lim JC, J. Ind. Eng. Chem., 15(2), 257 (2009)

[30] Bikerman JJ, Foams, Springer-Verlag, New York, 1973.

[31] Lai BKY, Dixit N, in: Prud’homme RK, Khan SA (Eds.), Foams: Theory, Measurements, and Applications, Marcel Dekker, New York, 1996.

[32] Zhang H, Miller CA, Garrett PR, Raney KH, J. Colloid Interface Sci., 263(2), 633 (2003)

[33] Zhang H, Miller CA, Garrett PR, Raney KH, J. Colloid Interface Sci., 279(2), 539 (2004)

[34] Schick MJ, Fowkes FM, J. Phys. Chem., 61, 1062 (1957)

[35] Lee SM, Kim BJ, Choi KY, Lee HS, Lim JC, in: Proceedings in the 6th Asian Conference on Colloid and Interface Science (ACCIS2015), Sasebo, Japan, November 24, 2015.