화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.38, 167-174, June, 2016
DOI10.1016/j.jiec.2016.04.020  Export Citation
In situ polymerization of poly(styrene-alt-maleic anhydride)/organic montmorillonite nanocomposites and their ionomers as crystallization nucleating agents for poly(ethylene terephthalate)
Shili Xing, Rui Li, Jingjing Si†, and Ping Tang†
  • State Key Laboratory of Molecular Engineering of Polymers, Collaborative Innovation Center of Polymers and Polymer Composite Materials, Department of Macromolecular Science, Fudan University, Shanghai 200433, China
E-mail:,
The poly(styrene-alt-maleic anhydride)/organic montmorillonite (SMA/OMMT) nanocomposites are obtained through in situ polymerization of styrene and maleic anhydride. The OMMT is exfoliated into small platelets and dispersed well in SMA copolymers, which is thus easily made into ionomers/OMMT (IM) nanocomposites. The IMs are employed as nucleating agents for poly(ethylene terephthalate) (PET) and the crystallization behavior is investigated by DSC isothermally and non-isothermally, respectively. The crystallization rate of PET is significantly accelerated and melt-crystallization temperature is increased with the addition of IMs which acted as heterogeneous nucleating agent due to good miscibility between anhydride and PET, and large interfaces provided by exfoliated OMMT.
Keywords:Crystallization;Nucleating agent;Ionomer;Poly(ethylene terephthalate);Organic montmorillonite
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