화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.39, 77-86, July, 2016
DOI10.1016/j.jiec.2016.05.010  Export Citation
Gel-type ion exchange resin stabilized Pd-Bi nanoparticles for the glycerol oxidation in liquid phase
Stanislav Vajıcek, Magdalena Stolcova†, Alexander Kaszonyi, Matej Micusık1, Pavel Alexy2, Patrizia Canton3, Gyorgy Onyestyak4, Szabolcs Harnos4, Ferenc Lonyi4, and Jozsef Valyon4
  • Department of Organic Technology, Joint Slovak-Hungarian Laboratory for Development of Catalyzed Chemical Processes of Biomass Utilization, Slovak University of Technology, Radlinskeho 9, 81237 Bratislava, Slovak Republic, Slovakia (Slovak Republic)
  • 1Polymer Institute, Slovak Academy of Sciences, Dubravska cesta 9, 845 41 Bratislava, Slovak Republic, Slovakia (Slovak Republic)
  • 2Department of Plastics and Rubber, Slovak University of Technology, Radlinskeho 9, 81237 Bratislava, Slovak Republic, Slovakia (Slovak Republic)
  • 3Dipartimento di Chimica Fisica, Universita di Venezia, via Torino 155/b, 30170 Venezia-Mestre, Italy
  • 4Institute of Materials and Research Centre for Natural Science, Joint Slovak-Hungarian Laboratory for Development of Catalyzed Chemical Processes of Biomass Utilization, Magyar tudosok korutja 2, H-1117 Budapest, Hungary
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Palladium-bismuth nanoparticles were supported into strongly basic anion-exchange resin of gel-type and tested as catalysts for the selective oxidation of glycerol with molecular oxygen at atmospheric pressure. Detailed study of the precursors preparation and reduction were undertaken. The catalyst 3%Pd-1%Bi where the bismuth was deposited on the palladium particles (3.4 nm) exhibited at 95% glycerol conversion more than 63% yield toward glyceric acid and tartronic acid after 3 h of reaction. The catalyst maintains practically similar catalytic performance as in fresh state for at least five consecutive catalytic cycles without extra catalyst treatment and reactivation.
Keywords:Gel-type anion-exchange resin;Pd-Bi nanoparticles;Glycerol liquid-phase oxidation;Glyceric acid;Tartronic acid
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