Acid baking of spent lithium ion batteries for selective recovery of major metals: A two-step process

Pratima Meshram; Abhilash; Banshi Dhar Pandey; Tilak Raj Mankhand; Haci Deveci

Journal of Industrial and Engineering Chemistry, Vol.43, 117-126, November, 2016

DOI10.1016/j.jiec.2016.07.056 Export Citation

Acid baking of spent lithium ion batteries for selective recovery of major metals: A two-step process

Pratima Meshram^{1, 2, †}, Abhilash^{1, 3}, Banshi Dhar Pandey^{1, 3}, Tilak Raj Mankhand², and Haci Deveci⁴

¹CSIR-National Metallurgical Laboratory (NML), Jamshedpur, India
²Dept. of Metallurgical Engineering, IIT (BHU), Varanasi, India
³, India
⁴Karadeniz Technical University, Trabzon, Turkey

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The present work focuses on a two-step process for selective dissolution of metals from cathode active material of spent LIBs. Cathode powder baked at 300 °C using H2SO4 being subjected to first stage leaching with water extracted 78.6% Li, 80.4% Co in 60 min at 75 °C and 25% pulp density; recovery of Ni and Mn being low (<15%). In second stage, reductive leaching was performed using an acid mixture (H2SO4 and HNO3) with glucose solubilizing 67% Ni, 64.8% Mn in 45 min. The overall recovery of the metals was 93.2% Li, 90.52% Co, 82.8% Ni, 77.7% Mn.

Keywords:Spent LIBs;Baking;Sulfuric acid;Two-stage leaching;Reductant

[References]

Zhu SG, He WZ, Li GM, Zhou X, Zhang XJ, Huang JW, Trans. Nonferrous Met. Soc. China, 22, 2274 (2012)
Meshram P, Pandey BD, Mankhand TR, Hydrometallurgy, 150, 192 (2014)
Zhang P, Yokoyama T, Itabashi O, Suzuki TM, Inoue K, Hydrometallurgy, 47, 259 (1998)
Joulie M, Laucournet R, Billy E, J. Power Sources, 247, 551 (2014)
Nan JM, Han DM, Zuo XX, J. Power Sources, 152(1), 278 (2005)
Meshram P, Pandey BD, Mankhand TR, Waste Manage., 45, 306 (2015)
Lee CK, Rhee KI, Hydrometallurgy, 68, 5 (2003)
Li L, Chen R, Sun F, Wu F, Liu J, Hydrometallurgy, 108, 220 (2011)
Li L, Dunn JB, Zhang XX, Gaines L, Chen RJ, Wu F, Amine K, J. Power Sources, 233, 180 (2013)
Li L, Qu WJ, Zhang XX, Lu J, Chen RJ, Wu F, Amine K, J. Power Sources, 282, 544 (2015)
Kang J, Senanayake G, Sohn J, Shin SM, Hydrometallurgy, 100, 168 (2010)
Chen L, Tang X, Zhang Y, Li L, Zeng Z, Zhang Y, Hydrometallurgy, 108, 80 (2011)
Meshram P, Pandey BD, Mankhand TR, Chem. Eng. J., 281, 418 (2015)
Wang J, Chen M, Chen H, Luo T, Xu Z, Proc. Environ. Sci. (The 7th Int. Conf. Waste Manage. Technol.), 16, 443 (2012)
Chen X, Luo C, Zhang J, Kong J, Zhou T, ACS Sustain. Chem. Eng., 3(12), 3104 (2015)
Ferreira DA, Prados LMZ, Majuste D, Mansur MB, J. Power Sources, 187(1), 238 (2009)
Lee JY, Kumar JR, Jeon HS, Kim JS, Braz. J. Chem. Eng., 30(2), 391 (2013)
Guo X, Li D, Park KH, Tian Q, Wu Z, Hydrometallurgy, 99, 144 (2009)
Kim HI, Park KH, Mishra D, Hydrometallurgy, 98, 192 (2009)
Safarzadeh MS, Moats MS, Miller JD, Miner. Metall. Process., 29(2), 97 (2012)
Granata G, Moscardini E, Pagnanelli F, Trabucco F, Toro L, J. Power Sources, 206, 393 (2012)
Pagnanelli F, Furlani G, Valentini P, Veglio F, Toro L, Hydrometallurgy, 75(1-4), 157 (2004)
Smith TN, Hash K, Davey CL, Mills H, Williams H, Kiely DE, Cabohydr. Res., 350, 6 (2012)

[Referenced By]

[1] Zhu SG, He WZ, Li GM, Zhou X, Zhang XJ, Huang JW, Trans. Nonferrous Met. Soc. China, 22, 2274 (2012)

[2] Meshram P, Pandey BD, Mankhand TR, Hydrometallurgy, 150, 192 (2014)

[3] Zhang P, Yokoyama T, Itabashi O, Suzuki TM, Inoue K, Hydrometallurgy, 47, 259 (1998)

[4] Joulie M, Laucournet R, Billy E, J. Power Sources, 247, 551 (2014)

[5] Nan JM, Han DM, Zuo XX, J. Power Sources, 152(1), 278 (2005)

[6] Meshram P, Pandey BD, Mankhand TR, Waste Manage., 45, 306 (2015)

[7] Lee CK, Rhee KI, Hydrometallurgy, 68, 5 (2003)

[8] Li L, Chen R, Sun F, Wu F, Liu J, Hydrometallurgy, 108, 220 (2011)

[9] Li L, Dunn JB, Zhang XX, Gaines L, Chen RJ, Wu F, Amine K, J. Power Sources, 233, 180 (2013)

[10] Li L, Qu WJ, Zhang XX, Lu J, Chen RJ, Wu F, Amine K, J. Power Sources, 282, 544 (2015)

[11] Kang J, Senanayake G, Sohn J, Shin SM, Hydrometallurgy, 100, 168 (2010)

[12] Chen L, Tang X, Zhang Y, Li L, Zeng Z, Zhang Y, Hydrometallurgy, 108, 80 (2011)

[13] Meshram P, Pandey BD, Mankhand TR, Chem. Eng. J., 281, 418 (2015)

[14] Wang J, Chen M, Chen H, Luo T, Xu Z, Proc. Environ. Sci. (The 7th Int. Conf. Waste Manage. Technol.), 16, 443 (2012)

[15] Chen X, Luo C, Zhang J, Kong J, Zhou T, ACS Sustain. Chem. Eng., 3(12), 3104 (2015)

[16] Ferreira DA, Prados LMZ, Majuste D, Mansur MB, J. Power Sources, 187(1), 238 (2009)

[17] Lee JY, Kumar JR, Jeon HS, Kim JS, Braz. J. Chem. Eng., 30(2), 391 (2013)

[18] Guo X, Li D, Park KH, Tian Q, Wu Z, Hydrometallurgy, 99, 144 (2009)

[19] Kim HI, Park KH, Mishra D, Hydrometallurgy, 98, 192 (2009)

[20] Safarzadeh MS, Moats MS, Miller JD, Miner. Metall. Process., 29(2), 97 (2012)

[21] Granata G, Moscardini E, Pagnanelli F, Trabucco F, Toro L, J. Power Sources, 206, 393 (2012)

[22] Pagnanelli F, Furlani G, Valentini P, Veglio F, Toro L, Hydrometallurgy, 75(1-4), 157 (2004)

[23] Smith TN, Hash K, Davey CL, Mills H, Williams H, Kiely DE, Cabohydr. Res., 350, 6 (2012)