화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.45, 197-205, January, 2017
Enhanced room-temperature HCHO decomposition activity of highly-dispersed Pt/Al2O3 hierarchical microspheres with exposed {110} facets
E-mail:,
Formaldehyde (HCHO) catalytic decomposition at room temperature is an important method for HCHO removal in indoor environment. Herein, flower-like γ-Al2O3 microspheres with high specific surface area, special textural structure, and abundant surface defects were prepared through a one-pot hydrothermal method by using aluminum foil as Al source. And it was used as oxide support to prepare highly-dispersed Pt catalyst (Pt/Al2O3). Compared with Pt supported on commercial γ-Al2O3, the as-prepared Pt/Al2O3 showed enhanced catalytic activity for HCHO decomposition at room temperature. This work provides new insights into designing and fabricating highly-dispersed Pt catalysts for efficient indoor air purification.
  1. Salthammer T, Mentese S, Marutzky R, Chem. Rev., 110(4), 2536 (2010)
  2. Kim KH, Jahan SA, Lee JT, J. Environ. Sci. Health Part C-Environ. Carcinog. Ecotoxicol. Rev., 29, 277 (2011)
  3. Zhang CB, He H, Tanaka K, Catal. Commun., 6, 211 (2005)
  4. Zhang CB, He H, Tanaka K, Appl. Catal. B: Environ., 65(1-2), 37 (2006)
  5. Huang HB, Leung DYC, ACS Catal., 1, 348 (2011)
  6. Chen BB, Zhu XB, Crocker M, Wang Y, Shi C, Catal. Commun., 42, 93 (2013)
  7. Huang HB, Ye XG, Huang HL, Zhang L, Leung DYC, Chem. Eng. J., 230, 73 (2013)
  8. Nie LH, Meng AY, Yu JG, Jaroniec M, Sci. Rep., 3, 3215 (2013)
  9. Huang HB, Hu P, Huang HL, Chen JD, Ye XG, Leung DYC, Chem. Eng. J., 252, 320 (2014)
  10. Hu P, Amghouz Z, Huang Z, Xu F, Chen Y, Tang X, Environ. Sci. Technol., 49, 2384 (2015)
  11. Ye JW, Cheng B, Wageh S, Al-Ghamdi AA, Yu JG, RSC Adv., 6, 34280 (2016)
  12. Xu QL, Lei W, Li X, Qi X, Yu JG, Liu G, Wang J, Zhang P, Environ. Sci. Technol., 48, 9702 (2014)
  13. Chen BB, Zhu XB, Crocker M, Wang Y, Shi C, Appl. Catal. B: Environ., 154-155, 73 (2014)
  14. Tanada S, Kawasaki N, Nakamura T, Araki M, Isomura M, J. Colloid Interface Sci., 214(1), 106 (1999)
  15. Liu XY, Zhang JM, Appl. Surf. Sci., 293, 216 (2014)
  16. Rong HQ, Ryu ZY, Zheng JT, Zhang YL, J. Colloid Interface Sci., 261(2), 207 (2003)
  17. Xu ZH, Yu JG, Low JX, Jaroniec M, ACS Appl. Mater. Interfaces, 6, 2111 (2014)
  18. Lin F, Zhu GQ, Shen YN, Zhang ZY, Dong B, Appl. Surf. Sci., 356, 150 (2015)
  19. Fu PF, Zhang PY, Li J, Appl. Catal. B: Environ., 105(1-2), 220 (2011)
  20. Fu PF, Zhang PY, Chin. J. Catal., 35, 210 (2014)
  21. Lam RCW, Leung MKH, Leung DYC, Vrijinoed LLP, Yam WC, Ng SP, Sol. Energy Mater. Sol. Cells, 91(1), 54 (2007)
  22. Wu CL, Appl. Surf. Sci., 319, 237 (2014)
  23. Yan ZX, Xu ZH, Yu JG, Jaroniec M, Environ. Sci. Technol., 49, 6637 (2015)
  24. Qi LF, Ho WK, Wang JL, Zhang PY, Yu JG, Catal. Sci. Technol., 5, 2366 (2015)
  25. Nie LH, Yu JG, Jaroniec M, Tao FF, Catal. Sci. Technol., 6, 3649 (2016)
  26. Wang JL, Yunus R, Li JG, Li PL, Zhang PY, Kim J, Appl. Surf. Sci., 357, 787 (2015)
  27. Sekine Y, Atmos. Environ., 36, 5543 (2002)
  28. Zhao DZ, Shi C, Li XS, Zhu AM, Jang BW, J. Hazard. Mater., 239-240, 362 (2012)
  29. Wang JL, Li D, Li P, Zhang PY, Xu QL, Yu JG, RSC Adv., 5, 100434 (2015)
  30. An NH, Yu QS, Liu G, Li SY, Jia MJ, Zhang WX, J. Hazard. Mater., 186(2-3), 1392 (2011)
  31. Xu ZH, Yu JG, Jaroniec M, Appl. Catal. B: Environ., 163, 306 (2015)
  32. Chen HY, Rui ZB, Wang XY, Ji HB, Catal. Today, 258, 56 (2015)
  33. Colussi S, Boaro M, de Rogatis L, Pappacena A, de Leitenburg C, Llorca J, Trovarelli A, Catal. Today, 253, 163 (2015)
  34. Qi LF, Cheng B, Yu JG, Ho WK, J. Hazard. Mater., 301, 522 (2016)
  35. Nie LH, Yu JG, Fu JW, ChemCatChem, 6, 1983 (2014)
  36. Nie LH, Zhou P, Yu JG, Jaroniec M, J. Mol. Catal. A-Chem., 390, 7 (2014)
  37. Qi LF, Cheng B, Ho WK, Liu G, Yu JG, ChemNanoMat, 1, 58 (2015)
  38. An H, Zhang WL, Yuan XL, Pan B, Liu G, Jia MJ, Yan WF, Zhang WX, Chem. Eng. J., 215-216, 1 (2013)
  39. Cui W, Yuan X, Wu P, Zheng B, Zhang W, Jia M, RSC Adv., 5, 104330 (2015)
  40. Peng JX, Wang SD, Appl. Catal. B: Environ., 73(3-4), 282 (2007)
  41. Tauster SJ, Fung SC, Baker RT, Horsley JA, Science, 211, 1121 (1981)
  42. Nagai Y, Hirabayashi T, Dohmae K, Takagi N, Minami T, Shinjoh H, Matsumoto S, J. Catal., 242(1), 103 (2006)
  43. Trueba M, Trasatti SP, Inorg. Chem., 17, 3393 (2005)
  44. Valero MC, Raybaud P, Sautet P, J. Phys. Chem. B, 110(4), 1759 (2006)
  45. Liu YL, Cen WL, Feng G, Chu YH, Kong DJ, Yin HQ, Appl. Surf. Sci., 313, 424 (2014)
  46. Zhu XF, Cheng B, Yu JG, Ho WK, Appl. Surf. Sci., 364, 808 (2016)
  47. Zhou P, Yu JG, Nie LH, Jaroniec M, J. Mater. Chem. A, 3, 10432 (2015)
  48. Ma MG, Zhu YJ, Xu ZL, Mater. Lett., 61, 1812 (2007)
  49. Shang NG, J. Phys. Chem. C, 114, 15837 (2010)
  50. Nie LH, Zheng YQ, Yu JG, J. Chem. Soc.-Dalton Trans., 43, 12935 (2014)
  51. Sing KSW, Pure Appl. Chem., 54, 2201 (1982)
  52. Moulder J, Stickle W, Sobol P, Bomben K, Chastain J (Eds.), Handbook of X-ray Photoelectron Spectroscopy, Perkm-Elmer Inc., Physical Electronics Division, Edoe Prairie, MN, 1992.
  53. Ma C, Chang Y, Ye W, Shang W, Wang C, J. Colloid Interface Sci., 317(1), 148 (2008)
  54. Digne M, Sautet P, Raybaud P, Euzen P, Toulhoat H, J. Catal., 226(1), 54 (2004)
  55. Digne M, Sautet P, Raybaud P, Euzen P, Toulhoat H, J. Catal., 211(1), 1 (2002)
  56. Li JR, Zhang RG, Wang BJ, Appl. Surf. Sci., 270, 728 (2013)
  57. Arana J, Cabo CGI, Dona-Rodriguez JM, Gonzalez-Diaz O, Heffera-Melian JA, Perez-Pena J, Appl. Surf. Sci., 239(1), 60 (2004)
  58. Ivanov EA, Popova GY, Chesalov YA, Andrushkevich TV, J. Mol. Catal. A-Chem., 312(1-2), 92 (2009)
  59. Chen D, Qu ZP, Shen SJ, Li XY, Shi Y, Wang Y, Fu Q, Wu JJ, Catal. Today, 175(1), 338 (2011)
  60. Li X, Yu JG, Jaroniec M, Chem. Soc. Rev., 45, 2603 (2016)
  61. Liu TZ, Li YY, Zhang H, Wang M, Fei XY, Duo SW, Chen Y, Pan J, Wang W, Appl. Surf. Sci., 357, 516 (2015)
  62. Chen L, Hua H, Yang Q, Hu CG, Appl. Surf. Sci., 327, 62 (2015)
  63. Hu B, Liu BS, Appl. Surf. Sci., 358, 412 (2015)