Selective acidic elution of Ca from sewage sludge ash for phosphorus recovery under pH control

B.H. Lim; Dong-Jin Kim

Journal of Industrial and Engineering Chemistry, Vol.46, 62-67, February, 2017

DOI10.1016/j.jiec.2016.10.016 Export Citation

Selective acidic elution of Ca from sewage sludge ash for phosphorus recovery under pH control

B.H. Lim, and Dong-Jin Kim^†

Department of Environmental Sciences and Biotechnology & Institute of Energy and Environment, Hallym University, Chuncheon, Gangwon 200-702, Republic of Korea

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Phosphorus (P) is recovered from sewage sludge ash (SSA) by selective HCl elution of Ca. Leaching and rearrangement of P were very fast and the amounts of leaching and recombination of P depend strongly on pH. pH control at 4.0 obtained selective elution ratio (Ca(%)/P(%)) of 20 by recombination of P to Al in SSA residue while it was 5.6 without pH control. XRD and element mass balance showed that Ca-P in the raw SSA was converted to Al-P complex during the acid pretreatment.

Keywords:Acid pretreatment;Ca elution;Phosphorus recovery;Sewage sludge ash

[References]

Cooper J, Lombardi R, Boardman D, Marquet CC, Resour. Conserv. Recycl., 57, 78 (2011)
Pastor L, Marti N, Bouzas A, Seco A, Bioresour. Technol., 99(11), 4817 (2008)
Takahashi M, Kato S, Shima H, Sarai E, Ichioka T, Hatyakawa S, Miyajiri H, Chemosphere, 44, 23 (2001)
Ottosen LM, Kirkelund GM, Jensen PE, Chemosphere, 91, 963 (2013)
Petzet S, Peplinski B, Bodkhe SY, Cornel P, Water Sci. Technol., 64, 693 (2011)
Adam C, Peplinski B, Michaelis M, Kley G, Simon FG, Waste Manage., 29, 1122 (2009)
Donatello S, Tong D, Cheeseman CR, Waste Manage., 30, 1634 (2010)
Petzet S, Peplinski B, Cornel P, Water Res., 46, 3769 (2012)
Stark K, Plaza E, Hultman B, Chemosphere, 62, 827 (2006)
Tejedor-Tejedor MI, Anderson MA, Langmuir, 6, 602 (1990)
Kabayama M, Sakiyama T, Kawasaki N, Nakamura T, Araki M, Tanada S, J. Chem. Eng. Jpn., 36(4), 499 (2003)
Gustafsson JP, Visual MINTEQ. Ver. 3.0, (2012) . http://vminteq.lwr.kth.se/.
Dimitar H, Claudia ED, Veselin K, Violeta S, Deyana G, Antonio C, Anal. Chim. Acta, 516, 187 (2004)
Kim W, Zhang QW, Saito F, J. Mater. Sci., 35(21), 5401 (2000)
Li W, Pierre-Louis AM, Kwon K, Kubicki JD, Strongin DR, Phillips BL, Geochem. Cosmochim., 107, 252 (2013)
Tanada S, Kabayama M, Kawasaki N, Sakiyama T, Nakamura T, Araki M, Tamura T, J. Colloid Interface Sci., 257(1), 135 (2003)
Wendling LA, Blomberg P, Sarlin T, Priha O, Arnold M, Appl. Geochem., 37, 157 (2013)
Huang X, Foster GD, Honeychuck RV, Schreifels JA, Langmuir, 25(8), 4450 (2009)

[Referenced By]

[1] Cooper J, Lombardi R, Boardman D, Marquet CC, Resour. Conserv. Recycl., 57, 78 (2011)

[2] Pastor L, Marti N, Bouzas A, Seco A, Bioresour. Technol., 99(11), 4817 (2008)

[3] Takahashi M, Kato S, Shima H, Sarai E, Ichioka T, Hatyakawa S, Miyajiri H, Chemosphere, 44, 23 (2001)

[4] Ottosen LM, Kirkelund GM, Jensen PE, Chemosphere, 91, 963 (2013)

[5] Petzet S, Peplinski B, Bodkhe SY, Cornel P, Water Sci. Technol., 64, 693 (2011)

[6] Adam C, Peplinski B, Michaelis M, Kley G, Simon FG, Waste Manage., 29, 1122 (2009)

[7] Donatello S, Tong D, Cheeseman CR, Waste Manage., 30, 1634 (2010)

[8] Petzet S, Peplinski B, Cornel P, Water Res., 46, 3769 (2012)

[9] Stark K, Plaza E, Hultman B, Chemosphere, 62, 827 (2006)

[10] Tejedor-Tejedor MI, Anderson MA, Langmuir, 6, 602 (1990)

[11] Kabayama M, Sakiyama T, Kawasaki N, Nakamura T, Araki M, Tanada S, J. Chem. Eng. Jpn., 36(4), 499 (2003)

[12] Gustafsson JP, Visual MINTEQ. Ver. 3.0, (2012) . http://vminteq.lwr.kth.se/.

[13] Dimitar H, Claudia ED, Veselin K, Violeta S, Deyana G, Antonio C, Anal. Chim. Acta, 516, 187 (2004)

[14] Kim W, Zhang QW, Saito F, J. Mater. Sci., 35(21), 5401 (2000)

[15] Li W, Pierre-Louis AM, Kwon K, Kubicki JD, Strongin DR, Phillips BL, Geochem. Cosmochim., 107, 252 (2013)

[16] Tanada S, Kabayama M, Kawasaki N, Sakiyama T, Nakamura T, Araki M, Tamura T, J. Colloid Interface Sci., 257(1), 135 (2003)

[17] Wendling LA, Blomberg P, Sarlin T, Priha O, Arnold M, Appl. Geochem., 37, 157 (2013)

[18] Huang X, Foster GD, Honeychuck RV, Schreifels JA, Langmuir, 25(8), 4450 (2009)