화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.51, 196-205, July, 2017
DOI10.1016/j.jiec.2017.02.032  Export Citation
Catalytic conversion of syngas to higher alcohols over mesoporous perovskite catalysts
Tae-Wan Kim1, 2, †, Freddy Kleitz3, Jong Won Jun1, Ho-Jeong Chae1, 2, and Chul-Ung Kim1, 2
  • 1Center for Convergent Chemical Process, Korea Research Institute of Chemical Technology, 141, Gajeong-ro, Yuseong-gu, Daejeon 34114, South Korea
  • 2Department of Advanced Materials and Chemical Engineering, University of Science and Technology (UST), 217 Gajeong-Ro, Daejeon 305-350, Yuseong, South Korea
  • 3Institute of Inorganic Chemistry—Functional Materials, University of Vienna, Währinger Strabe 42, 1090 Vienna, Austria, Australia
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Two types of mesoporous perovskite-type oxides (Meso-PTOs) were synthesized by combining a templated synthesis and a citrate complex method. The Meso-PTO catalysts exhibited superior catalytic activity in the higher alcohols synthesis from syngas compared to the bulk-PTO, likely due to the increased dispersion of active sites on the high surface of the Meso-PTOs. Moreover, the Meso-PTOs show higher productivity for C3 and C4 alcohols as well as C2+ oxygenates. Among the two Meso-PTOs developed here, the mesoporous LaFe0.7Cu0.3O3 catalyst was capable of significant suppression of the methanation reaction and better selectivity to higher alcohols compared to the mesoporous LaCo0.7Cu0.3O3 catalyst.
Keywords:Mesoporous material;Mixed alcohols;Syngas to alcohols;Nanocast;Perovskites
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