화학공학소재연구정보센터
Macromolecular Research, Vol.25, No.6, 629-634, June, 2017
A Hierarchically Porous Polyimide Composite Prepared by One-Step Condensation Reaction inside a Sponge for Heterogeneous Catalysis
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A compressible polyimide composite having metal binding sites was prepared by in situ polymerization inside a melamine sponge. 1,3,5-Tris(4-aminophenyl) benzene and pyromellitic dianhydride were used as a triamine and a dianhydride monomer, respectively, to construct the microporous framework, and 5-amino- 1,10-phenanthroline was used as a functional monomer. The microporous polyimide containing phenanthroline groups (MPI-Phen) was obtained as insoluble powders. However, when the polymerization was carried out in the melamine sponge, MPI-Phen formed a coating layer on the sponge skeletons. The melamine sponge/ microporous polyimide composite (MS/MPI-Phen) had an open cellular structure with a hierarchical porosity composed of macropores between the sponge skeletons and meso- and micropores of the MPI-Phen coating. It showed the higher compressive strength than the melamine sponge, indicating the reinforcement by the microporous polymer. The BET surface areas of MPI-Phen and MS/MPI-Phen were 723 m2g-1 and 524 m2g-1, respectively. Pd(II) ions were coordinated with the phenanthroline groups of MS/MPI-Phen for heterogeneous catalysis. The catalytic activity of MS/MPI-Phen-Pd was evaluated for the Suzuki coupling reaction between bromobenzene and phenylboronic acid.
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