화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.52, 331-337, August, 2017
DOI10.1016/j.jiec.2017.04.006  Export Citation
Metal organic framework derived Cu.carbon composite: An efficient non-noble metal catalyst for reduction of hexavalent chromium and pendimethalin
Zubair Hasan1, Jinwoo Cho1, Jörg Rinklebe1, 2, Yong Sik Ok3, Dong-Wan Cho1, and Hocheol Song1, †
  • 1Department of Environment and Energy, Sejong University, Seoul 05006, South Korea
  • 2Soil- and Groundwater-Management, Pauluskirchstrabe 7, Wuppertal 42285 Germany
  • 3Korea Biochar Research Center, Kangwon National University, Chuncheon 24341, South Korea
E-mail:
A Cu.carbon composite was facilely synthesized via one step calcination of a Cu-based metal organic frameworks (MOF), HKUST-1, under N2 atmosphere. Physicochemical characteristics of the composite were examined with a series of spectroscopy and surface analyzer. The composite was used as a catalyst in the reduction of Cr(VI) and pendimethalin using HCOOH and NaBH4 as reductants, respectively. The composite was very efficient in both reduction reactions, completing the reactions in several minutes. The composite also exhibited a robust reusability in the completion of four repeated Cr(VI) reduction cycles, demonstrating its potential utility as an alternative to noble-metal catalysts.
Keywords:Metal-organic frameworks;Composites;Non-noble metal catalyst;Chromium;Pendimethalin
  1. Ferey G, Chem. Soc. Rev., 37, 191 (2008)
  2. Jhung SH, Khan NA, Hasan Z, CrystEngComm, 14, 7099 (2012)
  3. Anbia M, Sheykhi S, J. Ind. Eng. Chem., 19(5), 1583 (2013)
  4. Zhu J, Wang PC, Lu M, Appl. Catal. A: Gen., 477, 125 (2014)
  5. Li X, Zhang J, Li W, J. Ind. Eng. Chem., 44, 146 (2016)
  6. Nguyen LTL, Nguyen TT, Nguyen KD, Phan NTS, J. Hazard. Mater., 286, 187 (2015)
  7. Liu H, Ren X, Chen L, J. Ind. Eng. Chem., 34, 278 (2016)
  8. Hasan Z, Jhung SH, J. Hazard. Mater., 283, 329 (2015)
  9. Hasan Z, Jun JW, Jhung SH, Chem. Eng. J., 278, 265 (2015)
  10. Maleki A, Hayati B, Naghizadeh M, Joo SW, J. Ind. Eng. Chem., 28, 211 (2015)
  11. Chaikittisilp W, Ariga K, Yamauchi Y, J. Mater. Chem., 1, 14 (2013)
  12. Hasan Z, Cho DW, Nam IH, Chon CM, Song H, Materials, 9, 261 (2016)
  13. Pan L, Muhammad T, Ma L, Huang ZF, Wang SB, Wang L, Zou JJ, Zhang XW, Appl. Catal. B: Environ., 189, 181 (2016)
  14. Hasan Z, Cho DW, Chon CM, Yoon K, Song H, Chem. Eng. J., 298, 183 (2016)
  15. Li X, Zeng C, Jiang J, Ai L, J. Mater. Chem., 4, 7476 (2016)
  16. Lin KYA, Chen SY, ACS Sustain. Chem. Eng., 3, 3096 (2015)
  17. Michailides MK, Tekerlekopoulou AG, Akratos CS, Coles S, Pavlou S, Vayenas DV, J. Hazard. Mater., 281, 95 (2015)
  18. Celebi M, Yurderi M, Bulut A, Kaya M, Zahmakiran M, Appl. Catal. B: Environ., 180, 53 (2016)
  19. Yadav M, Xu Q, Chem. Commun., 49, 3327 (2013)
  20. Elliott DW, Zhang W, Environ. Sci. Technol., 35, 4922 (2001)
  21. Stearns DM, Kennedy LJ, Courtney KD, Giangrande PH, Phieffer LS, Wetterhahn KE, Biochemistry, 34, 910 (1995)
  22. Voitkun V, Zhitkovich A, Costa M, Nucleic Acids Res., 26, 2024 (1998)
  23. Vincent JB, Acc. Chem. Res., 33, 503 (2000)
  24. Mao K, Chen Y, Wu Z, Zhou X, Shen A, Hu J, J. Agric. Food Chem., 62, 10638 (2014)
  25. Hakala JA, Chin YP, J. Agric. Food Chem., 58, 12840 (2010)
  26. Dai Y, Hu YC, Jiang BJ, Zou JL, Tian GH, Fu HG, J. Hazard. Mater., 309, 249 (2016)
  27. Choi J, Jung Y, Lee W, Korean J. Chem. Eng., 25(4), 764 (2008)
  28. Jung Y, Choi J, Lee W, Chemosphere, 68, 1968 (2007)
  29. Kim C, Zhou Q, Deng B, Thornton EC, Xu H, Environ. Sci. Technol., 35, 2219 (2001)
  30. Pezzin SH, Rivera JFL, Collins CH, Collins KE, J. Braz. Chem. Soc., 15, 58 (2004)
  31. Yadav M, Akita T, Tsumori N, Xu Q, J. Mater. Chem., 22, 12582 (2012)
  32. Wu X, Xiao J, Chem. Commun. (2007) 2449.
  33. Godinez-Salomon F, Arce-Estrada E, Hallen-Lopez M, Int. J. Electrochem. Sci., 7, 2566 (2012)
  34. Dandapat A, Jana D, De G, Appl. Catal. A: Gen., 396(1-2), 34 (2011)
  35. Omole MA, K'Owino IO, Sadik OA, Appl. Catal. B: Environ., 76(1-2), 158 (2007)
  36. Wang ZH, Du YL, Zhang FY, Zheng ZX, Zhang XL, Feng QL, Wang CM, Mater. Chem. Phys., 140(1), 373 (2013)
  37. Moza PN, Husterrt K, Pal S, Sukul P, Chemosphere, 25, 1675 (1992)
  38. Li Y, Wang Q, Liu P, Yang X, Dun G, Liu Y, Ceram. Int., 41, 4248 (2015)
  39. Jiang JG, Chen H, Wang Z, Bao LK, Qiang YW, Guan SY, Chen JD, J. Colloid Interface Sci., 452, 54 (2015)
  40. Biesinger MC, Lau LWM, Gerson AR, Smart RSC, Appl. Surf. Sci., 257(3), 887 (2010)
  41. Hamid S, Bae S, Lee W, Amin MT, Alazba AA, Ind. Eng. Chem. Res., 54(24), 6247 (2015)
  42. Valvo M, Rehnlund D, Lafont U, Hahlin M, Edstrom K, Nyholm L, J. Mater. Chem., 2, 9574 (2014)
  43. Park J, Lim K, Ramsier RD, Kang YC, Bull. Korean Chem. Soc., 32, 3395 (2011)
  44. Robert T, Bartel M, Offergeld G, Surf. Sci., 33, 123 (1972)
  45. Rajumon MK, Prabhakaran K, Rao CNR, Surf. Sci., 233, L237 (1990)
  46. Gonzalez-Dominguez JM, Castell P, Bespin-Gascon S, Anson-Casaos A, Diez-Pascual AM, Gomez-Fatou MA, Benito AM, Maser WK, Martinez MT, J. Mater. Chem., 22, 21285 (2012)
  47. Zhang R, Liu H, Wang B, Ling L, J. Phys. Chem., 116, 22266 (2012)
  48. Mori K, Dojo M, Yamashita H, ACS Catal., 3, 1114 (2013)
  49. Fu GT, Jiang X, Wu R, Wei SH, Sun DM, Tang YW, Lu YH, Chen Y, ACS Appl. Mate. Interfaces, 6, 22790 (2014)