석유계 바인더 피치의 β-resin이 탄소블럭의 밀도에 미치는 영향

김경훈; 이상민; 안동해; 이영석; Kyung Hoon Kim; Sangmin Lee; Donghae An; Young-Seak Lee

Applied Chemistry for Engineering, Vol.28, No.4, 432-436, August, 2017

DOI10.14478/ace.2017.1035 Export Citation

석유계 바인더 피치의 β-resin이 탄소블럭의 밀도에 미치는 영향

Effect of β-Resin of Petroleum-based Binder Pitch on Density of Carbon Block

김경훈, 이상민, 안동해, 이영석^†

충남대학교 응용화학공학과

Kyung Hoon Kim, Sangmin Lee, Donghae An, and Young-Seak Lee^†

Department of Chemical Engineering and Applied Chemistry, Chungnam National University, Daejeon 34134, Korea

E-mail:

Carbon blocks were prepared by compression molding process using the mixture of isotropic cokes and binder pitches, which were reformed with different β-resin contents from pyrolysis fuel oil. Physical and chemical properties and also thermal behavior of binder pitches were investigated through elemental analysis, FT-IR and thermogravimetric analysis, respectively. The adhesion of binder pitches to isotropic coke particles was evaluated from SEM images of the fracture surface of carbon blocks. From these results, it is shown that the adhesion between the cokes and binder was enhanced by increasing the β -resin content of binder pitches. The density of the carbon block after carbonization also increased from 1.325 to 1.383 g/cm3 by increasing the β-resin content of binder pitches from 1.4 to 20.1%.

Keywords:carbon block;binder pitch;β-resin;pyrolysis fuel oil

[References]

Savage E, Carbon-Carbon Composites, 323-354, Chapman & Hall, London, UK (1993).
Zhao Y, Shi J, Wang H, Tao Z, Liu Z, Guo Q, Liu L, Carbon, 51, 427 (2013)
Mochida I, Fujiura R, Kojima T, Sakamoto H, Yoshimura T, Carbon, 33, 265 (1995)
Lee SM, Kang DS, Roh JS, Carbon Lett., 16, 135 (2015)
Wang YG, Korai Y, Mochida I, Carbon, 37, 1049 (1999)
Park MS, Cho S, Jeong E, Lee YS, J. Ind. Eng. Chem., 23, 27 (2015)
Lee SM, Kang DS, Kim WS, Roh JS, Carbon Lett., 15, 142 (2014)
Kim JH, Lee YS, J. Ind. Eng. Chem., 30, 127 (2015)
Yingquan L, Zhengde Z, Chaoquan D, Yusheng S, Mater. Charact., 44, 425 (2000)
Ko S, Lee CW, Im JS, J. Ind. Eng. Chem., 36, 125 (2016)
Chevarin F., Azari K., Ziegler D., Gauvin R., Fafard M., Alamdari H., Fuel, 183, 123 (2016)
Hussain SN, Trzcinski AP, Asghar HMA, Sattar H, Brown NW, Roberts EPL, J. Ind. Eng. Chem., 44, 216 (2016)
Lee SM, Kang DS, Kim HS, Roh JS, Carbon Lett., 16, 132 (2015)
Honda H, Abe T, J. Jpn. Pet. Inst., 18, 758 (1975)
Yang JY, Park SH, Park SJ, Seo MK, Appl. Chem. Eng., 26(4), 406 (2015)
Metzinger T, Huttinger K, Carbon, 35, 885 (1997)
Yuan G, Li X, Dong Z, Xiong X, Rand B, Cui Z, Cong Y, Zhang J, Li Y, Zhang Z, Carbon, 68, 413 (2014)
Ball DR, Carbon, 16, 205 (1978)
Jung MJ, Ko Y, Lee YS, Appl. Chem. Eng., 26(2), 224 (2015)
Wombles RH, Kiser MD, Essential Readings in Light Metals: Electrode Technology for Aluminum Production, Volume 4, 246-250, Springer (2016).
Baron JT, McKinney SA, Wombles RH, Essential Readings in Light Metals: Electrode Technology for Aluminum Production, Volume 4, 177-181, Springer (2016).
Alcaniz-Monge J, Cazorla-Amoros D, Linares-Solano A, Oya A, Sakamoto A, Hosm K, Carbon, 35, 1079 (1997)
Zhang W, Andersson JT, Rader HJ, Mullen K, Carbon, 95, 672 (2015)
Kanno K, Yoon KE, Fernandez JJ, Mochida I, Fortin F, Korai Y, Carbon, 32, 801 (1994)
Fernandez J, Figueiras A, Granda M, Bermejo J, Menendez R, Carbon, 33, 295 (1995)
Jung JY, Park MS, Kim MI, Lee YS, Carbon Lett., 15, 262 (2014)
Yamada Y, J. Jpn. Pet. Inst., 24, 71 (1981)

[Referenced By]

[1] Savage E, Carbon-Carbon Composites, 323-354, Chapman & Hall, London, UK (1993).

[2] Zhao Y, Shi J, Wang H, Tao Z, Liu Z, Guo Q, Liu L, Carbon, 51, 427 (2013)

[3] Mochida I, Fujiura R, Kojima T, Sakamoto H, Yoshimura T, Carbon, 33, 265 (1995)

[4] Lee SM, Kang DS, Roh JS, Carbon Lett., 16, 135 (2015)

[5] Wang YG, Korai Y, Mochida I, Carbon, 37, 1049 (1999)

[6] Park MS, Cho S, Jeong E, Lee YS, J. Ind. Eng. Chem., 23, 27 (2015)

[7] Lee SM, Kang DS, Kim WS, Roh JS, Carbon Lett., 15, 142 (2014)

[8] Kim JH, Lee YS, J. Ind. Eng. Chem., 30, 127 (2015)

[9] Yingquan L, Zhengde Z, Chaoquan D, Yusheng S, Mater. Charact., 44, 425 (2000)

[10] Ko S, Lee CW, Im JS, J. Ind. Eng. Chem., 36, 125 (2016)

[11] Chevarin F., Azari K., Ziegler D., Gauvin R., Fafard M., Alamdari H., Fuel, 183, 123 (2016)

[12] Hussain SN, Trzcinski AP, Asghar HMA, Sattar H, Brown NW, Roberts EPL, J. Ind. Eng. Chem., 44, 216 (2016)

[13] Lee SM, Kang DS, Kim HS, Roh JS, Carbon Lett., 16, 132 (2015)

[14] Honda H, Abe T, J. Jpn. Pet. Inst., 18, 758 (1975)

[15] Yang JY, Park SH, Park SJ, Seo MK, Appl. Chem. Eng., 26(4), 406 (2015)

[16] Metzinger T, Huttinger K, Carbon, 35, 885 (1997)

[17] Yuan G, Li X, Dong Z, Xiong X, Rand B, Cui Z, Cong Y, Zhang J, Li Y, Zhang Z, Carbon, 68, 413 (2014)

[18] Ball DR, Carbon, 16, 205 (1978)

[19] Jung MJ, Ko Y, Lee YS, Appl. Chem. Eng., 26(2), 224 (2015)

[20] Wombles RH, Kiser MD, Essential Readings in Light Metals: Electrode Technology for Aluminum Production, Volume 4, 246-250, Springer (2016).

[21] Baron JT, McKinney SA, Wombles RH, Essential Readings in Light Metals: Electrode Technology for Aluminum Production, Volume 4, 177-181, Springer (2016).

[22] Alcaniz-Monge J, Cazorla-Amoros D, Linares-Solano A, Oya A, Sakamoto A, Hosm K, Carbon, 35, 1079 (1997)

[23] Zhang W, Andersson JT, Rader HJ, Mullen K, Carbon, 95, 672 (2015)

[24] Kanno K, Yoon KE, Fernandez JJ, Mochida I, Fortin F, Korai Y, Carbon, 32, 801 (1994)

[25] Fernandez J, Figueiras A, Granda M, Bermejo J, Menendez R, Carbon, 33, 295 (1995)

[26] Jung JY, Park MS, Kim MI, Lee YS, Carbon Lett., 15, 262 (2014)

[27] Yamada Y, J. Jpn. Pet. Inst., 24, 71 (1981)