Calcium extraction from steelmaking slag and production of precipitated calcium carbonate from calcium oxide for carbon dioxide fixation

Sang Moon Lee; Sang Hyun Lee; Soon Kwan Jeong; Min Hye Youn; Dinh Duc Nguyen; Soon Woong Chang; Sung Su Kima

Journal of Industrial and Engineering Chemistry, Vol.53, 233-240, September, 2017

DOI10.1016/j.jiec.2017.04.030 Export Citation

Calcium extraction from steelmaking slag and production of precipitated calcium carbonate from calcium oxide for carbon dioxide fixation

Sang Moon Lee, Sang Hyun Lee, Soon Kwan Jeong¹, Min Hye Youn¹, Dinh Duc Nguyen, Soon Woong Chang, and Sung Su Kima^†

Department of Environmental Energy Engineering, Department of Environmental Energy Engineering, 94-6 San, Iui-dong, Youngtong-ku, Suwon-si, Gyeonggi-do 442-760, Republic of Korea
¹Green Energy Process Laboratory, Korea Institute of Energy Research, Daejeon 305-343, Republic of Korea

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We investigate the effect of ball milling and heat treatment on slag particle size, revealing that this parameter significantly influences the efficiency of calcium extraction. The efficiency and morphological properties of precipitated calcium carbonate (PCC) produced from calcium oxide were investigated for different extraction solvent, temperatures, CO2 injection rate and solvent concentration. As a result, ammonium chloride was determined to be the best extraction solvent for PCC production. Initial rate of PCC production is improved with increasing solvent concentrations and CO2 injection rate. The precipitated CaCO3 could be obtained in three different polymorphic forms, depending on the Gibbs free energy.

Keywords:Steelmaking slag;Calcium extraction;Precipitated calcium carbonate (PCC);Ammonium chloride

[References]

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Mattila HP, Grigaliunaite I, Zevenhoven R, Chem. Eng. J., 192, 77 (2012)
O’Connor WK, Dahlin DC, Rush GE, Miner. Metall. Process., 19(2), 95 (2002)
O’Connor WK, Dahlin DC, Turner PC, Walters R, Technology, 78, 115 (1999)
Hall C, Large DJ, Adderley B, West HM, Miner. Eng., 65, 156 (2014)
Kim Y, Worrell E, Energy Policy, 30(10), 827 (2002)
Eloneva S, Said A, Fogelholm CJ, Zevenhoven R, Appl. Energy, 90(1), 329 (2012)
Said A, Mattila HP, Jarvinen M, Zevenhoven R, Appl. Energy, 112, 765 (2013)
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Bao WJ, Li HQ, Zhang Y, Ind. Eng. Chem. Res., 49(5), 2055 (2010)
Teir S, Eloneva S, Fogelholm CJ, Zevenhoven R, Energy, 32(4), 528 (2007)
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Yildirim IZ, J. Mater. Civ. Eng., 16, 230 (2015)
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Kakizawa M, Yamasaki A, Yanagisawa Y, Energy, 26(4), 341 (2001)
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[Referenced By]

[1] Sun Y, Yao MS, Zhang JP, Yang G, Chem. Eng. J., 173(2), 437 (2011)

[2] Newall PS, Clarke SJ, Haywood HM, Scholes H, Clarke NR, King PA, Report PH2/17 for IEA Greenhouse Gas R&D Programme, CSMA Consultants Ltd, Cornwall, UK, 2000.

[3] Eloneva S, Teir S, Salminen J, Fogelholm CJ, Zevenhoven R, Energy, 33(9), 1461 (2008)

[4] Mattila HP, Grigaliunaite I, Zevenhoven R, Chem. Eng. J., 192, 77 (2012)

[5] O’Connor WK, Dahlin DC, Rush GE, Miner. Metall. Process., 19(2), 95 (2002)

[6] O’Connor WK, Dahlin DC, Turner PC, Walters R, Technology, 78, 115 (1999)

[7] Hall C, Large DJ, Adderley B, West HM, Miner. Eng., 65, 156 (2014)

[8] Kim Y, Worrell E, Energy Policy, 30(10), 827 (2002)

[9] Eloneva S, Said A, Fogelholm CJ, Zevenhoven R, Appl. Energy, 90(1), 329 (2012)

[10] Said A, Mattila HP, Jarvinen M, Zevenhoven R, Appl. Energy, 112, 765 (2013)

[11] Said A, Mattila O, Eloneva S, Jarvinen M, Chem. Eng. Prog., 89, 1 (2015)

[12] Bao WJ, Li HQ, Zhang Y, Ind. Eng. Chem. Res., 49(5), 2055 (2010)

[13] Teir S, Eloneva S, Fogelholm CJ, Zevenhoven R, Energy, 32(4), 528 (2007)

[14] Zevenhoven R, Fagerlund J, Wiklund A, Nduagu E, Forsman AM, Falt M, Mattila HP, Int. Flame Res. Found. (2009) 1.

[15] Kodama S, Nishimoto T, Yamamoto N, Yogo K, Yamada K, Energy, 33(5), 776 (2008)

[16] Eloneva S, Puheloinen EM, Kanerva J, Ekroos A, Zevenhoven R, Fogelholm CJ, J. Clean Prod., 18, 1833 (2010)

[17] Yildirim IZ, J. Mater. Civ. Eng., 16, 230 (2015)

[18] Navarro C, Diaz M, Garcia MAV, Environ. Sci. Technol., 44, 5383 (2010)

[19] Mazzotti M, Carbon Dioxide Capture and Storage, Cambridge University Press, Cambridge, UK, New York, 2005 (Chapter 7).

[20] Kakizawa M, Yamasaki A, Yanagisawa Y, Energy, 26(4), 341 (2001)

[21] Iizuka A, Fujii M, Yamasaki A, Yanagisawa Y, Ind. Eng. Chem. Res., 43(24), 7880 (2004)

[22] Park AHA, Fan LS, Chem. Eng. Sci., 59(22-23), 5241 (2004)