화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.55, 164-172, November, 2017
DOI10.1016/j.jiec.2017.06.041  Export Citation
Heavy metal remediation via poly(3,4-ethylene dioxythiophene) deposition onto neat and sulfonated nonwoven poly(ether sulfone)
Zahra Mohamadi1, and Amir Abdolmaleki1, 2, †
  • 1Department of Chemistry, Isfahan University of Technology, Isfahan 84156-83111, Islamic Republic of Iran
  • 2Department of Chemistry, College of Sciences, Shiraz University, Shiraz 71467-13565, Islamic Republic of Iran
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Poly(ether sulfone) (PES) and sulfonated poly(ether sulfone) (SPES) nanofiber mats were synthesized by electrospinning and modified via the in-situ polymerization of poly(3,4-ethylene dioxythiophene) (PEDOT) on nonwoven (NW) electrospun PES and SPES mats. Chelating property of the obtained nanofiber mats were evaluated (for Pb(II), Cd(II) and Cr(VI) ions). The adsorption capacity was influenced by pH, concentration and contact time and followed a pseudo-second-order kinetics model (Freundlich model). The adsorption capacities of NW PEDOT/SPES mats were remarkably greater than NW PEDOT/ PES mats. The charge transport characteristics electrical impedance (EIS) results indicated that they were sensitive to the nature of adsorbed metal ions.
Keywords:Nanofiber;Poly(ether sulfone);Sulfonated poly(ether sulfone);Poly(3,4-ethylene dioxythiophene);Heavy metal
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