화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.55, 204-214, November, 2017
DOI10.1016/j.jiec.2017.06.047  Export Citation
Diisopropyldithiophosphoric acid-impregnated macroporous non-ionogenic styrene-divinylbenzene polymeric sorbent (Porolas) for effective copper extraction
Shahlo S. Daminova1, Zukhra C. Kadirova1, †, Khasan T. Sharipov1, Olga V. Stoyko2, Stanislav A. Chepulsky2, Adewale Adewuyi3, and Mirabbos Hojamberdiev4, 5, †
  • 1Department of Silicate Materials and Rare Earth and Noble Metals, Tashkent Institute of Chemical Technology, Navoi Street 32, Tashkent 100011, Uzbekistan
  • 2Department of Chemistry, National University of Uzbekistan, Vuzgorodok, Tashkent 100174, Uzbekistan
  • 3Department of Chemical Sciences, Faculty of Natural Sciences,, Redeemer’s University, Mowe, Ogun State, Nigeria
  • 4Department of Natural and Mathematic Sciences, Turin Polytechnic University in Tashkent, Kichik Halqa Yo’li 17, Tashkent 100095, Uzbekistan
  • 5Department of Materials Physics, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603, Japan
E-mail:,
The extraction and sorption of copper from wastewaters can be improved by applying solvent- impregnated resins (SIRs) with chelating organic extractant. The SIRs are capable of increasing the sorption capacity of expensive ion-exchange resin in order to enhance the performance of traditional liquid.liquid extraction by organic solvents thus reducing copper pollution in water. In this present study, macroporous non-ionogenic styrene-divinylbenzene polymeric sorbent (Porolas) matrix was impregnated with diisopropyldithiophosphoric acid (DIPDTP) to enhance Cu2+ sorption in aqueous system. The influence of pore-filling degree (0-100%) by DIPDTP on copper sorption from aqueous chloride solution (pH = 1.95-10.7) was also evaluated. Higher degree of pore-filling by DIPDTP led to a significant decrease of the specific surface area (SBET) of the DIPDTP-Porolas sorbents, confirming an effective impregnation. The Cu2+ adsorption isotherm fitted well for Freundlich isotherm, and the maximum KF (8.45 g L-1) was obtained for 50% DIPDTP-Porolas with 97-99% Cu2+ uptake due to the formation of Cu2+ -complexes, CuCltL2-t(HL)q. The Cu2+ adsorption kinetic followed pseudo-second-order kinetic model at pH = 4-5 while the Lemna minor ecotoxicity test revealed absence of toxic secondary pollution of wastewater. The DIPDTP-impregnated Porolas was found to be an efficient sorbent for simple, safe, and environment-friendly extraction of Cu2+ from industrial wastewaters using small amount of organic solvent.
Keywords:Styrene-divinylbenzene polymeric resin;Porolas;Diisopropyldithiophosphoric acid;Copper extraction;Macroporosity
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