Niobium carbide/carbon nanotubular porous structures have been prepared using electrospinning and used as electrocatalyst supports for proton exchange membrane fuel cells. They were functionalised with 3.1 nm Pt particles synthesised by a microwave-assisted polyol method and characterised for their electrochemical properties. The novel NbC-based electrocatalyst demonstrated electroactivity towards the oxygen reduction reaction as well as greater stability over high potential cycling than a commercial carbon-based electrocatalyst. Pt/Nbc/c was integrated at the cathode of a membrane electrode assembly and characterised in a single fuel cell showing promising activity and power density. (C) 2017 Elsevier B.V. All rights reserved.