Adsorption, aggregation and wetting behaviors of biodegradable surfactant: Perfluoropolyether quaternary ammonium salt

Jixian Shen; Yanyun Bai; Qiwen Yin; Wanxu Wang; Xiaoyuan Ma; Guoyong Wang

Journal of Industrial and Engineering Chemistry, Vol.56, 82-89, December, 2017

DOI10.1016/j.jiec.2017.06.048 Export Citation

Adsorption, aggregation and wetting behaviors of biodegradable surfactant: Perfluoropolyether quaternary ammonium salt

Jixian Shen, Yanyun Bai, Qiwen Yin, Wanxu Wang, Xiaoyuan Ma, and Guoyong Wang^†

China Research Institute of Daily Chemical Industry, Taiyuan 030001, PR China

E-mail:

A novel cationic fluorinated surfactant, (PFP-AI), was synthesized via amidation and quaterisation successively with perfluorinated acyl fluride (PFPF) as starting material. Their structure was analyzed by FT-IR, 1H NMR and 19F NMR. The TG indicated the PFP-AI possess thermal stability with initiation decomposition temperatures about 217 °C. The physicochemical properties of PFP-AI were studied systematically by equilibrium surface tension, dynamic surface tension, dynamic light scatting measurement (DLS) and transmission electron microscopy (TEM). The results revealed the PFP-AI exhibited high surface activity (γcmc = 16.4 mN/m) and could aggregate into vesicles at the concentration of 4.15 mmol/L. Furthermore, contact angle measurements demonstrated that PFP-AI exhibited efficient wettability on the hydrophobic surface.

Keywords:Fluorinated surfactant;Quaternary ammonium salt;Perfluoropolyether;Aggregation behavior

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[12] Mendenhall JD, Lin S, Blankschtein D, Aiche Meeting, (2009).

[13] Salam A, Lucia LA, Jameel H, Cellulose, 22, 397 (2015)

[14] Loos R, Wollgast J, Huber T, Hanke G, Anal. Bioanal. Chem., 387, 1469 (2007)

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[23] Bodduri VDV, Chirumarry S, Lim JM, et al., J. Fluor. Chem., 163, 42Y (2014)

[24] Yin Q, Xue W, Bai Y, Wang W, Ma X, Du Z, Wang G, J. Ind. Eng. Chem., 42, 63 (2016)

[25] Kettwich SC, Kappagantula K, Kusel BS, et al., Thermochim. Acta, 45 (2014).

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[31] Rosen MJ, Colloids Surf., 40, 347 (2004)

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[38] Szymczyk K, J. Colloid Interface Sci., 363(1), 223 (2011)

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