화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.56, 74-81, December, 2017
DOI10.1016/j.jiec.2017.06.013  Export Citation
Upgrading of sawdust pyrolysis oil to hydrocarbon fuels using tungstate-zirconia-supported Ru catalysts with less formation of cokes
Inho Kim1, 2, Adid Adep Dwiatmoko1, 2, Jae-Wook Choi1, Dong Jin Suh1, 3, Jungho Jae1, 2, Jeong-Myeong Ha1, 2, †, and Jae-Kon Kim4
  • 1Clean Energy Research Center, Korea Institute of Science and Technology, Seoul 02792, Republic of Korea
  • 2Division of Energy & Environment Technology, KIST School, Korea University of Science and Technology, Seoul 02792, Republic of Korea
  • 3Green School (Graduate School of Energy and Environment), Korea University, Seoul 02841, Republic of Korea
  • 4Research Institute of Petroleum Technology, Korea Petroleum Quality & Distribution Authority, Chungcheongbuk-do 28115, Republic of Korea
E-mail:
Using a continuous flow reactor, bio-oil prepared by the pyrolysis of sawdust was upgraded to produce petroleum-like deoxygenated hydrocarbon fuels. Dispersed tiny bio-char particles in the raw bio-oil were removed by extraction using diethyl ether to suppress solid-particle-nucleated coking. Noble metal catalysts, instead of molybdenum-based catalysts, were selected to avoid the continuous addition of sulfur compounds. Among the catalysts, tungstate-zirconia-supported Ru catalysts (Ru/WZr) exhibited high hydrodeoxygenation activity and less formation of cokes, which characteristics are important in the development of feasible upgrading processes. The investigation of catalysts used in this study demonstrates that the larger quantity of Brønsted acid sites compared to Lewis acid sites suppresses the formation of cokes.
Keywords:Hydrodeoxygenation;Bio-oil;Upgrading;Catalyst;Coke
  1. Jacobson K, Maheria KC, Dalai AK, Renew. Sust. Energ. Rev., 23, 91 (2013)
  2. Vitolo S, Bresci B, Seggiani M, Gallo M, Fuel, 80, 17 (2001)
  3. Zhang XH, Long JX, Kong W, Zhang Q, Chen LG, Wang TJ, Ma LL, Li YP, Energy Fuels, 28(4), 2562 (2014)
  4. Gollakota AR, Reddy M, Subramanyam MD, Kishore N, Renew. Sust. Energ. Rev., 58, 1543 (2016)
  5. Lee Y, Choi JW, Suh DJ, Ha JM, Lee CH, Appl. Catal. A: Gen., 506, 288 (2015)
  6. Kim SK, Lee HS, Hong MH, Lim JS, Kim J, ChemSusChem, 7, 492 (2014)
  7. Dwiatmoko AA, Zhou LP, Kim I, Choi JW, Suh DJ, Ha JM, Catal. Today, 265, 192 (2016)
  8. Dwiatmoko AA, Lee S, Ham HC, Choi JW, Suh DJ, Ha JM, ACS Catal., 5, 433 (2015)
  9. Yoon JS, Choi JW, Suh DJ, Lee K, Lee H, Ha JM, ChemCatChem, 7, 2669 (2015)
  10. Lee EH, Park RS, Kim H, Park SH, Jung SC, Jeon JK, Kim SC, Park YK, J. Ind. Eng. Chem., 37, 18 (2016)
  11. Shafaghat H, Rezaei PS, Daud WMAW, J. Ind. Eng. Chem., 35, 268 (2016)
  12. Zhang XH, Zhang Q, Wang TJ, Li BS, Xu Y, Ma LL, Fuel, 179, 312 (2016)
  13. ADJAYE JD, BAKHSHI NN, Fuel Process. Technol., 45(3), 161 (1995)
  14. ADJAYE JD, BAKHSHI NN, Fuel Process. Technol., 45(3), 185 (1995)
  15. Bridgwater AV, Cottam ML, Energy Fuels, 6, 113 (1992)
  16. Zhang XH, Wang TJ, Ma LL, Zhang Q, Jiang T, Bioresour. Technol., 127, 306 (2013)
  17. Elliott DC, Neuenschwander GG, Hart TR, ACS Sustain. Chem. Eng., 1, 389 (2013)
  18. Fan Y, Cai Y, Li X, Yin H, Xia J, J. Ind. Eng. Chem., 46, 139 (2017)
  19. Laurent E, Delmon B, J. Catal., 146(1), 281 (1994)
  20. Zhao C, Lercher JA, Angew. Chem.-Int. Edit., 124, 6037 (2012)
  21. Cordero-Lanzac T, Palos R, Arandes JM, Castano P, Rodriguez-Mirasol J, Cordero T, Bilbao J, Appl. Catal. B: Environ., 203, 389 (2017)
  22. Ardiyanti AR, Khromova SA, Venderbosch RH, Yakovlev VA, Melian-Cabrera IV, Heeres HJ, Appl. Catal. A: Gen., 449, 121 (2012)
  23. Liu SY, Zhu QQ, Guan QX, He LN, Li W, Bioresour. Technol., 183, 93 (2015)
  24. Zhang XH, Chen LG, Kong W, Wang TJ, Zhang Q, Long JX, Xu Y, Ma LL, Energy, 84, 83 (2015)
  25. Elliott DC, Hart TR, Neuenschwander GG, Rotness LJ, Olarte MV, Zacher AH, Solantausta Y, Energy Fuels, 26(6), 3891 (2012)
  26. Valle B, Aramburu B, Santiviago C, Bilbao J, Gayubo AG, Energy Fuels, 28(10), 6419 (2014)
  27. Tang Z, Lu Q, Zhang Y, Zhu XF, Guo QX, Ind. Eng. Chem. Res., 48(15), 6923 (2009)
  28. Wang JJ, Chang J, Fan J, Energy Fuels, 24, 3251 (2010)
  29. Barton DG, Soled SL, Iglesia E, Top. Catal., 6, 87 (1998)
  30. Hong YK, Lee DW, Eom HJ, Lee KY, Appl. Catal. B: Environ., 150, 438 (2014)
  31. Hong YK, Lee DW, Eom HJ, Lee KY, J. Mol. Catal. A-Chem., 392, 241 (2014)
  32. Marin-Flores OG, Karim AM, Wang Y, Catal. Today, 237, 118 (2014)
  33. dos Santos VC, Wilson K, Lee AF, Nakagaki S, Appl. Catal. B: Environ., 162, 75 (2015)
  34. Cheng J, Biomass to Renewable Energy Processes, CRC Press/Taylor & Francis, Boca Raton, FL, 2010.
  35. Rowley H, Reed WR, J. Am. Chem. Soc., 73, 2960 (1951)
  36. Elliott DC, Hart TR, Neuenschwander GG, Rotness LJ, Zacher AH, Environ. Progress Sustain. Energy, 28, 441 (2009)
  37. Zacher AH, Olarte MV, Santosa DM, Elliott DC, Jones SB, Green Chem., 16, 491 (2014)
  38. Lee CR, Yoon JS, Suh YW, Choi JW, Ha JM, Suh DJ, Park YK, Catal. Commun., 17, 54 (2012)
  39. Furimsky E, Massoth FE, Catal. Today, 52(4), 381 (1999)
  40. Mortensen PM, Grunwaldt JD, Jensen PA, Knudsen KG, Jensen AD, Appl. Catal. A: Gen., 407(1-2), 1 (2011)
  41. Emeis CA, J. Catal., 141, 347 (1993)
  42. Yoon JS, Lee Y, Ryu J, Kim YA, Park ED, Choi JW, Ha JM, Suh DJ, Lee H, Appl. Catal. B: Environ., 142-143, 668 (2013)
  43. Boyse RA, Ko EI, J. Catal., 171(1), 191 (1997)
  44. Barton DG, Shtein M, Wilson RD, Soled SL, Iglesia E, J. Phys. Chem. B, 103(4), 630 (1999)
  45. Lopez DE, Suwannakarn K, Bruce DA, Goodwin JG, J. Catal., 247(1), 43 (2007)
  46. Iglesia E, Barton DG, Soled SL, Miseo S, Baumgartner JE, Gates WE, Fuentes GA, Meitzner GD, Stud. Surf. Sci. Catal., 101, 533 (1996)
  47. Ramu S, Lingaiah N, Devi BLAP, Prasad RBN, Suryanarayana I, Prasad PSS, Appl. Catal. A: Gen., 276(1-2), 163 (2004)
  48. Barton DG, Soled SL, Meitzner GD, Fuentes GA, Iglesia E, J. Catal., 181(1), 57 (1999)
  49. Valigi M, Gazzoli D, Pettiti I, Mattei G, Colonna S, De Rossi S, Ferraris G, Appl. Catal. A: Gen., 231(1-2), 159 (2002)
  50. Vaidyanathan N, Hercules DM, Houalla M, Anal. Bioanal. Chem., 373, 547 (2002)
  51. Wachs IE, Kim T, Ross EI, Catal. Today, 116(2), 162 (2006)