화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.37, 18-21, May, 2016
DOI10.1016/j.jiec.2016.03.019  Export Citation
Hydrodeoxygenation of guaiacol over Pt loaded zeolitic materials
Eun Hwa Lee, Rae-su Park1, Hannah Kim, Sung Hoon Park2, Sang-Chul Jung2, Jong-Ki Jeon3, Sang Chai Kim4, and Young-Kwon Park†
  • School of Environmental Engineering, University of Seoul, Seoul 130-743, Korea
  • 1Department of Bioenviromental & Chemical Engineering, Chosun College of Science & Technology, Gwangju 501-744, Korea
  • 2Department of Environmental Engineering, Sunchon National University, Suncheon 540-950, Korea
  • 3Department of Chemical Engineering, Kongju National University, Cheonan 330-717, Korea
  • 4Department of Environmental Education, Mokpo National University, Muan 534-729, Korea
E-mail:
Hydrodeoxygenation (HDO) of guaiacol in a batch-type reactor at 40 bar and 250 ℃ was investigated using six different catalysts, Pt/HZSM-5, Pt/Mesoporous Beta, Pt/HBeta, Pt/MMZBeta, Pt/Al-MCM-48, and Pt/Si-MCM-48. Among various catalysts, Pt/Mesoporous Beta and Pt/HBeta, which have both large pores and strong acid sites, showed guaiacol conversions larger than 90%. The main product species of HDO of guaiacol was cyclohexane. Meanwhile, Pt/Al-MCM-48 and Pt/MMZBeta, which are mesoporous catalysts with weak acid sites, led to lower guaiacol conversions than Pt/Mesoporous Beta and Pt/HBeta and the main product components were cyclohexane and 1,1-bicyclohexyl resulting from C-C coupling reactions.
Keywords:Hydrodeoxygenation;Bio-oil;Guaiacol;Mesoporous beta
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