화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.59, 149-159, March, 2018
DOI10.1016/j.jiec.2017.10.019  Export Citation
Aluminum carboxylate-based metal organic frameworks for effective adsorption of anionic azo dyes from aqueous media
Kyung-Won Jung1, Brian Hyun Choi2, 3, Chau Minh Dao2, 3, Young Jae Lee1, Jae-Woo Choi2, 3, Kyu-Hong Ahn2, and Sang-Hyup Lee2, 4, †
  • 1Department of Earth and Environmental Sciences, Korea University, 145 Anam-ro, Seongbuk-gu, Seoul 02841, South Korea
  • 2Center for Water Resources Cycle Research, Korea Institute of Science and Technology, 5 Hwarang-ro 14-gil, Seongbuk-gu, Seoul 02792, South Korea
  • 3Division of Energy and Environmental Engineering, KIST School, Korea University of Science and Technology, 5 Hwarang-ro 14-gil, Seongbuk-gu, Seoul 02792, South Korea
  • 4Green School, Korea University, 145 Anam-ro, Seongbuk-gu, Seoul 02841, South Korea
E-mail:
High quantities of synthetic dyes are prevalent in wastewater, which are disposed into the environment without proper treatment. In this work, two types of aluminum based metal-organic frameworks, Al-FA (fumaric acid) and Al-SA (succinic acid), were synthesized using water as the solvent and employed for the adsorption of mono and di-azo dyes. Al-SA exhibited superior affinities towards both substrates compared to those of Al-FA, with maximum adsorption capacities of 559.28 and 332.48 mg/g for mono and di-azo dyes, respectively. Overall findings insinuate that Al-SA can be considered as a promising candidate for efficient azo dye removing agent.
Keywords:Metal-organic frameworks;Fumaric acid;Succinic acid;Azo dyes;Adsorbents
  1. Yagub MT, Sen TK, Afroze S, Ang H, Adv. Colloid Interface Sci., 209, 172 (2014)
  2. Konicki W, Aleksandrzak M, Moszynski D, Mijowska E, J. Colloid Interface Sci., 496, 188 (2017)
  3. Jung KW, Choi BH, Hwang MJ, Jeong TU, Ahn KH, Bioresour. Technol., 219, 185 (2016)
  4. Tan KB, Vakili M, Hord BA, Poh PE, Abdullah AZ, Salamatinia B, Sep. Purif. Technol., 150, 229 (2015)
  5. Khan NA, Hasan Z, Jhung SH, J. Hazard. Mater., 244-245, 444 (2013)
  6. Ayati A, Shahrak MN, Tanhaei B, Sillanpaa M, Chemosphere, 160, 30 (2016)
  7. Rafatullah M, Sulaiman O, Hashim R, Ahmad A, J. Hazard. Mater., 177(1-3), 70 (2010)
  8. Hasan Z, Jhung SH, J. Hazard. Mater., 283, 329 (2015)
  9. Li M, Eddaoudi M, O’Keeffe M, Yaghi OM, Nature, 402, 276 (1999)
  10. James SL, Chem. Soc. Rev., 32, 276 (2003)
  11. Qiu JH, Feng Y, Zhang XF, Jia MM, Yao JF, J. Colloid Interface Sci., 499, 151 (2017)
  12. Yaghi OM, O’Keeffe M, Ockwig NW, Chae HK, Eddaoudi M, Nature, 423, 705 (2003)
  13. Li JR, Kuppler RJ, Zhou HC, Chem. Soc. Rev., 38, 1477 (2009)
  14. Roberts JM, Fini BM, Sarjeant AA, Farha OK, Hupp JT, Scheidt KA, J. Am. Ceram. Soc., 134, 3334 (2012)
  15. Cavka JH, Jakobsen S, Olsbye U, Guillou N, Lamberti C, Bordiga S, Lillerud KP, J. Am. Chem. Soc., 130(42), 13850 (2008)
  16. Loiseau T, Serre C, Huguenard C, Fink G, Taulelle F, Henry M, Bataille T, Ferey G, Chem. Eur. J., 10, 1373 (2004)
  17. Alvarez E, Guillou N, Martineau C, Bueken B, Van de Voorde B, Le Guillouzer C, Fabry P, Nouar F, Taulelle F, de Vos JSD, Chang K, Cho H, Ramsahye N, Devic T, Daturi M, Maurin G, Serre C, Angew. Chem.-Int. Edit., 54, 3664 (2015)
  18. Demessence A, D'Alessandro DM, Foo ML, Long JRJ, Am. Chem. Soc., 131, 8787 (2009)
  19. Ferey G, Mellot-Draznieks C, Serre C, Millange F, Dutour J, Surble S, Margiolaki I, Science, 309, 2040 (2005)
  20. Howarth AJ, Katz MJ, Wang TC, Platero-Prats AE, Chapman KW, Hupp JT, Farha OK, J. Am. Chem. Soc., 137(23), 7488 (2015)
  21. Huo SH, Yan XP, J. Mater. Chem., 22, 7449 (2012)
  22. He YC, Yang J, Kan WQ, Zhang HM, Liu YY, Ma JF, J. Mater. Chem., 3, 1675 (2015)
  23. Meng Q, Xin X, Zhang L, Dai F, Wang R, Sun D, J. Mater. Chem., 3, 24016 (2015)
  24. Zhang SR, Li J, Du DY, Qin JS, Li SL, He WW, Su ZM, Lan YQ, J. Mater. Chem., 3, 23426 (2015)
  25. Duan S, Li J, Liu X, Wang Y, Zeng S, Shao D, Hayat T, ACS Sustain. Chem. Eng., 4, 3368 (2016)
  26. Haque E, Jun JW, Jhung SH, J. Hazard. Mater., 185, 507 (2011)
  27. Zhu X, Li B, Yang J, Li Y, Zhao W, Shi J, Gu J, ACS Appl. Mater. Interfaces, 7, 223 (2015)
  28. Karmakar S, Dechnik J, Janiak C, De S, J. Hazard. Mater., 303, 10 (2016)
  29. Zhang NT, Yang X, Yu XY, Jia Y, Wang J, Kong LT, Jin Z, Sun B, Luo T, Liu JH, Chem. Eng. J., 252, 220 (2014)
  30. Lin KYA, Chen SY, Jochems AP, Mater. Chem. Phys., 160, 168 (2015)
  31. Wang B, Lv XL, Feng D, Xie LH, Zhang J, Li M, Xie Y, Li JR, Zhou HC, J. Am. Ceram. Soc., 138, 6204 (2016)
  32. Zhu BJ, Yu XY, Jia Y, Peng FM, Sun B, Zhang MY, Luo T, Liu JH, Huang XJ, J. Phys. Chem., 113, 8601 (2012)
  33. Ke F, Qiu LG, Yuan YP, Peng FM, Jiang X, Xie AJ, Shen YH, Zhu JF, J. Hazard. Mater., 196, 36 (2011)
  34. Fang QR, Yuan DQ, Sculley J, Li JR, Han ZB, Zhou HC, Inorg. Chem., 49(24), 11637 (2010)
  35. DeFuria MD, Zeller M, Genna DT, Cryst. Growth Des., 16, 3530 (2016)
  36. Mani MR, Chellaswamy R, Marathe YN, Pillai VK, RSC Adv., 6, 1907 (2016)
  37. Mani MR, Chellaswamy R, Marathe YN, Pillai VK, Chem. Commun., 51, 10026 (2015)
  38. Cazetta AL, Pezoti O, Bedin KC, Silva TL, Paesano A, Asefa T, Almeida VC, ACS Sustain. Chem. Eng., 4, 1058 (2016)
  39. Zhu X, Li B, Yang J, Li Y, Zhao W, Shi J, Gu J, ACS Appl. Mater. Interfaces, 7, 223 (2015)
  40. Zhu HY, Fu YQ, Jiang R, Jiang JH, Xiao L, Zeng GM, Zhao SL, Wang Y, Chem. Eng. J., 173(2), 494 (2011)
  41. Mittal A, Malviya A, Kaur D, Mittal J, Kurup L, J. Hazard. Mater., 148(1-2), 229 (2007)
  42. Ghorai S, Sarkar A, Raoufi M, Panda AB, Schonherr H, Pal S, ACS Appl. Mater. Interfaces, 6, 4766 (2014)
  43. Abramian L, El-Rassy H, Chem. Eng. J., 150(2-3), 403 (2009)
  44. Hsiu-Mei C, Ting-Chien C, San-De P, Hung-Lung C, J. Hazard. Mater., 161(2-3), 1384 (2009)
  45. Zhang G, Qu J, Liu H, Cooper AT, Wu R, Chemosphere, 68, 1058 (2007)
  46. GarciaER, Medina RL, Lozano MM, Perez IH, Valero MJ, Franco AMM, Materials, 7, 8037 (2014)
  47. Jung KW, Choi BH, Jeong TU, Ahn KH, Bioresour. Technol., 220, 672 (2016)
  48. Pethkar AV, Bhagat AP, Mater. Sci. Forum, 757, 285 (2013)
  49. Samarghandi MR, Zarrabi M, Amrane A, Soori MM, Sepher MN, Environ. Eng. Manage. J., 12, 2137 (2013)
  50. Kousha M, Daneshvar E, Dopeikar H, Taghavi D, Bhatnagar A, Chem. Eng. J., 179, 158 (2012)