화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.60, 268-278, April, 2018
DOI10.1016/j.jiec.2017.11.013  Export Citation
Well-defined nanostructured core.shell magnetic surface imprinted polymers (Fe3O4@SiO2@MIPs) for effective extraction of trace tetrabromobisphenol A from water
Qiong Wu1, Minna Li1, Zheng Huang1, Yanming Shao1, Lei Bai2, and Lincheng Zhou1, 3, †
  • 1State Key Laboratory of Applied Organic Chemistry, College of Chemistry and Chemical Engineering, Institute of Biochemical Engineering & Environmental Technology, Lanzhou University, Lanzhou 730000, PR China
  • 2College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou 730070, PR China
  • 3Zhongwei High-tech Institute of Lanzhou University, 755000, PR China
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Magnetic molecular imprinted polymers (MIPs) with well-defined core.shell nanostructure for extracting tetrabromobisphenol A (TBBPA) have been fabricated by surface molecular imprinting method. Fe3O4@SiO2@MIPs exhibit the good adsorption capacity, high recognition ability and fast kinetics to TBBPA. The maximum adsorption capacity of Fe3O4@SiO2@MIPs towards TBBPA is 88.3 mg g-1, which is 2.3 times as high as that of Fe3O4@SiO2@NIPs. Besides, the material has the short equilibrium time (40 min), the rapid magnetic separation (15.6 emu g-1, 20 s) and the high stability (the adsorption efficiency is at least 85% after seven cycles).
Keywords:Molecularly imprinted polymer;Surface molecular imprinting technique;Superparamagnetic;TBBPA;Selectivity recognition
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