화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.61, 133-141, May, 2018
DOI10.1016/j.jiec.2017.12.010  Export Citation
A novel process for leaching of metals from LiNi1/3Co1/3Mn1/3O2 material of spent lithium ion batteries: Process optimization and kinetics aspects
Qi Meng, Yingjie Zhang†, Peng Dong†, and Feng Liang
  • National and Local Joint Engineering Laboratory for Lithium-ion Batteries and Materials Preparation Technology, Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China
E-mail:,
A novel process of electrochemical cathode reduction has been developed for leaching of metals from spent LiNi1/3Co1/3Mn1/3O2 material. The leaching efficiencies of Li, Ni, Co and Mn reached to 100, 99.87, 99.58 and 99.82%, respectively with 1.5 mol/L malic acid and working voltage of 8 V at 300 r/min and 60 °C for 30 min. Kinetics analysis indicates that leaching process is controlled by surface chemical reaction. The Ea for Li, Ni, Co and Mn was 41.71, 42.83, 44.38 and 43.17 kJ/mol, respectively. Based on EIS analysis, leaching process is mainly controlled by charge transfer resistance of the surface chemical reaction.
Keywords:Spent LiNi1/3Co1/3Mn1/3O2 material;Leaching;Electrochemical cathode reduction;Kinetics;EIS
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