Effect of Electron Beam Irradiation on the Mechanical and Thermal Properties of Ternary Polyamide Copolymer

Chengwen Cui; Yong Zhang

Macromolecular Research, Vol.26, No.4, 359-364, April, 2018

DOI10.1007/s13233-018-6050-y Export Citation

Effect of Electron Beam Irradiation on the Mechanical and Thermal Properties of Ternary Polyamide Copolymer

Chengwen Cui, and Yong Zhang^†

School of Chemistry and Chemical Engineering, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai, 200240, P. R. China

E-mail:

In this study, the effect of electron beam irradiation on the thermal and mechanical properties of ternary polyamide copolymer (tPA) was investigated. The crosslinking of tPA induced by e-beam irradiation was carried out over a range of dose from 50 to 300 kGy with triallyl cyanurate (TAC), triallyl isocyanurate (TAIC), and N,N′-m-phenylene dismaleimide (HVA-2) as crosslinking co-agents. With increasing dose, the gel contents of tPA containing the co-agents increased more significantly than neat tPA. After the addition of 2.5 phr HVA-2 into tPA and the electron beam irradiation of 150 kGy, the gel content of tPA increased from 11% to 77%, which has a profound influence on the tensile strength, glass transition temperature, and thermal stability of tPA.

Keywords:electron beam irradiation;ternary polyamide copolymer;crosslinking co-agent

[References]

Chmielewski A, Haji-Saeid M, Radiat. Phys. Chem., 71, 17 (2004)
Svoboda P, Poongavalappil S, Theravalappil R, Svobodova D, Mokrejs P, Kolomaznik K, Ougizawa T, Inoue T, J. Appl. Polym. Sci., 121(1), 521 (2011)
Pramanik NK, Haldar R, Niyogi UK, Alam S, J. Macromol. Sci.-Pure Appl. Chem., 51, 296 (2014)
Rajeshbabu R, Gohs U, Naskar K, Mondal M, Wagenknecht U, Heinrich G, Macromol. Mater. Eng., 297, 659 (2012)
Valentine L, J. Polym. Sci. A: Polym. Chem., 23, 297 (1957)
Lugao AB, Hutzler B, Ojeda T, Tokumoto S, Siemens R, Makuuchi K, Villavicencio ALC, Radiat. Phys. Chem., 57, 389 (2000)
Charlesby A, Nature, 171, 167 (1953)
Lawton EJ, Bueche AM, Balwit JS, Nature, 172, 76 (1953)
Little K, Nature, 173, 680 (1954)
Bernstein BS, George O, Gyula O, Sebastian T, J. Polym. Sci. A: Polym. Chem., 3, 3405 (1965)
Dadbin S, Frounchi M, Goudarzi D, Polym. Degrad. Stabil., 89, 436 (2005)
Shin BS, Jeun JP, Kim HB, Kang PH, Polym. Korea, 35(1), 30 (2011)
Pramanik N, Haldar R, Niyogi U, Alam M, Defence Sci. J., 64, 281 (2014)
Burillo G, Adem E, Munoz E, Vasquez M, Radiat. Phys. Chem., 84, 140 (2013)
Adem E, Burillo G, Del Castillo L, Vasquez M, Avalos-Borja M, Marcos-Fernandez A, Radiat. Phys. Chem., 97, 165 (2014)
Huang H, Zhang X, Lu H, J. Macromol. Sci.-Phys., 46, 1105 (2007)
Shin BY, Kim JH, Radiat. Phys. Chem., 112, 88 (2015)
Nishi Y, Sato H, Takei H, Iwata K, J. Mater. Res., 24, 3503 (2009)
Imam MA, Jeelani S, Rangari VK, Gome MG, Moura EAB, Int. J. Nanosci., 15, 165000 (2016)
Pramanik N, Haldar R, Bhardwaj Y, Sabharwal S, Niyogi U, Khandal R, Radiat. Phys. Chem., 78, 199 (2009)
Pramanik NK, Haldar RS, Bhardwaj YK, Sabharwal S, Niyogi UK, Khandal RK, J. Appl. Polym. Sci., 122(1), 193 (2011)
Pramanik NK, Haldar R, Niyogi UK, Alam S, J. Macromol. Sci.-Pure Appl. Chem., 51, 296 (2014)
Imam MA, Gomes MG, Moura EAB, Jeelani S, Rangari VK, International SAMPE Technical Conference, 2013.
Linggawati A, Mohammad AW, Ghazali Z, Eur. Polym. J., 45, 2797 (2009)
Nasef MM, Saidi H, Dahlan KZM, Nucl. Instrum. Methods Phys. Res. Sect. B-Beam Interact. Mater. Atoms, 265, 168 (2007)
Liu F, Du CH, Zhu BK, Xu YY, Polymer, 48(10), 2910 (2007)
Kim H, Abdala AA, Macosko CW, Macromolecules, 43(16), 6515 (2010)
Wu W, Wan C, Wang S, Zhang Y, RSC Adv., 3, 26166 (2013)
Jin XD, Hu GS, Yang YF, Zhou XM, Wang BB, J. Adhes. Sci. Technol., 23(5), 779 (2009)
Zhou YH, Xue WL, Zeng ZX, Zhu WY, Li ZL, J. Adhes. Sci. Technol., 29(7), 670 (2015)
Sengupta R, Sabharwal S, Tikku VK, Somani AK, Chaki TK, Bhowmick AK, J. Appl. Polym. Sci., 99(4), 1633 (2006)
Charlesby A, Pinner S, Proc. R. Soc. Lond. A, 249, 367 (1959)
Sengupta R, Tikku V, Somani AK, Chaki TK, Bhowmick AK, Radiat. Phys. Chem., 72, 625 (2005)
Nasef MM, Saidi H, Dahlan KZM, Polym. Degrad. Stabil., 75, 85 (2002)
Ye HJ, Yang L, Shao WZ, Li Y, Sun SB, Zhen L, RSC Adv., 4, 13525 (2014)

[Referenced By]

[1] Chmielewski A, Haji-Saeid M, Radiat. Phys. Chem., 71, 17 (2004)

[2] Svoboda P, Poongavalappil S, Theravalappil R, Svobodova D, Mokrejs P, Kolomaznik K, Ougizawa T, Inoue T, J. Appl. Polym. Sci., 121(1), 521 (2011)

[3] Pramanik NK, Haldar R, Niyogi UK, Alam S, J. Macromol. Sci.-Pure Appl. Chem., 51, 296 (2014)

[4] Rajeshbabu R, Gohs U, Naskar K, Mondal M, Wagenknecht U, Heinrich G, Macromol. Mater. Eng., 297, 659 (2012)

[5] Valentine L, J. Polym. Sci. A: Polym. Chem., 23, 297 (1957)

[6] Lugao AB, Hutzler B, Ojeda T, Tokumoto S, Siemens R, Makuuchi K, Villavicencio ALC, Radiat. Phys. Chem., 57, 389 (2000)

[7] Charlesby A, Nature, 171, 167 (1953)

[8] Lawton EJ, Bueche AM, Balwit JS, Nature, 172, 76 (1953)

[9] Little K, Nature, 173, 680 (1954)

[10] Bernstein BS, George O, Gyula O, Sebastian T, J. Polym. Sci. A: Polym. Chem., 3, 3405 (1965)

[11] Dadbin S, Frounchi M, Goudarzi D, Polym. Degrad. Stabil., 89, 436 (2005)

[12] Shin BS, Jeun JP, Kim HB, Kang PH, Polym. Korea, 35(1), 30 (2011)

[13] Pramanik N, Haldar R, Niyogi U, Alam M, Defence Sci. J., 64, 281 (2014)

[14] Burillo G, Adem E, Munoz E, Vasquez M, Radiat. Phys. Chem., 84, 140 (2013)

[15] Adem E, Burillo G, Del Castillo L, Vasquez M, Avalos-Borja M, Marcos-Fernandez A, Radiat. Phys. Chem., 97, 165 (2014)

[16] Huang H, Zhang X, Lu H, J. Macromol. Sci.-Phys., 46, 1105 (2007)

[17] Shin BY, Kim JH, Radiat. Phys. Chem., 112, 88 (2015)

[18] Nishi Y, Sato H, Takei H, Iwata K, J. Mater. Res., 24, 3503 (2009)

[19] Imam MA, Jeelani S, Rangari VK, Gome MG, Moura EAB, Int. J. Nanosci., 15, 165000 (2016)

[20] Pramanik N, Haldar R, Bhardwaj Y, Sabharwal S, Niyogi U, Khandal R, Radiat. Phys. Chem., 78, 199 (2009)

[21] Pramanik NK, Haldar RS, Bhardwaj YK, Sabharwal S, Niyogi UK, Khandal RK, J. Appl. Polym. Sci., 122(1), 193 (2011)

[22] Pramanik NK, Haldar R, Niyogi UK, Alam S, J. Macromol. Sci.-Pure Appl. Chem., 51, 296 (2014)

[23] Imam MA, Gomes MG, Moura EAB, Jeelani S, Rangari VK, International SAMPE Technical Conference, 2013.

[24] Linggawati A, Mohammad AW, Ghazali Z, Eur. Polym. J., 45, 2797 (2009)

[25] Nasef MM, Saidi H, Dahlan KZM, Nucl. Instrum. Methods Phys. Res. Sect. B-Beam Interact. Mater. Atoms, 265, 168 (2007)

[26] Liu F, Du CH, Zhu BK, Xu YY, Polymer, 48(10), 2910 (2007)

[27] Kim H, Abdala AA, Macosko CW, Macromolecules, 43(16), 6515 (2010)

[28] Wu W, Wan C, Wang S, Zhang Y, RSC Adv., 3, 26166 (2013)

[29] Jin XD, Hu GS, Yang YF, Zhou XM, Wang BB, J. Adhes. Sci. Technol., 23(5), 779 (2009)

[30] Zhou YH, Xue WL, Zeng ZX, Zhu WY, Li ZL, J. Adhes. Sci. Technol., 29(7), 670 (2015)

[31] Sengupta R, Sabharwal S, Tikku VK, Somani AK, Chaki TK, Bhowmick AK, J. Appl. Polym. Sci., 99(4), 1633 (2006)

[32] Charlesby A, Pinner S, Proc. R. Soc. Lond. A, 249, 367 (1959)

[33] Sengupta R, Tikku V, Somani AK, Chaki TK, Bhowmick AK, Radiat. Phys. Chem., 72, 625 (2005)

[34] Nasef MM, Saidi H, Dahlan KZM, Polym. Degrad. Stabil., 75, 85 (2002)

[35] Ye HJ, Yang L, Shao WZ, Li Y, Sun SB, Zhen L, RSC Adv., 4, 13525 (2014)