화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Applied Chemistry for Engineering, Vol.29, No.4, 388-394, August, 2018
DOI10.14478/ace.2018.1024  Export Citation
폐감귤박으로 제조한 자성 활성탄을 이용한 2,4-디클로로페놀의 흡착특성
Adsorption Characteristics of 2,4-Dichlrophenol by Magnetic Activated Carbon Prepared from Waste Citrus Peel
감상규, 이민규1, †
  • 제주대학교 환경공학과
  • 1부경대학교 화학공학과
Sang-Kyu Kam, and Min-Gyu Lee1, †
  • Department of Environmental Engineering, Jeju National University, 102 Jejudaehak-ro, Jeju-si, Jeju Special Self-Governing Province 63243, Korea
  • 1Department of Chemical Engineering, Pukyong National University, 365 Sinseon-ro, Nam-Gu, Busan 48547, Korea
E-mail:
초록
폐감귤박으로 제조한 자성 활성탄(MAC, magnetic activated carbon)을 이용하여 수용액 중의 2,4-디클로로페놀(2,4-dichlorophenol, 2,4-DCP)을 제거하는 연구하였다. 접촉시간, MAC의 투여량, 용액의 온도, pH 및 2,4-DCP 농도를 변화시켜 MAC에 의한 2,4-DCP의 흡착특성을 조사하였다. 등온 흡착 실험결과는 Langmuir 등온 모델식에 의해 잘 설명되었으며, Langmuir 등온식으로부터 구한 최대 흡착량은 312.5 mg/g이었다. 흡착속도는 유사 2차 속도식에 의해 잘 기술되었으며, 입자 내 확산 모델 자료는 흡착 과정 동안 막 확산과 입자 내 확산이 동시에 일어나는 것을 말해 주었다. 열역학적 파라미터인 △H°와 △G°는 각각 양의 값과 음의 값을 가지므로 MAC에 의한 2,4-DCP의 흡착은 자발적이며 흡열반응으로 일어나는 것을 알 수 있었다. 흡착실험을 완료한 후 사용한 MAC는 외부에서 자석을 이용하여 쉽게 분리할 수 있었다.
The removal of 2,4-dichlorophenol (2,4-dichlorophenol, 2,4-DCP) in aqueous solution was studied using the magnetic activated carbon (MAC) prepared from waste citrus peel. The adsorption characteristics of 2,4-DCP by MAC were investigated by varying the contact time, MAC dose, solution temperature, pH and 2,4-DCP concentration. The isothermal adsorption data were well explained by the Langmuir isotherm model equation and the maximum adsorption capacity calculated from the Langmuir isotherm equation was 312.5 mg/g. The adsorption kinetic data were well described by the pseudo-second-order reaction equation. The intraparticle diffusion model data indicated that both the film and intraparticle diffusion occur simultaneously during the adsorption process. The thermodynamic parameters of △H° and △G° have positive and negative values, respectively, indicating that the adsorption of 2,4-DCP by MAC is a spontaneous endothermic reaction. After the adsorption experiment was completed, the used MAC could be easily separated by an external magnet.
Keywords:adsorption;2,4-dichlrophenol;activated carbon;magnetic activated carbon;citrus peel
  1. Dabrowski A, Podkoscielny P, Hubicki Z, Barczak M, Chemosphere, 58, 1049 (2005)
  2. Kusmierek K, Szala M, Swiatkowski A, J. Taiwan Inst. Chem. Eng., 63, 371 (2016)
  3. Das S, Banthia AK, Adhikari B, Chem. Eng. J., 138(1-3), 215 (2008)
  4. Wang CC, Lee CM, Kuan CH, Bacillus insolitus, Chemosphere, 41, 447-452 (2000).
  5. Rodgers JD, Jedral W, Bunce NJ, Environ. Sci. Technol., 33, 1453 (1999)
  6. Devipriya SP, Yesodharan S, J. Environ. Biol., 31, 247 (2010)
  7. Nevskaia DM, Santianes A, Munoz V, Guerrero-Ruiz A, Carbon, 37, 1065 (1999)
  8. Wang SL, Tzou YM, Lu YH, Sheng GY, J. Hazard. Mater., 147(1-2), 313 (2007)
  9. Liu QS, Zheng T, Wang P, Jiang JP, Li N, Chem. Eng. J., 157(2-3), 348 (2010)
  10. Dias M, Alvim-Ferraz MCM, Almeida MF, Rivera-Utrilla J, Sanchez-Polo M, J. Environ. Manage., 85, 833 (2007)
  11. Annadurai G, Juang RS, Lee DJ, Water Sci. Technol., 47, 185 (2002)
  12. Hameed BH, J. Hazard. Mater., 161, 253 (2009)
  13. Popuri SR, Jammala A, Reddy KVN, Abburi K, Electron. J. Biotechnol., 3, 358 (2007)
  14. Ahmedna M, Marshall WE, Rao RM, Bioresour Technol., 71(2), 113 (2000)
  15. Reddad Z, Gerente C, Andres Y, Lecloirec P, Environ. Sci. Technol., 36, 2067 (2002)
  16. Lee CH, Kam SK, Lee MG, Korean Chem. Eng. Res., 55(5), 723 (2017)
  17. Kam SK, Lee MG, Appl. Chem. Eng., 29(3), 270 (2018)
  18. Schwickardi M, Olejnik S, Salabas EL, Schmidt W, Schuth F, Chem. Commun., 38, 3987 (2006)
  19. Banerjee SS, Chen DH, J. Hazard. Mater., 147(3), 792 (2007)
  20. Chang CF, Lin PH, Holl W, Colloids Surf., 280, 194 (2006)
  21. Yang N, Zhu S, Zhang D, Xu S, Mater. Lett., 62, 645 (2008)
  22. Shon JS, Kim DB, Kim TI, Kim EJ, Lee CH, Kam SK, Lee MG, Proceedings of 2016 Annual Conf. of the Korean Soc. Environ. Sci., Nov. 3-5, Daegu Univ., Korea (2016).
  23. Shaarani FW, Hameed BH, Chem. Eng. J., 169(1-3), 180 (2011)
  24. Sathishkumar M, Binupriya AR, Kavitha D, Selvakumar R, Jayabalan R, Choi JG, Yun SE, Chem. Eng. J., 147(2-3), 265 (2009)
  25. Hameed BH, Chin LH, Rengaraj S, Desalination, 225(1-3), 185 (2008)
  26. Lee CH, Park JM, Lee MG, J. Environ. Sci. Int., 24, 151 (2015)
  27. Lagergren S, Kunglia Svenska Vetenskapsa-kademiens Handlingar., 24, 1-39 (1898).
  28. Ho YS, McKay G, Process Biochem., 34(5), 451 (1999)
  29. Wang JP, Feng HM, Yu HQ, J. Hazard. Mater., 144(1-2), 200 (2007)
  30. Weber WJ, Morris JC, J. Sanit. Eng. Div., 89, 31 (1963)
  31. Shaarani FW, Hameed BH, Desalination, 255(1-3), 159 (2010)
  32. Srivastava VC, Swamy MM, Mall ID, Prasad B, Mishra IM, Colloids Surf. A: Physicochem. Eng. Asp., 272, 89 (2006)
  33. Langmuir I, J. Am. Chem. Soc., 40, 1361 (1918)
  34. Freundlich HMF, J. Phys. Chem., 57, 385 (1906)
  35. Sathishkumar M, Vijayaraghavan K, Binupriya AR, Stephan AM, Choi JG, Yun SE, J. Colloid Interface Sci., 320(1), 22 (2008)
  36. Bhatnagar A, Minocha AK, J. Hazard. Mater., 168(2-3), 1111 (2009)
  37. Alam MZA, Muyibi SA, Toramae J, J. Environ. Sci., 19, 674 (2007)
  38. Daifullah AAM, Girgis BS, Water Res., 32, 1169 (1998)