화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.65, 290-299, September, 2018
DOI10.1016/j.jiec.2018.04.040  Export Citation
Fluorescent detection of Zn(II) and In(III) and colorimetric detection of Cu(II) and Co(II) by a versatile chemosensor
Ahran Kim, Ji Hye Kang, Hyo Jung Jang, and Cheal Kim†
  • Department of Fine Chemistry, Seoul National University of Science & Technology (SNUT), Seoul 139-743, Republic of Korea
E-mail:
A new versatile chemosensor 1 ((Z)-N'-(quinolin-2-ylmethylene)furan-2-carbohydrazide), based on quinoline and furan, has been synthesized. Sensor 1 showed immediate responses toward Zn2+ and In3+ ions through selective fluorescence enhancement in different solvent conditions, respectively. In addition, sensor 1 could detect Cu2+ and Co2+ by “naked eye” color changes from colorless to pale yellow in a near-perfect aqueous solution. This observation was the first case that a single sensor can detect the four metal ions. The binding modes of 1 to Zn2+, In3+, Cu2+ and Co2+ were verified through Job plots and ESI-mass spectrometry analyses. The limits of detection (0.33 mμ, 0.23 mM and 0.06 mM) for Zn2+, Cu2+ and Co2+ were far lower than the World Health Organization (WHO) guidelines (76 mμ for Zn2+ and 31.5 mM for Cu2+) and Department of Environmental Protection (DEP) guideline (1.7 mμ for Co2+) for drinking water. Moreover, sensor 1 could quantify Zn2+ and Co2+ in water samples. The sensing mechanisms of Zn2+, In3+ and Cu2+ by sensor 1 were explained by theoretical calculations.
Keywords:Multiple analytes;Colorimetric;Fluorescent;Chemosensor;Theoretical calculation
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