화학공학소재연구정보센터
Macromolecular Research, Vol.26, No.8, 717-723, August, 2018
Nanocomposite Hydrogel Adhered to Concrete Material for Aquaculture of Marine Organism
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Nanocomposite (NC) hydrogels based on N,N′-dimethyl acrylamide (DMAAm) using Laponite were prepared. The mechanical properties, adhesive properties to concrete material, and bio-fouling behavior of microalgae Nitzschia sp. were investigated. The elongation and fracture strength of the NC hydrogels were greatly increased and the elastic modulus was decreased in comparison with those of typical hydrogels prepared by using the organic cross-linking agent N,N′-methylenebis(acrylamide) (MBAA). In case of NC hydrogels, they had excellent adhesion properties to the concrete material. The adherence of microalgae on the NC hydrogel surface was also much higher. As the concentration of Laponite in the nanocomposite hydrogels increased, the elastic modulus and fracture strength increased, and the elongation at break, peeling force, and peeling energy were found to be at a maximum at certain concentrations.
  1. Peak CW, Wilker JJ, Schmidt G, Colloid Polym. Sci., 291, 2031 (2013)
  2. Na YH, Korea-Australia Rheol. J., 25, 185 (2013)
  3. Haraguchi K, Takehisa T, Adv. Mater., 14(16), 1120 (2002)
  4. Gong JP, Katsuyama Y, Kurokawa T, Osada Y, Adv. Mater., 15(14), 1155 (2003)
  5. Okumura Y, Ito K, Adv. Mater., 13(7), 485 (2001)
  6. Sakai T, Matsunaga T, Yamamoto Y, Ito C, Yoshida R, Suzuki S, Sasaki N, Shibayama M, Chung UI, Macromolecules, 41(14), 5379 (2008)
  7. Henderson KJ, Zhou TC, Otim KJ, Shull KR, Macromolecules, 43(14), 6193 (2010)
  8. Haraguchi K, Farnworth R, Ohbayashi A, Takehisa T, Macromolecules, 36(15), 5732 (2003)
  9. Haraguchi K, Li HJ, Song LY, Murata K, Macromolecules, 40(19), 6973 (2007)
  10. Haraguchi K, Li HJ, Matsuda K, Takehisa T, Elliott E, Macromolecules, 38(8), 3482 (2005)
  11. Haraguchi K, Polym. J., 43, 223 (2011)
  12. Hoppe A, Guldal NS, Boccaccini AR, Biomaterials, 32, 2757 (2011)
  13. Hench LL, J. Eur. Ceram. Soc., 29, 1257 (2009)
  14. Hench LL, Paschall H, J. Biomed. Mater. Res. A, 7, 25 (1973)
  15. Thompson DW, Butterworth JT, J. Colloid Interface Sci., 151, 236 (1992)
  16. Hotta M, Kennedy J, Higginbotham C, Morris N, Appl. Mech. Mater., 679, 81 (2014)
  17. Pedrini S, Merritt DJ, Stevens J, Dixon K, Trends Plant Sci., 22, 106 (2017)
  18. Liu Y, Meng H, Konst S, Sarmiento R, Rajachar R, Lee BP, ACS Appl. Mater. Interfaces, 6, 16982 (2014)
  19. Dawson JI, Oreffo ROC, Adv. Mater., 25(30), 4069 (2013)
  20. Shen MX, Li L, Sun YM, Xu J, Guo XH, Prud'homme RK, Langmuir, 30(6), 1636 (2014)
  21. Wang M, Yuan D, Fan XS, Sahoo NG, He CB, Langmuir, 29(23), 7087 (2013)
  22. Skelton S, Bostwick M, O'Connor K, Konst S, Casey S, Lee BP, Soft Matter, 9, 3825 (2013)
  23. Murosaki T, Noguchi T, Kakugo A, Putra A, Kurokawa T, Furukawa H, Osada Y, Gong JP, Nogata Y, Matsumura K, Biofouling, 25, 313 (2009)
  24. Murosaki T, Noguchi T, Hashimoto K, Kakugo A, Kurokawa T, Saito J, Chen YM, Furukawa H, Gong JP, Biofouling, 25, 657 (2009)
  25. Zhang D, Yang J, Bao S, Wu Q, Wang Q, Sci Rep, 3 (2013)
  26. Na YH, Oh HY, Ahn YJ, Han Y, Korea-Australia Rheol. J., 27, 25 (2015)
  27. Hoang MV, Chung HJ, Elias AL, J. Micromech. Microeng., 26, 105019 (2016)
  28. Messing R, Frickel N, Belkoura L, Strey R, Rahn H, Odenbach S, Schmidt AM, Macromolecules, 44(8), 2990 (2011)
  29. Duong VT, Thomas-Hall SR, Schenk PM, Front. Plant Sci., 6, 359 (2015)
  30. Watermann F, Hillebrand H, Gerdes G, Krumbein WE, Sommer U, Mar. Ecol. Prog. Ser., 77 (1999)
  31. Stal L, De Brouwer J, Berichte-Forschungszentrum TERRAMARE, 12, 109 (2003)
  32. Xia B, Chen B, Sun X, Qu K, Ma F, Du M, Sci. Total Environ., 508, 525 (2015)
  33. Teli SB, Molina S, Sotto A, Garcia-Calvo E, de Abajo J, Ind. Eng. Chem. Res., 52(27), 9470 (2013)