Korean Journal of Chemical Engineering, Vol.35, No.11, 2296-2302, November, 2018
A strategy to prepare internally plasticized PVC using a castor oil based derivative
E-mail:
Internally plasticized PVC was prepared via chemical reaction of azide PVC and alkynyl group containing castor oil methyl ester. The chemical structure of alkynyl group containing castor oil methyl ester and internally plasticized PVC was characterized with FT-IR and 1H NMR. Properties of internally plasticized PVC, including thermal stability, tensile tests and resistance to extraction in different solvents, was investigated. The results showed that alkynyl group containing castor oil methyl ester, as internal plasticizer of PVC, not only decreased the Tg of PVC from 84.6 °C to 41.6 °C efficiently, but also presented no plasticizer loss in five different solvents. The tensile tests showed that elongation at break and tensile strength of internally plasticized PVC was 353.8% and 18.1MPa. The internally plasticized PVC has potential application in replacing the traditional PVC material in PVC products with high durability.
- Zhou Y, Yang N, Hu S, Resour. Conserv. Recycl., 73, 33 (2013)
- Qiu Z, Zhou P, RSC Adv., 4, 51411 (2014)
- Jia P, Zhang M, Hu L, Zhou J, Feng G, Zhou Y, Polym. Degrad. Stabil., 121, 292 (2015)
- Vieira MGA, da Silva MA, dos Santos LO, Beppu MM, Eur. Polym. J., 47, 254 (2011)
- Rahman M, Brazel CS, Prog. Polym. Sci, 29, 1223 (2004)
- Jia P, Zhang M, Hu L, Zhou Y, Korean J. Chem. Eng., 33(3), 1080 (2016)
- Benjamin S, Masai E, Kamimura N, Takahashi K, Anderson RC, Faisal PA, J. Hazard. Mater., 340, 360 (2017)
- Perez AL, Liong M, Plotkin K, Rickabaugh KP, Paustenbach DJ, Chemosphere, 167, 541 (2017)
- Li JH, Ko YC, Kaohsiung J. Med. Sci., 28, S17 (2012)
- Gani KM, Tyagi VK, Kazmi AA, Environ. Sci. Pollut. Res., 24, 17267 (2017)
- Jia P, Zhang M, Hu L, Feng F, Bo C, Zhou Y, ACS. Sustain. Chem. Eng., 3, 2187 (2015)
- Chen J, Li X, Wang Y, Li K, Huang J, Jiang J, Nie X, J. Taiwan Inst. Chem. E., 65, 488 (2016)
- Jia P, Zhang M, Liu C, Hu L, Feng G, Bo C, Zhou Y, RSC Adv., 5, 41169 (2015)
- Chieng BW, Ibrahim NA, Then YY, Loo YY, Polymers, 9, 204 (2017)
- Arrieta MP, Samper MD, Jimenez-Lopez M, Aldas M, Lopez J, Ind. Crop. Prod., 99, 196 (2017)
- Ang DTC, Khong YK, Gan SN, J. Vinyl. Addit. Techn., 22, 80 (2016)
- Lee S, Park MS, Shin J, Kim YW, Polym. Degrad. Stabil., 147, 1 (2018)
- Jia P, Hu L, Yang X, Zhang M, Shang Q, Zhou Y, RSC Adv., 7, 30101 (2017)
- Jia P, Zhang M, Hu L, Song F, Feng G, Zhou Y, SCI REPUK, 8, 1589 (2018)
- Jia P, Zhang M, Hu L, Wang R, Sun C, Zhou Y, Polymers, 9, 621 (2017)
- Jia P, Hu L, Zhang M, Feng G, Zhou Y, Eur. Polym. J., 87, 209 (2017)
- Navarro R, Perrino MP, Garcia C, Elvira C, Gallardo A, Reinecke H, Macromolecules, 49(6), 2224 (2016)
- Lee KW, Chung JW, Kwak SY, Macromol. Rapid Commun., 37(24), 2045 (2016)
- Choi J, Kwak SY, Environ. Sci. Technol., 41, 3763 (2007)
- Yu BY, Chung JW, Kwak SY, Environ. Sci. Technol., 42, 7522 (2008)
- Choi W, Chung JW, Kwak SY, ACS Appl. Mater. Interfaces, 6, 11118 (2014)
- Liu C, Li J, Lei W, Zhou Y, Ind. Crop. Prod., 52, 329 (2014)
- Zhang L, Zhang M, Zhou Y, Hu L, Polym. Degrad. Stabil., 98, 2784 (2013)
- Jia P, Hu L, Zhang M, Zhou Y, J. Therm. Anal. Calorim., 124, 1331 (2016)
- Jia P, Wang R, Hu L, Zhang M, Zhou Y, Pol. J. Chem. Technol., 19, 16 (2017)
- Lafarge J, Kebir N, Schapman D, Gadenne V, Burel F, Cellulose, 20, 2779 (2013)
- Kiskan B, Demiray G, Yagci Y, J. Polym. Sci. A: Polym. Chem., 46(11), 3512 (2008)
- Qu HQ, Liu X, Xu JZ, Ma HY, Jiao YH, Xie JX, Ind. Eng. Chem. Res., 53(20), 8476 (2014)
- Levchik SV, Weil ED, Polym. Adv. Technol., 15, 691 (2004)
- Balabanovich AI, Zevaco TA, Schnabel W, Macromol. Mater. Eng., 289, 181 (2004)
- Balabanovich AI, Thermochim. Acta, 435(2), 188 (2005)