화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.68, 48-56, December, 2018
DOI10.1016/j.jiec.2018.07.028  Export Citation
Immobilization of potassium copper hexacyanoferrate in doubly crosslinked magnetic polymer bead for highly effective Cs+ removal and facile recovery
Yun Kon Kim, Kyeonghui Bae, Yonghwan Kim, and David Harbottle1, †
  • Department of Chemical and Biomolecular Engineering, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 305-701, Republic of Korea
  • 1School of Chemical and Process Engineering, University of Leeds, Leeds LS2 9JT, United Kingdom, UK
E-mail:
A potassium copper hexacyanoferrate (KCuHCF) embedded magnetic hydrogel bead (HCF-Mbead) was synthesized via a facile double crosslinking methods of Fe3+ ionic binding and freeze-thaw for effective Cs+ removal. The HCF-Mbead had a hierarchical porous structure facilitating fast access of Cs+ ions to embedded active sites. The adsorbent showed enhanced Cs+ removal properties in terms of capacity (69.2 mg/g), selectivity (Kd = 4 × 104 mL/g, 1 ppm Cs+ in seawater) and stability (>99.5% removal in pH 3 ∼ 11) with rapid magnetic separation. This study further opens the possibility to develop an efficient material that links the integration of adsorption and recovery.
Keywords:Cesium removal;Adsorption;Hexacyanoferrate;Polymer bead;Magnetic recovery
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