Physical properties of mungbean starch/PVA bionanocomposites added nano-ZnS particles and its photocatalytic activity

Yeon-Hum Yun; Eun-Sik Kim; Wang-Geun Shim; Soon-Do Yoon

Journal of Industrial and Engineering Chemistry, Vol.68, 57-68, December, 2018

DOI10.1016/j.jiec.2018.07.029 Export Citation

Physical properties of mungbean starch/PVA bionanocomposites added nano-ZnS particles and its photocatalytic activity

Yeon-Hum Yun, Eun-Sik Kim¹, Wang-Geun Shim^{2, †}, and Soon-Do Yoon^{3, †}

Department of Energy & Resources Engineering, Chonnam National University, Gwangju 61186, Republic of Korea
¹Department of Environmental System Engineering, Chonnam National University, Yeosu 59626, Republic of Korea
²Department of Polymer Science and Engineering, Sunchon National University, Suncheon 57922, Republic of Korea
³Department of Chemical and Biomolecular Engineering, Chonnam National University, Yeosu 59626, Republic of Korea

E-mail:,

The main objective of this study is to prepare the bionanocomposite films using mungbean starch (MBS), PVA, ZnS, and plasticizers, and to evaluate the physical properties, thermal stability, and photocatalytic activity. The bionanocomposite films were cross-linked by heat-curing process. The ZnS and bionanocomposite films were characterized by FT-IR, XRD, and SEM. The results indicated that the mechanical properties and water resistance enhanced up to 1.2?1.5 times by the addition of nano-ZnS particles, and the thermal stability was improved by the addition of nano-ZnS particles. The photocatalytic activity of the bionanocomposite films added nano-ZnS particles was examined using bisphenol A (BPA) and methyl orange (MO). In addition, the photodegradation efficiency of BPA and MO was evaluated using the pseudo-first order kinetic model (PFOK).

Keywords:Mungbean starch/PVA bionanocomposite;films;Nano-ZnS particles;Physical properties;Photodegradation efficiency

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[3] Cazon P, Velazquez G, Ramirez JA, Vazquez M, Food Hydrocolloids, 68, 136 (2017)

[4] Huang D, Wang W, Xu J, Wang A, J. Chem. Eng., 210, 166 (2012)

[5] Liu Y, Wang S, Lan W, Int. J. Biol. Macromol., 107, 848 (2018)

[6] Kim EH, Han GD, Noh SH, Kim JW, Lee JG, Ito Y, Son TI, J. Ind. Eng. Chem., 54, 1 (2017)

[7] Aydın AA, Ilberg V, Carbohydr. Polym., 136, 441 (2016)

[8] Liu Z, Dong Y, Men H, Jiang M, Tonga J, Zhou J, Carbohydr. Polym., 89, 473 (2012)

[9] Ali A, Xie F, Yu L, Liu H, Meng L, Khalid S, Chen L, Compos. Partt B Eng., 133, 122 (2018)

[10] Luo X, Li J, Lin X, Carbohydr. Polym., 90, 1595 (2012)

[11] Jia XL, Listak J, Witherspoon V, Kalu EE, Yang XP, Bockstaller MR, Langmuir, 26(14), 12190 (2010)

[12] Xie F, Pollet E, Halley PJ, Averous L, Prog. Polym. Sci, 38, 1590 (2013)

[13] Naushad M, Ahamad T, Sharma G, Al-Muhtaseb AH, Albadarin AB, Alam MM, ALOthman ZA, Alshehri SM, Ghfar AA, J. Chem. Eng., 300, 306 (2016)

[14] Muller CMO, Laurindo JB, Yamashita F, Ind. Crop. Prod., 33, 605 (2011)

[15] Majdzadeh-Ardakani K, Nazari B, Compos. Sci. Technol., 70, 1557 (2010)

[16] Tang S, Zou P, Xiong H, Tang H, Carbohydr. Polym., 72, 521 (2008)

[17] Yao K, Cai J, Liu M, Yu Y, Xiong H, Tang S, Ding S, Carbohydr. Polym., 86, 1784 (2011)

[18] Frost K, Barthes J, Kaminski D, Lascaris E, Niere J, Shanks R, Carbohydr. Polym., 84, 343 (2011)

[19] Harrison BS, Atala A, Biomaterials, 28, 344 (2007)

[20] Fama LM, Pettarin V, Goyanes SN, Bernal CR, Carbohydr. Polym., 83, 1226 (2011)

[21] Ma X, Yu J, Wang N, Compos. Sci. Technol., 68, 268 (2008)

[22] Ma X, Chang PR, Yu J, Starch Starke, 60, 373 (2008)

[23] Ma X, Chang PR, Yang J, Yu J, Carbohydr. Polym., 75, 472 (2009)

[24] Ma T, Chang PR, Zheng P, Ma X, Carbohydr. Polym., 94, 63 (2013)

[25] Jose J, Al-Harthi MA, AlMaadeed MAA, Dakua JB, De SK, J. Appl. Polym. Sci., 132, 41827 (2015)

[26] Feng Y, Feng N, Dua G, RSC Adv., 3, 21466 (2013)

[27] Byun HS, Park MH, Lim GT, Yoon SD, J. Nanosci. Nanotechnol., 11, 1701 (2011)

[28] Hoover R, Hynes YXL, Senanayake N, Food Hydrocolloids, 11, 401 (1997)

[29] Yun YH, Youn HG, Shin JY, Yoon SD, Int. J. Biol. Macromol., 104, 1150 (2017)

[30] Juliano BO, Cereal Sci. Today, 16, 334 (1971)

[31] Chrastil J, Carbohydr. Res., 159, 154 (1987)

[32] Cho SR, Cho HG, J. Korean Chem. Soc., 57, 432 (2013)

[33] Park K, Yu HJ, Chung WK, Kim BJ, Kim SH, J. Mater. Sci., 44(16), 4315 (2009)

[34] Eggleston CM, Hug S, Stumm W, Sulzberger B, Afonso MDS, Geochim. Cosmochim. Acta, 62, 585 (1998)

[35] Panaitescu DM, Frone A, Ghiurea M, Chiulan I, Ind. Crop. Prod., 70, 170 (2015)

[36] Bursali EA, Coskun S, Kizil M, Yurdakoc M, Carbohydr. Polym., 83, 1377 (2011)

[37] Maiti S, Ray D, Mitra D, Sengupta S, Kar T, J. Appl. Polym. Sci., 122(4), 2503 (2011)

[38] Sreekumar PA, Al-Harthi MA, De SK, J. Compos. Mater., 46, 3181 (2012)

[39] Yun YH, Yoon SD, Polym. Bull., 64(6), 553 (2010)

[40] Zeng JB, Jiao L, Li YD, Srinivasan M, Li T, Wang YZ, Carbohydr. Polym., 83, 762 (2011)

[41] Radhu S, Vijayan C, Mater. Chem. Phys., 129(3), 1132 (2011)

[42] Yoon SD, Byun HS, Yun YH, Ceram. Int., 41, 8241 (2015)

[43] Yoon SD, Kim ES, Yun YH, J. Ind. Eng. Chem., 64, 230 (2018)

[44] Li F, Du P, Liu W, Li X, Ji H, Duan J, Zhao D, J. Chem. Eng., 331, 685 (2018)

[45] Li Y, Zhao HJ, Yang MJ, J. Colloid Interface Sci., 508, 500 (2017)