화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.68, 69-78, December, 2018
DOI10.1016/j.jiec.2018.07.030  Export Citation
Regenerability of a Ni catalyst in the catalytic steam reforming of biomass pyrolysis volatiles
Aitor Arregi, Gartzen Lopez†, Maider Amutio, Itsaso Barbarias, Laura Santamaria, Javier Bilbao, and Martin Olazar
  • Department of Chemical Engineering, University of the Basque Country UPV/EHU, P.O. Box 644, E48080 Bilbao, Spain
E-mail:
A study has been carried out of the regenerability of a commercial Ni catalyst used in the steam reforming of the volatiles from biomass pyrolysis (gases and bio-oil), determining the evolution of the reaction indices (conversion, product yields and H2 production) in successive reaction?regeneration cycles. The causes of catalyst deactivation (coke deposition and Ni sintering) have been ascertained characterizing the deactivated and regenerated catalysts by TPO, TEM, TPR and XRD. Catalyst activity is not fully recovered by coke combustion in the first cycles due to the irreversible deactivation by Ni sintering, but the catalyst reaches a pseudo-stable state beyond the fourth cycle, reproducing its behaviour in subsequent cycles.
Keywords:Biomass;Pyrolysis;Reforming;Deactivation;Regeneration
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