화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.68, 129-139, December, 2018
DOI10.1016/j.jiec.2018.07.037  Export Citation
Significance of N-moieties in regulating the electrochemical properties of nano-porous graphene: Toward highly capacitive energy storage devices
Firoz Khan, and Jae Hyun Kim†
  • Smart Textile Convergence Research Group, Daegu Gyeongbuk Institute of Science and Technology (DGIST), 333, Techno Jungang-Daero, Hyeonpung-Myeon, Dalseong-Gun, Daegu 42988, Republic of Korea
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The effects of N doping concentration and dopant moieties on the electrochemical properties of nanoporous graphene and their dependence on annealing temperature are investigated. Four types of N moieties - amide, amine, graphitic-N, and oxidized-N ? are obtained, which transformed into pyridinic-N and pyrrolic-N upon annealing. The diffusion coefficient (D′) of the ions in the electrode is the maximum at 400 °C because of a high level of N doping, whereas the second highest D′ value is obtained at 700 °C owing to a high level of reduction and N doping. The highest specific capacitance is obtained for the sample annealed at 400 °C.
Keywords:Porous graphene;Nitrogen moieties;Nitrogen doping;Electrochemical properties
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