화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.68, 140-145, December, 2018
DOI10.1016/j.jiec.2018.07.038  Export Citation
Bulky carbon layer inlaid with nanoscale Fe2O3 as an excellent lithium-storage anode material
Thuy-An Nguyen, and Sang-Wha Lee†
  • Department of Chemical & Biological Engineering, Gachon University, 1342 Seongnamdaero, Sujeong-gu, Seongnam-si, 461-701, Republic of Korea
E-mail:
Bulky carbon layer uniformly distributed with nanoscale Fe2O3 was prepared via a direct carbonation of Fe3+-polyacrylonitrile complexes at 700 °C under N2 flow. The iron oxide carbon composites exhibited an excellent cycling performance for lithium storage with a reversible capacity of ∼810 mAh g-1 after 250 cycles at a current rate of 100 mA g-1. The enhancement was mainly attributed to dual functions of bulky carbon layer which facilitated the lithium-ion diffusion and accommodated the volume changes of active Fe2O3 during charge/discharge process. Our novel chemical strategy is quite effective for scalable fabrication of high capacity lithium-storage materials.
Keywords:Bulky carbon layer;Nanoscale Fe2O3;Anode materials;PAN;Lithium storage
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